576 research outputs found

    On the equation of state of a dense columnar liquid crystal

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    An accurate description of a columnar liquid crystal of hard disks at high packing fractions is presented using an improved free-volume theory. It is shown that the orientational entropy of the disks in the one-dimensional fluid direction leads to a different high-density scaling pressure compared to the prediction from traditional cell theory. Excellent quantitative agreement is found with recent Monte-Carlo simulation results for various thermodynamic and structural properties of the columnar state.Comment: 4 pages, 2 figures, to appear in Phys. Rev. Let

    Simulation of a semiflexible polymer in a narrow cylindrical pore

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    The probability that a randomly accelerated particle in two dimensions has not yet left a simply connected domain A{\cal A} after a time tt decays as e−E0te^{-E_0t} for long times. The same quantity E0E_0 also determines the confinement free energy per unit length Δf=kBT E0\Delta f=k_BT\thinspace E_0 of a semiflexible polymer in a narrow cylindrical pore with cross section A{\cal A}. From simulations of a randomly accelerated particle we estimate the universal amplitude of Δf\Delta f for both circular and rectangular cross sections.Comment: 10 pages, 2 eps figure

    Material line fluctuations slaved to bulk correlations in two-dimensional turbulence

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    Theoretical Physic

    Mean-field theory of the interaction of the magnesium ion with biopolymers: the case of lysozyme

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    Theoretical Physic

    A closed form for the electrostatic interaction between two rod-like charged objects

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    We have calculated the electrostatic interaction between two rod-like charged objects with arbitrary orientations in three dimensions. we obtained a closed form formula expressing the interaction energy in terms of the separation distance between the centers of the two rod-like objects, rr, their lengths (denoted by 2l12l_1 and 2l22l_2), and their relative orientations (indicated by θ\theta and ϕ\phi). When the objects have the same length (2l1=2l2=l2l_1=2l_2=l), for particular values of separations, i.e for r≤0.8lr\leq0.8 l, two types of minimum are appeared in the interaction energy with respect to θ\theta. By employing the closed form formula and introducing a scaled temperature tt, we have also studied the thermodynamic properties of a one dimensional system of rod-like charged objects. For different separation distances, the dependence of the specific heat of the system to the scaled temperature has been studied. It is found that for r<0.8lr<0.8 l, the specific heat has a maximum.Comment: 10 pages, 9 figures, 1 table, Accepted by J. Phys.: Condens. Matte

    Buckling instability for a charged and fluctuating semiflexible polymer

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    In this article we address the problem of Euler's buckling instability in a charged semi-flexible polymer that is under the action of a compressive force. We consider this instability as a phase transition and investigate the role of thermal fluctuations in the buckling critical force. By performing molecular dynamic simulations, we show that the critical force decreases when the temperature increases. Repulsive electrostatic interaction in the finite temperature is in competition with thermal fluctuations to increase the buckling threshold
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