Applications of Ideas from Random Matrix Theory to Step Distributions on "Misoriented" Surfaces

Arising as a fluctuation phenomenon, the equilibrium distribution of meandering steps with mean separation $$ on a "tilted" surface can be fruitfully analyzed using results from RMT. The set of step configurations in 2D can be mapped onto the world lines of spinless fermions in 1+1D using the Calogero-Sutherland model. The strength of the ("instantaneous", inverse-square) elastic repulsion between steps, in dimensionless form, is $\beta(\beta-2)/4$. The distribution of spacings $s$ between neighboring steps (analogous to the normalized spacings of energy levels) is well described by a {\it "generalized" Wigner surmise}: $p_{\beta}(0,s) \approx a s^{\beta}\exp(-b s^2)$. The value of $\beta$ is taken to best fit the data; typically $2 \le \beta \le 10$. The procedure is superior to conventional Gaussian and mean-field approaches, and progress is being made on formal justification. Furthermore, the theoretically simpler step-step distribution function can be measured and analyzed based on exact results. Formal results and applications to experiments on metals and semiconductors are summarized, along with open questions. (conference abstract)Comment: 7 pages, 2 figures; based on talk presented at TH-2002, UNESCO, Paris, July 2002; to be published in Ann. Henri Poincare

The evolution of radiation towards thermal equilibrium: A soluble model which illustrates the foundations of Statistical Mechanics

In 1916 Einstein introduced the first rules for a quantum theory of electromagnetic radiation, and he applied them to a model of matter in thermal equilibrium with radiation to derive Planck's black-body formula. Einstein's treatment is extended here to time-dependent stochastic variables, which leads to a master equation for the probability distribution that describes the irreversible approach of Einstein's model towards thermal equilibrium, and elucidates aspects of the foundation of statistical mechanics. An analytic solution of this equation is obtained in the Fokker-Planck approximation which is in excellent agreement with numerical results. At equilibrium, it is shown that the probability distribution is proportional to the total number of microstates for a given configuration, in accordance with Boltzmann's fundamental postulate of equal a priori probabilities for these states. While the counting of these configurations depends on particle statistics- Boltzmann, Bose-Einstein, or Fermi-Dirac - the corresponding probability is determined here by the dynamics which are embodied in the form of Einstein's quantum transition probabilities for the emission and absorption of radiation. In a special limit, it is shown that the photons in Einstein's model can act as a thermal bath for the evolution of the atoms towards the canonical equilibrium distribution of Gibbs. In this limit, the present model is mathematically equivalent to an extended version of the Ehrenfests' ``dog-flea'' model, which has been discussed recently by Ambegaokar and Clerk

Analytic Formulas for the Orientation Dependence of Step Stiffness and Line Tension: Key Ingredients for Numerical Modeling

We present explicit analytic, twice-differentiable expressions for the temperature-dependent anisotropic step line tension and step stiffness for the two principal surfaces of face-centered-cubic crystals, the square {001} and the hexagonal {111}. These expressions improve on simple expressions that are valid only for low temperatures and away from singular orientations. They are well suited for implementation into numerical methods such as finite-element simulation of step evolution.Comment: 10 pages; reformatted with revtex (with typos corrected) from version accepted by SIAM--Multiscale Modeling and Simulation on Nov. 21, 2006; greatly expanded introduction, several minor fixes (mostly stylistic

Cosmological Constant and Noncommutative Spacetime

We show that the cosmological constant appears as a Lagrange multiplier if nature is described by a canonical noncommutative spacetime. It is thus an arbitrary parameter unrelated to the action and thus to vacuum fluctuations. The noncommutative algebra restricts general coordinate transformations to four-volume preserving noncommutative coordinate transformations. The noncommutative gravitational action is thus an unimodular noncommutative gravity. We show that spacetime noncommutativity provides a very natural justification to an unimodular gravity solution to the cosmological problem. We obtain the right order of magnitude for the critical energy density of the universe if we assume that the scale for spacetime noncommutativity is the Planck scale.Comment: 7 page

Doubly Special Relativity with a minimum speed and the Uncertainty Principle

The present work aims to search for an implementation of a new symmetry in the space-time by introducing the idea of an invariant minimum speed scale ($V$). Such a lowest limit $V$, being unattainable by the particles, represents a fundamental and preferred reference frame connected to a universal background field (a vacuum energy) that breaks Lorentz symmetry. So there emerges a new principle of symmetry in the space-time at the subatomic level for very low energies close to the background frame ($v\approx V$), providing a fundamental understanding for the uncertainty principle, i.e., the uncertainty relations should emerge from the space-time with an invariant minimum speed.Comment: 10 pages, 8 figures, Correlated paper in: http://www.worldscientific.com/worldscinet/ijmpd?journalTabs=read. arXiv admin note: substantial text overlap with arXiv:physics/0702095, arXiv:0705.4315, arXiv:0709.1727, arXiv:0805.120

The Effects of Next-Nearest-Neighbor Interactions on the Orientation Dependence of Step Stiffness: Reconciling Theory with Experiment for Cu(001)

Within the solid-on-solid (SOS) approximation, we carry out a calculation of the orientational dependence of the step stiffness on a square lattice with nearest and next-nearest neighbor interactions. At low temperature our result reduces to a simple, transparent expression. The effect of the strongest trio (three-site, non pairwise) interaction can easily be incorporated by modifying the interpretation of the two pairwise energies. The work is motivated by a calculation based on nearest neighbors that underestimates the stiffness by a factor of 4 in directions away from close-packed directions, and a subsequent estimate of the stiffness in the two high-symmetry directions alone that suggested that inclusion of next-nearest-neighbor attractions could fully explain the discrepancy. As in these earlier papers, the discussion focuses on Cu(001).Comment: 8 pages, 3 figures, submitted to Phys. Rev.

A Possible Origin of Dark Energy

We discuss the possibility that the existence of dark energy may be due to the presence of a spin zero field $\phi(x)$, either elementary or composite. In the presence of other matter field, the transformation $\phi(x)\to \phi(x) +$ constant can generate a negative pressure, like the cosmological constant. In this picture, our universe can be thought as a very large bag, similar to the much smaller MIT bag model for a single nucleon.Comment: 4 pages, no figure, typos correcte

Rings sliding on a honeycomb network: Adsorption contours, interactions, and assembly of benzene on Cu(111)

Using a van der Waals density functional (vdW-DF) [Phys. Rev. Lett. 92, 246401 (2004)], we perform ab initio calculations for the adsorption energy of benzene (Bz) on Cu(111) as a function of lateral position and height. We find that the vdW-DF inclusion of nonlocal correlations (responsible for dispersive interactions) changes the relative stability of eight binding-position options and increases the binding energy by over an order of magnitude, achieving good agreement with experiment. The admolecules can move almost freely along a honeycomb web of "corridors" passing between fcc and hcp hollow sites via bridge sites. Our diffusion barriers (for dilute and two condensed adsorbate phases) are consistent with experimental observations. Further vdW-DF calculations suggest that the more compact (hexagonal) Bz-overlayer phase, with lattice constant a = 6.74 \AA, is due to direct Bz-Bz vdW attraction, which extends to ~8 \AA. We attribute the second, sparser hexagonal Bz phase, with a = 10.24 \AA, to indirect electronic interactions mediated by the metallic surface state on Cu(111). To support this claim, we use a formal Harris-functional approach to evaluate nonperturbationally the asymptotic form of this indirect interaction. Thus, we can account well for benzene self-organization on Cu(111).Comment: 13 pages, 7 figures, 3 tables, submitted for publication Accepted for publication in Phys. Rev. B. This version contains improved notation (with corresponding relabeling of figures), very small corrections to some tabulated values, and corrections concerning lattice lengths and subsequent discussion of commensurability of unit-cell dimension