19 research outputs found

    東大寺南大門仁王像の迎角 : 日本美術鑑賞メソッド開発研究

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    東大寺南大門仁王像はその巨像であることにおいて「迎角」を必要とし、見事に視覚効果を高めることに成功している。ここではその「迎角」が一定の傾斜を工夫したレリーフ的圧縮を取り入れた造形的解釈による効果の仕組みを生かしたものであると結論した。この成果を得て、「迎角」という視覚効果を生み出す造形的装置の対象領域に言及する

    Real-time observation of X-ray-induced intramolecular and interatomic electronic decay in CH2I2

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    The increasing availability of X-ray free-electron lasers (XFELs) has catalyzed the development of single-object structural determination and of structural dynamics tracking in realtime. Disentangling the molecular-level reactions triggered by the interaction with an XFEL pulse is a fundamental step towards developing such applications. Here we report real-time observations of XFEL-induced electronic decay via short-lived transient electronic states in the diiodomethane molecule, using a femtosecond near-infrared probe laser. We determine the lifetimes of the transient states populated during the XFEL-induced Auger cascades and find that multiply charged iodine ions are issued from short-lived (similar to 20 fs) transient states, whereas the singly charged ones originate from significantly longer-lived states (similar to 100 fs). We identify the mechanisms behind these different time scales: contrary to the short-lived transient states which relax by molecular Auger decay, the long-lived ones decay by an interatomic Coulombic decay between two iodine atoms, during the molecular fragmentation

    Biomimetic Synthesis of Iheyamine A from Spirocyclic Oxindoles

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    Association between head-and-neck cancers and active and passive cigarette smoking

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    Although there have been many reports on the toxicity of tobacco smoke, fewer studies have reported the relationship between the smoke and carcinogenesis of head-and-neck cancers. It is assumed that direct stimulations due to to-bacco smoke, such as chemical and mechanical stimulations, strongly influence the epithelium of the nasal cavity, paranasal sinuses, pharynx, and larynx. We investigated the influence of ac-tive and passive cigarette smoking on head-and-neck cancers. The subjects were 283 head-and-neck cancer patients examined at the otolaryn-gology department of Showa University North-ern Yokohama Hospital in a 9-year and 2-mont
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