210 research outputs found
Microwave cavity perturbation studies on H-form and Cu ion-exchanged SCR catalyst materials: correlation of ammonia storage and dielectric properties
Ammonia-based selective catalytic reduction (SCR) has become the major control strategy for NOx emissions from light and heavy duty diesel engines. Before reducing NOx on the SCR active material, ammonia storage on the active sites of the catalyst is crucial. The in operando measurement of the dielectric properties of the catalyst material using microwave cavity perturbation is a promising indicator of ammonia loading. In this work, the influence of copper ion-exchange of the zeolite-based SCR material ZSM-5 on the NH3 storage and the dielectric properties is highlighted. The catalyst powder samples were monitored by microwave cavity perturbation as a function of the stored ammonia content at a frequency of approximately 1.2 GHz in a temperature range between 200 and 350 °C. Due to ion exchange, the NH3 storage behavior changes, what could be monitored in the sensitivity of the dielectric permittivity to NH3. The dependence of the complex dielectric permittivity on ammonia loading is decreased by ion exchange, hinting that mostly ammonia storage on Brønsted sites affects the dielectric permittivity. This finding adds new knowledge to the electrical conduction and polarization mechanisms occurring in these zeolite materials
GGE BIPLOT ANALYSIS OF YIELD STABI LITY FOR ANDEAN DRY BEAN ACCESSIONS GROWN UNDER DIFFERENT ABIOTIC STRESS REGIMES IN TANZANIA
Large seeded Andean dry beans (Phaseolus vulgaris L.) are most preferred in Africa. However, low soil fertility and increasing drought stress conditions due to climate change are among the challenges faced by farmers in this region. The purpose of this study was to identify Andean genotypes with yield stability and to identify the best environments for selection of this trait. GGE-Biplot analysis was used to examine 183 Andean bean genotypes in Tanzania. Results indicated significant environment (E), genotype (G) and genotype x environment (GE) effects for seed yield. The environment explained 46%, genotype 20%, and GE 34% of the total (G + E + GE) variation. Two principal components explained 41.21% (PC1) and 26.35% (PC2) of GGE sum of squares. The Andean genotypes, ADP-102 (Jessica)- purple mottle, large seed, bush plant habit, released by Selian Agriculture Research Institution (ARI) in Tanzania; ADP-220 (G5625)- red, large seed, vine plant habit, from Central America; ADP-276 (G13654) - brown, medium seed, vine, from Mexico; and ADP-648 (‘Red Kloud’) large red kidney, with bush plant habit, were stable across environments and can be recommended for general adaptation across environments. An individual location for selection for yield stability was not identified, thus justifying the continued need for multiple test sites
GGE BIPLOT ANALYSIS OF YIELD STABI LITY FOR ANDEAN DRY BEAN ACCESSIONS GROWN UNDER DIFFERENT ABIOTIC STRESS REGIMES IN TANZANIA
Large seeded Andean dry beans (Phaseolus vulgaris L.) are most preferred in Africa. However, low soil fertility and increasing drought stress conditions due to climate change are among the challenges faced by farmers in this region. The purpose of this study was to identify Andean genotypes with yield stability and to identify the best environments for selection of this trait. GGE-Biplot analysis was used to examine 183 Andean bean genotypes in Tanzania. Results indicated significant environment (E), genotype (G) and genotype x environment (GE) effects for seed yield. The environment explained 46%, genotype 20%, and GE 34% of the total (G + E + GE) variation. Two principal components explained 41.21% (PC1) and 26.35% (PC2) of GGE sum of squares. The Andean genotypes, ADP-102 (Jessica)- purple mottle, large seed, bush plant habit, released by Selian Agriculture Research Institution (ARI) in Tanzania; ADP-220 (G5625)- red, large seed, vine plant habit, from Central America; ADP-276 (G13654) - brown, medium seed, vine, from Mexico; and ADP-648 (‘Red Kloud’) large red kidney, with bush plant habit, were stable across environments and can be recommended for general adaptation across environments. An individual location for selection for yield stability was not identified, thus justifying the continued need for multiple test sites
Description of Baetao-Manteiga 41 and ‘Yunguilla’ superior Andean common beans for Tanzanian production environments
An international effort was initiated with the evaluation of a diverse set of largeseeded Andean common beans (Phaseolus vulgaris L.), the Andean Diversity Panel, in sub-Saharan Africa. Several entries in the panel have been selected for extensive characterization on the basis of high performance acrossmultiple location × year trials in Tanzania—conducted both on station and on farm. Baetao- Manteiga 41, tested asADP-190, has a commercialKablanketi (light purple speckled) seed type, and ‘Yunguilla’, tested as ADP-447, has a commercial Calima (red mottled) seed type. Both lines exhibited yield stability, vigorous growth under low fertility conditions, angular leaf spot resistance, andmoderate common bacterial blight resistance; Yunguilla also possessed rust resistance. These two lines were tested, selected, and characterized cooperatively by Sokoine University of Agriculture (SUA), the Tanzanian Agricultural Research Institute (TARI), the USDA-ARS, and the Agricultural Research Council (ARC) of South Africa, and in collaboration with local farmers in Tanzania
Unusual microwave response and bulk conductivity of very thin fese0.3te0.7 films as a function of temperature
Results of X-band microwave surface impedance measurements of FeSe1-xTex very
thin film are reported. The effective surface resistance shows appearance of
peak at T less and near Tc when plotted as function of temperature. The authors
suggests that the most well-reasoned explanation can be based on the idea of
the changing orientation of the microwave magnetic field at a SN phase
transition near the surface of a very thin film. The magnetic penetration depth
exhibits a power-law behavior of delta lambda proportional to T with an
exponent n = 2.4 at low temperatures, which is noticeably higher than in the
published results on FeSe1-xTexsingle crystal. However the temperature
dependence of the superfluid conductivity remains very different from the
behavior described by the BCS theory. Experimental results are fitted very well
by a two-gap model with delta1/kTc=0.43 and delta2/kTc=1.22,thus supporting
s(+-)- wave symmetry. The rapid increase of the quasiparticle scattering time
is obtained from the microwave impedance measurements.Comment: 13 pages, 13 figure
Unusual features in the nonlinear microwave surface impedance of Y-Ba-Cu-O thin films
Striking features have been found in the nonlinear microwave (8 GHz) surface
impedance of high-quality YBaCuO thin films with comparable
low power characteristics [ and ]. The surface resistance is found to increase,
decrease, or remain independent of the microwave field (up to 60 mT)
at different temperatures and for different samples. However, the surface
reactance always follows the same functional form. Mechanisms which may
be responsible for the observed variations in and are briefly
discussed.Comment: 4 pages, 4 figure
c-Axis Superfluid Response and Pseudogap in High-Tc Superconductors
To gain insight into the out-of-plane electrodynamics of high-
superconduct ors we have measured the absolute values and temperature
dependence of the c-a xis magnetic penetration depth for two
typical single layer high - cuprates, LaSrCuO and
HgBaCuO as a function o f doping. A distinct change in the
behaviour of is observed near 0. 20 holes/Cu, which is related to
the opening of the normal state pseudogap. The variation of with
doping is qualitatively similar to that of the in -plane component, , which suggests that the c-axis superfluid r esponse is mainly governed
by the superconducting condensation energy. The stron g doping dependence of
for p<0.20 provides an explanation for the discrepancies in the
literature.Comment: 4 pages, 2 figure
Systematic behaviour of the in-plane penetration depth in d-wave cuprates
We report the temperature T and oxygen concentration dependences of the
penetration depth of grain-aligned YBa_2Cu_3O_{7-\delta} with \delta= 0.0, 0.3
and 0.43. The values of the in-plane \lambda_{ab}(0) and out-of-plane
\lambda_{c}(0) penetration depths, the low temperature linear term in
\lambda_{ab}(T), and the ratio \lambda_{c}(0) /\lambda_{ab}(T) were found to
increase with increasing . The systematic changes of the linear term in
\lambda_{ab}(T) with T_c found here and in recent work on HgBa_2Ca_{n-1}
Cu_nO_{2n+2+\delta} (n = 1 and 3) are discussed.Comment: 4 pages, 4 figure
Penetration Depth Measurements in MgB_2: Evidence for Unconventional Superconductivity
We have measured the magnetic penetration depth of the recently discovered
binary superconductor MgB_2 using muon spin rotation and low field
-susceptibility. From the damping of the muon precession signal we find the
penetration depth at zero temperature is about 85nm. The low temperature
penetration depth shows a quadratic temperature dependence, indicating the
presence of nodes in the superconducting energy gap.Comment: 4 pages 3 figure
Pressure effect on the in-plane magnetic penetration depth in YBa_2Cu_4O_8
We report a study of the pressure effect (PE) on the in-plane magnetic field
penetration depth lambda_{ab} in YBa_2Cu_4O_8 by means of Meissner fraction
measurements. A pronounced PE on lambda_{ab}^{-2}(0) was observed with a
maximum relative shift of \Delta\lambda^{-2}_{ab}/\lambda^{-2}_{ab}= 44(3)% at
a pressure of 10.2 kbar. It arises from the pressure dependence of the
effective in-plane charge carrier mass and pressure induced charge carrier
transfer from the CuO chains to the superconducting CuO_2 planes. The present
results imply that the charge carriers in YBa_2Cu_4O_8 are coupled to the
lattice.Comment: 4pages 3 figure
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