Ground state of an S=1/2S=1/2 distorted diamond chain - model of Cu3Cl6(H2O)2⋅2H8C4SO2\rm Cu_3 Cl_6 (H_2 O)_2 \cdot 2H_8 C_4 SO_2

We study the ground state of the model Hamiltonian of the trimerized $S=1/2$ quantum Heisenberg chain $\rm Cu_3 Cl_6 (H_2 O)_2 \cdot 2H_8 C_4 SO_2$ in which the non-magnetic ground state is observed recently. This model consists of stacked trimers and has three kinds of coupling constants between spins; the intra-trimer coupling constant $J_1$ and the inter-trimer coupling constants $J_2$ and $J_3$. All of these constants are assumed to be antiferromagnetic. By use of the analytical method and physical considerations, we show that there are three phases on the $\tilde J_2 - \tilde J_3$ plane ($\tilde J_2 \equiv J_2/J_1$, $\tilde J_3 \equiv J_3/J_1$), the dimer phase, the spin fluid phase and the ferrimagnetic phase. The dimer phase is caused by the frustration effect. In the dimer phase, there exists the excitation gap between the two-fold degenerate ground state and the first excited state, which explains the non-magnetic ground state observed in $\rm Cu_3 Cl_6 (H_2 O)_2 \cdot 2H_8 C_4 SO_2$. We also obtain the phase diagram on the $\tilde J_2 - \tilde J_3$ plane from the numerical diagonalization data for finite systems by use of the Lanczos algorithm.Comment: LaTeX2e, 15 pages, 21 eps figures, typos corrected, slightly detailed explanation adde

Finite-Field Ground State of the S=1 Antiferromagnetic-Ferromagnetic Bond-Alternating Chain

We investigate the finite-field ground state of the S=1 antiferromagnetic-ferromagnetic bond-alternating chain described by the Hamiltonian {\calH}=\sum\nolimits_{\ell}\bigl\{\vecS_{2\ell-1}\cdot\vecS_{2\ell} +J\vecS_{2\ell}\cdot\vecS_{2\ell+1}\bigr\} +D\sum\nolimits_{\ell} \bigl(S_{\ell}^z)^2 -H\textstyle\sum\nolimits_\ell S_\ell^z, where \hbox{$J\leq0$} and \hbox{$-\infty<D<\infty$}. We find that two kinds of magnetization plateaux at a half of the saturation magnetization, the 1/2-plateaux, appear in the ground-state magnetization curve; one of them is of the Haldane type and the other is of the large-$D$-type. We determine the 1/2-plateau phase diagram on the $D$ versus $J$ plane, applying the twisted-boundary-condition level spectroscopy methods developed by Kitazawa and Nomura. We also calculate the ground-state magnetization curves and the magnetization phase diagrams by means of the density-matrix renormalization-group method

Convergence of the Allen-Cahn equation with Neumann boundary conditions

We study a singular limit problem of the Allen-Cahn equation with Neumann boundary conditions and general initial data of uniformly bounded energy. We prove that the time-parametrized family of limit energy measures is Brakke's mean curvature flow with a generalized right angle condition on the boundary.Comment: 26 pages, 1 figur

Co-operative density wave and giant spin gap in the quarter-filled zigzag ladder

Strong co-operative interactions occur between four different broken symmetries involving charge-ordering and bond distortions in the quarter-filled correlated zigzag electron ladder. The ground state is singlet, with spin gap several times larger than in the spin-Peierls state of the one-dimensional quarter-filled chain with the same parameters. We propose the quarter-filled zigzag electron ladder model for several different organic charge-transfer solids with coupled pairs of quasi-one-dimensional stacks, the spin-gap transition temperatures in which are unusually high.Comment: 4 pages, 4 EPS figures. accepted in Physical Review Letter

Spin and chiral orderings of frustrated quantum spin chains

Ordering of frustrated S=1/2 and 1 XY and Heisenberg spin chains with the competing nearest- and next-nearest-neighbor antiferromagnetic couplings is studied by exact diagonalization and density-matrix renormalization-group methods. It is found that the S=1 XY chain exhibits both gapless and gapped `chiral' phases characterized by the spontaneous breaking of parity, in which the long-range order parameter is a chirality, $\kappa_i = S_i^xS_{i+1}^y-S_i^yS_{i+1}^x$, whereas the spin correlation decays either algebraically or exponentially. Such chiral phases are not realized in the S=1/2 XY chain nor in the Heisenberg chains.Comment: 4 pages, 5 EPS-figures, LaTeX(RevTeX),to appear in J.Phys.Soc.Japa

Dimerization-induced enhancement of the spin gap in the quarter-filled two-leg rectangular ladder

We report density-matrix renormalization group calculations of spin gaps in the quarter-filled correlated two-leg rectangular ladder with bond-dimerization along the legs of the ladder. In the small rung-coupling region, dimerization along the leg bonds can lead to large enhancement of the spin gap. Electron-electron interactions further enhance the spin gap, which is nonzero for all values of the rung electron hopping and for arbitrarily small bond-dimerization. Very large spin gaps, as are found experimentally in quarter-filled band organic charge-transfer solids with coupled pairs of quasi-one-dimensional stacks, however, occur within the model only for large dimerization and rung electron hopping that are nearly equal to the hopping along the legs. Coexistence of charge order and spin gap is also possible within the model for not too large intersite Coulomb interaction

Universal emergence of the one-third plateau in the magnetization process of frustrated quantum spin chains

We present a numerical study of the magnetization process of frustrated quantum spin-S chains with S=1, 3/2, 2 as well as the classical limit. Using the exact diagonalization and density-matrix renormalization techniques, we provide evidence that a plateau at one third of the saturation magnetization exists in the magnetization curve of frustrated spin-S chains with S>1/2. Similar to the case of S=1/2, this plateau state breaks the translational symmetry of the Hamiltonian and realizes an up-up-down pattern in the spin component parallel to the external field. Our study further shows that this plateau exists both in the cases of an isotropic exchange and in the easy-axis regime for spin-S=1, 3/2, and 2, but is absent in classical frustrated spin chains with isotropic interactions. We discuss the magnetic phase diagram of frustrated spin-1 and spin-3/2 chains as well as other emergent features of the magnetization process such as kink singularities, jumps, and even-odd effects. A quantitative comparison of the one-third plateau in the easy-axis regime between spin-1 and spin-3/2 chains on the one hand and the classical frustrated chain on the other hand indicates that the critical frustration and the phase boundaries of this state rapidly approach the classical result as the spin S increases.Comment: 15 pages RevTex4, 13 figure

How to distinguish the Haldane/Large-D state and the intermediate-D state in an S=2 quantum spin chain with the XXZ and on-site anisotropies

We numerically investigate the ground-state phase diagram of an S=2 quantum spin chain with the $XXZ$ and on-site anisotropies described by ${\mathcal H}=\sum_j (S_j^x S_{j+1}^x+S_j^y S_{j+1}^y+\Delta S_j^z S_{j+1}^z) + D \sum_j (S_j^z)^2$, where $\Delta$ denotes the XXZ anisotropy parameter of the nearest-neighbor interactions and $D$ the on-site anisotropy parameter. We restrict ourselves to the $\Delta>0$ and $D>0$ case for simplicity. Our main purpose is to obtain the definite conclusion whether there exists or not the intermediate-$D$ (ID) phase, which was proposed by Oshikawa in 1992 and has been believed to be absent since the DMRG studies in the latter half of 1990's. In the phase diagram with $\Delta>0$ and $D>0$ there appear the XY state, the Haldane state, the ID state, the large-$D$ (LD) state and the N\'eel state. In the analysis of the numerical data it is important to distinguish three gapped states; the Haldane state, the ID state and the LD state. We give a physical and intuitive explanation for our level spectroscopy method how to distinguish these three phases.Comment: Proceedings of "International Conference on Frustration in Condensed Matter (ICFCM)" (Jan. 11-14, 2011, Sendai, Japan

Magnetization Plateau of an S=1 Frustrated Spin Ladder

We study the magnetization plateau at 1/4 of the saturation magnetization of the S=1 antiferromagnetic spin ladder both analytically and numerically, with the aim of explaining recent experimental results on BIP-TENO by Goto et al. We propose two mechanisms for the plateau formation and clarify the plateau phase diagram on the plane of the coupling constants between spins