Deuterium fractionation on interstellar grains studied with the direct master equation approach

We have studied deuterium fractionation on interstellar grains with the use of an exact method known as the direct master equation approach. We consider conditions pertinent to dense clouds at late times when the hydrogen is mostly in molecular form and a large portion of the gas-phase carbon has already been converted to carbon monoxide. Hydrogen, oxygen and deuterium atoms, as well as CO molecules, are allowed to accrete on to dust particles and react there to produce various stable molecules. The surface abundances, as well as the abundance ratios between deuterated and normal isotopomers, are compared with those calculated with the Monte Carlo approach. We find that the agreement between the Monte Carlo and the direct master equation methods can be made as close as desired. Compared with previous examples of the use of the direct master equation approach, our present method is much more efficient. It should now be possible to run large-scale gas-grain models in which the diffusive dust chemistry is handled `exactly'.Comment: 7 pages, 3 figure

From Prestellar to Protostellar Cores II. Time Dependence and Deuterium Fractionation

We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model with infalling fluid parcels. Spatial distributions of gas and ice-mantle species are calculated at the first-core stage, and at times after the birth of a protostar. Gas-phase methanol and methane are more abundant than CO at radii $r\lesssim 100$ AU in the first-core stage, but gradually decrease with time, while abundances of larger organic species increase. The warm-up phase, when complex organic molecules are efficiently formed, is longer-lived for those fluid parcels in-falling at later stages. The formation of unsaturated carbon chains (warm carbon-chain chemistry) is also more effective in later stages; C$^+$, which reacts with CH$_4$ to form carbon chains, increases in abundance as the envelope density decreases. The large organic molecules and carbon chains are strongly deuterated, mainly due to high D/H ratios in the parent molecules, determined in the cold phase. We also extend our model to simulate simply the chemistry in circumstellar disks, by suspending the 1-D infall of a fluid parcel at constant disk radii. The species CH$_3$OCH$_3$ and HCOOCH$_3$ increase in abundance in $10^4-10^5$ yr at the fixed warm temperature; both also have high D/H ratios.Comment: accepted to ApJ. 55 pages, 7 figures, 3 table

Electron attachment rates for PAH anions in the ISM and dark molecular clouds: dependence on their chemical properties

CONTEXT: The attachment of free electrons to polycondensed aromatic ring molecules (PAHs) is studied for the variety of these molecules with different numbers of condensed rings and over a broad range of electron temperatures, using a multichannel quantum scattering approach. The calculations of the relevant cross sections are used in turn to model the corresponding attachment rates for each of the systems under study, and these rates are parametrized as a function of temperature using a commonly employed expression for two-body processes in the interstellar medium (ISM). AIM: The scope of this work is to use first principles to establish the influence of chemical properties on the efficiency of the electron-attachment process for PAHs. METHODS: Quantum multichannel scattering methods are employed to generate the relevant cross sections, hence the attachment rates, using integral elastic cross sections computed over a broad range of relevant energies, from threshold up to 1000 K and linking the attachment to low-energy resonant collisions. RESULTS: The rates obtained for the present molecules are found to markedly vary within the test ensemble of the present work and to be lower than the earlier values used for the entire class of PAHs anions, when modelling their evolutions in ISM environments. The effects of such differences on the evolutions of chemical networks that include both PAH and PAH- species are analysed in some detail and related to previous calculations.Comment: accepted to be published on A&

Sarma phase in relativistic and non-relativistic systems

We investigate the stability of the Sarma phase in two-component fermion systems in three spatial dimensions. For this purpose we compare strongly-correlated systems with either relativistic or non-relativistic dispersion relation: relativistic quarks and mesons at finite isospin density and spin-imbalanced ultracold Fermi gases. Using a Functional Renormalization Group approach, we resolve fluctuation effects onto the corresponding phase diagrams beyond the mean-field approximation. We find that fluctuations induce a second order phase transition at zero temperature, and thus a Sarma phase, in the relativistic setup for large isospin chemical potential. This motivates the investigation of the cold atoms setup with comparable mean-field phase structure, where the Sarma phase could then be realized in experiment. However, for the non-relativistic system we find the stability region of the Sarma phase to be smaller than the one predicted from mean-field theory. It is limited to the BEC side of the phase diagram, and the unitary Fermi gas does not support a Sarma phase at zero temperature. Finally, we propose an ultracold quantum gas with four fermion species that has a good chance to realize a zero-temperature Sarma phase.Comment: version published in Phys.Lett.B; 10 pages, 5 figure

LIINUS/SERPIL: a design study for interferometric imaging spectroscopy at the LBT

LIINUS/SERPIL is a design study to augment LBTs interferometric beam combiner camera LINC-NIRVANA with imaging spectroscopy. The FWHM of the interferometric main beam at 1.5 micron will be about 10 mas, offering unique imaging and spectroscopic capabilities well beyond the angular resolution of current 8-10m telescopes. At 10 mas angular scale, e.g., one resolution element at the distance of the Galactic Center corresponds to the average diameter of the Pluto orbit (79 AU), hence the size of the solar system. Taking advantage of the LBT interferometric beam with an equivalent maximum diameter of 23 m, LIINUS/SERPIL is an ideal precursor instrument for (imaging) spectrographs at extremely large full aperture telescopes. LIINUS/SERPIL will be built upon the LINC-NIRVANA hardware and LIINUS/SERPIL could potentially be developed on a rather short timescale. The study investigates several concepts for the optical as well as for the mechanical design. We present the scientific promises of such an instrument together with the current status of the design study.Comment: 12 pages, SPIE conference proceeding, Orlando, 200

Electron-attachment rates for carbon-rich molecules in protoplanetary atmospheres: the role of chemical differences

The formation of anionic species in the interstellar medium from interaction of linear molecules containing carbon, nitrogen and hydrogen as atomic components (polyynes) with free electrons in the environment is modelled via a quantum treatment of the collision dynamics. The ensuing integral cross sections are employed to obtain the corresponding attachment rates over a broad range of temperatures for the electrons. The calculations unequivocally show that a parametrization form often employed for such rates yields a broad range of values that turn out to be specific for each molecular species considered, thus excluding using a unique set for the whole class of polyynes.Comment: accepted to be published on MNRA

Methanol in the sky with diamonds

The present of gas phase methanol in dense interstellar molecular clouds was established by radio detection of its rotational emission lines. However, the position, width, and profile of a absorption band near 1470 cm(exp -1) in the IR spectra of many dense molecular clouds strongly suggests that solid methanol is an important component of interstellar ices. In an attempt to better constrain the identification of 1470 cm(exp -1) feature, we began a program to search for other characteristic absorption bands of solid state methanol in the spectra of objects known to produce this band. One such feature is now identified in the spectra of several dense molecular clouds and its position, width, and profile fit well with those of laboratory H2O:CH3OH ices. Thus, the presence of methanol-bearing ices in space is confirmed