3,086 research outputs found
Effects of periodic application of cattle slurry on soil microbial biomass in an Andisol grassland (Biological Interactions in Arable Land-Grassland-Forest Continuums and their Impact on the Ecosystem Functions, 7th International Symposium on Integrated Field Science)
Quantum Metallicity on the High-Field Side of the Superconductor-Insulator Transition
We investigate ultrathin superconducting TiN films, which are very close to
the localization threshold. Perpendicular magnetic field drives the films from
the superconducting to an insulating state, with very high resistance. Further
increase of the magnetic field leads to an exponential decay of the resistance
towards a finite value. In the limit of low temperatures, the saturation value
can be very accurately extrapolated to the universal quantum resistance h/e^2.
Our analysis suggests that at high magnetic fields a new ground state, distinct
from the normal metallic state occurring above the superconducting transition
temperature, is formed. A comparison with other studies on different materials
indicates that the quantum metallic phase following the magnetic-field-induced
insulating phase is a generic property of systems close to the disorder-driven
superconductor-insulator transition.Comment: 4 pages, 4 figures, published versio
Photochemical R2PI study of chirality and intermolecular forces in supersonic beam
One and two-color, mass selected R2PI spectra of theS1←S0transitions in the bare(+)-(R)- 1-phenyl-1-ethanol(ER) and its complexes with different solvent molecules (solv) (-)-(R)-2-butanol(BR) or(+)-(S)-2-butanol(BS), (—)-(R)-2-pentanol (TR) or(+)-(S)-2-pentanol(TS) and(-)-(R)-2-butylamine(AR) or(+)-(S)-2-butylamine(AS), have been recorded after a supersonic molecular beam expansion. The one-color R2PI excitation spectra of the diastereomeric complexes are characterized by significant shifts of their band origin relative to that of bareER. The extent and the direction of these spectral shifts are found to depend upon the structure and the configuration ofsolvand are attributed to different short-range interactions in the ground and excited states of the complexes. In analogy with other diastereomeric complexes, the phenomenological binding energy of the homochiral cluster is found to be greater than that of the heterochiral one. Preliminary measurements of excitation spectrum of(+)-(R)-1-Indanol(IR) is also reported
Laser production of gas phase complexes of metal α-aminophosphonic acid mixtures and their role in chiral recognition
Clusters between first-group metal ions and chiralα-aminophosphonic acids have been readily generated by Pulsed Laser Ablation (PLA) and by Electrospray Ionization (ESI) and their fragmentation investigated by mass spectrometry. The complexes studied have the general formula[Me(I)Cl2]+, where Me(I) is H, Li, Na, or K, C is (R)-(—)-(1-aminoethyl) phosphonic acid(ER)and (S)-(+)-(1-aminoethyl) phosphonic acid(ES),(1R)-(+)-(1-amino-2-methylpropyl) phosphonic acid(PR)and (1S)-(—)-(1-amino-2-methylpropyl) phosphonic acid(PS),(1R)-(-)-(1-amino-hexyl) phosphonic acid (HR) and (1S)-(+)-(1-amino-hexyl) phosphonic acid (HS), o-phospho-L-serine (SS)ando-phospho-D-serine(SR), and L is a referenceα-aminophosphonic acid (E, P, H or S) of defined configuration. Collision induced dissociation (CID) of diastereomeric[Me(I)Cl2]+complexes leads to fragmentation patterns characterized by[Me(I)Cl]+/[Me(I)L2]+abundance ratios which depend upon the configuration of solute C. These different spectral features were correlated to the different stability of the diastereomeric[Me(I)CRL]+and[Me(I)CSL]+complexes in the gas phase
RVB Contribution to Superconductivity in
We view as electronically equivalent to (non-staggered) graphite
( layer) that has undergone a zero gap semiconductor to a superconductor
phase transition by a large c-axis (chemical) pressure due to layers.
Further, like the \ppi bonded planar organic molecules, graphite is an old
resonating valence bond (RVB) system. The RVB's are the `preexisting cooper
pairs' in the `parental' zero gap semiconducting (graphite) sheets that
manifests themselves as a superconducting ground state of the transformed
metal. Some consequences are pointed out.Comment: 4 pages, 2 figure, RevTex. Based on a talk given at the Institute
Seminar Week, IMSc, Madras (12-16, Feb. 2001
Superconductivity on the localization threshold and magnetic-field-tuned superconductor-insulator transition in TiN films
Temperature- and magnetic-field dependent measurements of the resistance of
ultrathin superconducting TiN films are presented. The analysis of the
temperature dependence of the zero field resistance indicates an underlying
insulating behavior, when the contribution of Aslamasov-Larkin fluctuations is
taken into account. This demonstrates the possibility of coexistence of the
superconducting and insulating phases and of a direct transition from the one
to the other. The scaling behavior of magnetic field data is in accordance with
a superconductor-insulator transition (SIT) driven by quantum phase
fluctuations in two-dimensional superconductor. The temperature dependence of
the isomagnetic resistance data on the high-field side of the SIT has been
analyzed and the presence of an insulating phase was confirmed. A transition
from the insulating to a metallic phase is found at high magnetic fields, where
the zero-temperature asymptotic value of the resistance being equal to h/e^2.Comment: 5 pages, 4 eps figures, RevTeX4, Published versio
Small Fermi energy and phonon anharmonicity in MgB_2 and related compounds
The remarkable anharmonicity of the E_{2g} phonon in MgB_2 has been suggested
in literature to play a primary role in its superconducting pairing. We
investigate, by means of LDA calculations, the microscopic origin of such an
anharmonicity in MgB_2, AlB_2, and in hole-doped graphite. We find that the
anharmonic character of the E_{2g} phonon is essentially driven by the small
Fermi energy of the sigma holes. We present a simple analytic model which
allows us to understand in microscopic terms the role of the small Fermi energy
and of the electronic structure. The relation between anharmonicity and
nonadiabaticity is pointed out and discussed in relation to various materials.Comment: 5 pages, 2 figures replaced with final version, accepted on Physical
Review
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