511 research outputs found

    High pressure transport study of non-Fermi liquid behaviour in U2Pt2In and U3Ni3Sn4

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    The strongly correlated metals U2Pt2In and U3Ni3Sn4 show pronounced non-Fermi liquid (NFL) phenomena at ambient pressure. Here we review single-crystal electrical resistivity measurements under pressure (p <= 1.8 GPa) conducted to investigate the stability of the NFL phase. For tetragonal U2Pt2In (I||a) we observe a rapid recovery of the Fermi-liquid T^2-term with pressure. The Fermi-liquid temperature varies as T_FL ~ p-p_c, where p_c= 0 is a critical pressure. The analysis within the magnetotransport theory of Rosch provides evidence for the location of U2Pt2In at a zero pressure antiferromagnetic quantum critical point (QCP). In the case of cubic U3Ni3Sn4 we find T_FL ~ (p-p_c)^1/2. The analysis provides evidence for an antiferromagnetic QCP in U3Ni3Sn4 at a negative pressure p_c= -0.04+-0.04 GPa.Comment: 6 pages (4 figures); to appear in Proc. of Int. Conf. PPHMF-IV (20-25 Oct. 2001, Santa Fe

    Resistivity of non-Fermi liquid U2Pt2In under pressure

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    Non-Fermi liquid behaviour in single-crystalline U2Pt2In has been studied by means of resistivity experiments (I||c) under hydrostatic pressure (P<1.5 GPa). At ambient pressure the resistivity rho(T) follows a power law rho~T^alpha with alpha~0.5. Upon applying pressure alpha increases. For P>1 GPa a minimum develops in rho(T). A study of the field dependence of the minimum confirms its magnetic origin. The ratio c/a is proposed as the effective control parameter, rather than the unit cell volume.Comment: 5 pages (incl. 2 figures), submitted to SCES'99, Nagan

    Methodology for Optimization of Polymer Blends Composition

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    The research of polymer blends, or alloys, has experienced enormous growth in size and sophistication in terms of its scientific base, technology and commercial development (Paul &amp; Bucknall, 2000). As a consequence two very important issues arise: the increased availability of new materials and the need for materials with better performance. Polymer blends are polymer systems originated from the physical mixture of two or more polymers and/or copolymers, without a high degree of chemical reactions between them. To be considered a blend, the compounds should have a concentration above 2% in mass of the second component (Hage &amp; Pessan, 2001; Ihm &amp; White, 1996). However, the commercial viability of new polymers has begun to become increasingly difficult, due to several factors. The advantages of polymer blends lie in the ability to combine existing polymers into new compositions obtaining in this way, materials with specific properties. This strategy allows for savings in research and development of new materials with equivalent properties, as well as versatility, simplicity, relatively low cost (Koning et al., 1998) and faster development time of new materials (Silva, 2011). Rossini (2005) mentions that economically and environmentally, a very viable alternative is to replace the recycling of pure polymers by mixtures of discarded materials. Mechanical recycling causes the breakdown of polymer chains, which impairs the properties of polymers. This degradation is directly proportional to the number of cycles of recycling. Therefore, the blend of two or more discarded polymers can be a realistic alternative, since it can result in materials with very interesting properties, at a low cost. Besides its inexpensiveness, this choice is also a smart solution to the reutilization of garbage. Postconsumption package disposal always occurs in a disorderly manner and without regard for the environment. The recycling process becomes increasingly more important and necessary to remediate environmental impact. According Pang et al. (2000) apud Marconcini &amp; Ruvolo Filho (2006) polyolefins such as high density polyethylene (HDPE), low density polyethylene (LDPE) and polypropylene (PP) and polyesters such as poly (ethylene terephthalate) (PET) are classes of thermoplastics that have been widely used in packaging and constitute a large part of post-consumer waste. The recycling of these materials and their mechanical characterization anticipating the possibility of a new cycle of life in the form of new products is challenging, although technologically and environmentally correct (Marconcini &amp; Ruvolo Filho, 2006). The polymer blends can be obtained basically in two ways (Rossini, 2005):  By dissolving the polymers in a good solvent, common to them, and subsequently letting the solvent evaporate; and  In a mixer where the working temperature is high enough to melt or mollify the polymeric components, without causing degradation of the same. According to Wessler (2007), the polymer blends may be miscible or immiscible. The miscibility is the most important property to be analyzed in a blend, given that all other system properties depend on the number of phases, their morphology and adhesion between them. The miscibility term is directly related to the solubility, i.e., a blend is miscible when the polymers dissolve in each other mutually (Silva, 2011). The immiscible between the various engineering polymers is a limiting factor for its production. Thus, it is necessary to use compatibilization agents for their production. Computational modeling has become increasingly popular. The main objective of models is to assist process optimization with minimal investment of time and resources for experimental work. Most techniques are classified into two main groups: physical models and statistical models as shown by Malinov &amp; Sha (2003). Statistical methods are chosen according to research objectives. There are several multivariate analysis methods for purposes quite different from each other. The desired value and quality of one or more product characteristics can be obtained via experiment analysis and DOE. These methods help determining optimal settings and controllable factors of a process such as: temperature, pressure, amount of reagents, operating time, etc.. When compared to the method of trial and error, DOE also allows a reduction of the number of required tests, and savings in time, labor and money. An important application of DOE is the optimization of experimental formulations as, for example, the composition of mixtures. The formulation development is a fundamental part of the food industry, chemicals, plastics, rubber, paints, medicines, and the like. In materials science, it is important to understand the correlation between material processing, microstructure and properties that enable the optimization of process parameters and compositions of materials to achieve the desired combination of properties, according Malinov &amp; Sha (2003). The problem presented here is to determine the fraction of each polymer blend component, and to determine the agent or, in some cases, an agents system, when it is necessary to use more than one compatibilizing agent. Thus, this text studies the effect of factors, for example, amount of polypropylene, additive type, and amount of additive in the composition of polymer blends, i.e., the optimal polymer blends formulation using factorial design

    High-pressure study of the non-Fermi liquid material U_2Pt_2In

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    The effect of hydrostatic pressure (p<= 1.8 GPa) on the non-Fermi liquid state of U_2Pt_2In is investigated by electrical resistivity measurements in the temperature interval 0.3-300 K. The experiments were carried out on single-crystals with the current along (I||c) and perpendicular (I||a) to the tetragonal axis. The pressure effect is strongly current-direction dependent. For I||a we observe a rapid recovery of the Fermi-liquid T^2-term with pressure. The low-temperature resistivity can be analysed satisfactorily within the magnetotransport theory of Rosch, which provides strong evidence for the location of U_2Pt_2In at an antiferromagnetic quantum critical point. For I||c the resistivity increases under pressure, indicating the enhancement of an additional scattering mechanism. In addition, we have measured the pressure dependence of the antiferromagnetic ordering temperature (T_N= 37.6 K) of the related compound U_2Pd_2In. A simple Doniach-type diagram for U_2Pt_2In and U_2Pd_2In under pressure is presented.Comment: 21 pages (including 5 figures); pdf forma

    Fabrication and electrical transport properties of embedded graphite microwires in a diamond matrix

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    Micrometer width and nanometer thick wires with different shapes were produced \approx 3~\upmum below the surface of a diamond crystal using a microbeam of He+^+ ions with 1.8~MeV energy. Initial samples are amorphous and after annealing at T1475T\approx 1475~K, the wires crystallized into a graphite-like structures, according to confocal Raman spectroscopy measurements. The electrical resistivity at room temperature is only one order of magnitude larger than the in-plane resistivity of highly oriented pyrolytic bulk graphite and shows a small resistivity ratio(ρ(2K)/ρ(315K)1.275\rho(2{\rm K})/\rho(315{\rm K}) \approx 1.275). A small negative magnetoresistance below T=200T=200~K was measured and can be well understood taking spin-dependent scattering processes into account. The used method provides the means to design and produce millimeter to micrometer sized conducting circuits with arbitrary shape embedded in a diamond matrix.Comment: 12 pages, 5 figures, to be published in Journal of Physics D: Applied Physics (Feb. 2017

    A Compact Sift-Based Strategy for Visual Information Retrieval in Large Image Databases

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    This paper applies the Standard Scale Invariant Feature Transform (S-SIFT) algorithm to accomplish the image descriptors of an eye region for a set of human eyes images from the UBIRIS database despite photometric transformations. The core assumption is that textured regions are locally planar and stationary. A descriptor with this type of invariance is sufficient to discern and describe a textured area regardless of the viewpoint and lighting in a perspective image, and it permits the identification of similar types of texture in a figure, such as an iris texture on an eye. It also enables to establish the correspondence between texture regions from distinct images acquired from different viewpoints (as, for example, two views of the front of a house), scales and/or subjected to linear transformations such as translation. Experiments have confirmed that the S-SIFT algorithm is a potent tool for a variety of problems in image identification

    A method to assess annual average renewable groundwater reserves for large regions in Spain

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    This paper proposes a method for assessing the groundwater renewable reserves of large regions for an average year, based on the integration of the recession curves for their basins springs or the natural base flow of their rivers. In this method, the hydrodynamic volume (or renewable reserves), were estimated from the baseflow equation. It was assumed that the flow was the same as the natural recharge, and that the recession coefficients were derived by the hydrogeological parameters and geometrical characteristics of aquifers, and adjusted to fit the recession curves at gauging stations. The method was applied to all the aquifers of Spain, which have a total groundwater renewable reserve of 86,895 hm3 four times the mean annual recharge. However, the distribution of these reserves is very variable; 18.6% of the country aquifers contain 94.7% of the entire reserve
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