improving the mechanical performance of cement composites by carbon nanotubes addition

Abstract: The addition of high performance nano materials like carbon fibers, carbon nanotubes, graphene etc. in the cement and concrete is gaining attention for achieving multifunctional composite materials with enhanced mechanical, physical and electrical properties. The nano-metric size range and the exceptionally high mechanical properties of carbon nanotubes possess very great potential for their utilization in cementitious composites for obtaining remarkable properties. Billions of ton of concrete is used every year in construction industry and its quantity may be reduced to a large extent only by improving the mechanical and durability properties. One way of achieving the enhanced mechanical properties of cement composite is the utilization of thoroughly dispersed carbon nanotubes in the composite matrix. In the present research, small fractions of multiwall carbon nanotube (MWCNTs) i.e. 0.05 and 0.10 wt.% of cement have been incorporated into the cement concrete and their influence on the mechanical properties of the resulting composites have been studied. It is a well-known fact that the uniform dispersion of the MWCNTs in the composite matrix holds the key for the performance improvement. Therefore, special attention was paid to this aspect and uniform dispersion of MWCNTs was achieved through the use of high energy sonication in the presence of modified acrylic based polymer (acting as a surfactant). The concrete specimens were tested in splitting tensile, flexure and compressive strength after 3, 7, 28 and 56 days of immersed water curing. It was observed that the addition of 0.05wt.% MWCNTs increased the splitting tensile strength by 20.58%, flexural strength by 26.29% and compressive strength by 15.60% as compared to the control mix at 28 days of curing. The strength enhancements for the concrete mixes containing MWCNTs may be regarded to the phenomenon of bridging, pinning and branching of the cracks at nano/micro level due to the presence of MWCNTs. Beside strength enhancements, it was also observed that the MWCNTs had tremendously enhanced the fracture energy and breaking strains of the concrete mixes as observed in three-point bending tests. The research concludes that very low amounts of MWCNTs incorporated in the cement concrete mixes improve their mechanical strengths and fracture behavior remarkably but the thorough dispersion of MWCNTs in the matrix have to be insured

Clay bricks prepared with sugarcane bagasse and rice husk ash – A sustainable solution

This study aims to characterize the clay bricks produced by the addition of the two agricultural waste materials i.e. sugarcane bagasse and rice husk ash. Disposing off these waste materials is a very challenging task and is a hazard to environment. The sugarcane bagasse and rice husk ash were collected locally from the cities of Peshawar and Wazirabad, respectively. These were mixed with the clay for brick manufacturing in three different proportions i.e. 5, 10 and 15% by weight of clay. Mechanical i.e. compressive strength and modulus of rupture and durability properties i.e. water absorption; freeze-thaw and sulphate resistance of these bricks were evaluated. Test results indicated that the sulphate attack resistance and efflorescence of clay bricks incorporating sugarcane bagasse and rice husk ash have been increased significantly. However, no significant effect on mechanical properties was observed. Furthermore, the additions of wastes have reduced the unit weight of bricks which decrease the overall weight of the structure leading to economical construction. Therefore, it can be concluded that the addition of waste materials in brick manufacturing can minimize the environmental burden leading towards more economical and sustainable construction

Development of Concrete Mixture for Spun-Cast Full-Scale Precast Concrete Pipes Incorporating Bundled Steel and Polypropylene Fibers

Spin casting is the oldest method of manufacturing precast concrete pipes among all existing methods. While improved concrete mixtures incorporating fibers for other methods of concrete pipe manufacturing, such as the vibration method and roller compaction method, have been developed, no such concrete mixture has yet been developed for spun-cast concrete pipes. This study was designed to explore the possibility of incorporating locally manufactured steel fibers and commercially available polypropylene fibers to develop an improved concrete mixture for use in the manufacturing of full-scale spun-cast concrete pipes. The used steel fibers were of two types, i.e., straight and bundled steel fibers, manufactured by cutting locally available long straight and bundled steel wires, respectively. Various dosages of steel fibers (i.e., 20, 30, 40, and 50 kg/m3) and polypropylene fibers (i.e., 5, 10, 15, and 20 kg/m3) were used in mono and hybrid (steel and polypropylene) forms. The properties in the fresh state and mechanical properties of the test mixtures were investigated. Full-scale spun-cast concrete pipes having a 450 mm internal diameter were manufactured and tested using the three-edge bearing test. The compressive strength of the mixtures was largely insensitive to the dosage of the fibers. The splitting tensile strength of all fiber-reinforced concrete mixtures was higher than that of the reference mixture without fibers, with a 24% increase recorded for the concrete mixture incorporating 50 kg/m3 of bundled steel fibers relative to the reference mixture with no fibers. The flexural performance of the fiber-reinforced concrete mixtures was superior to that of the reference mixture without fibers in terms of flexural strength, toughness, residual strength, and crack control, with up to 28% higher flexural strength relative to the reference mixture without fibers. The three-edge bearing tests on full-scale spun-cast pipes incorporating steel fibers showed that the use of fibers is a promising alternative to the traditional steel cage in spun-cast concrete pipes

Suitability Assessment of Marble, Glass Powders and Poly-Propylene Fibers for Improvement of Siwalik Clay

Raising of the Mangla Dam in Pakistan submerged about 15,780 acres of land, resulting in the relocation of 8020 inhabitants to a newly developed town named New City. The new site, consisting of 1300 acres, is in the sub-tropical zone and comprises badland topography. The parent soils (Siwalik clay) pose infrastructure serviceability issues, causing immense loss to property. The study aims to improve the properties of Siwalik clay (base soil) using industrial wastes like marble and glass powders (5 to 20%) and polypropylene fibers (0.25 to 1.25%) as modifiers. Laboratory tests including grain size distribution, Atterberg limits, standard Proctor compaction, unconfined compression, indirect tensile strength, swell potential, and California bearing ratio were conducted on the control and modified clay samples. The results showed that unconfined compressive strength (UCS) and swelling strains (SS) were increased by 43% and 8% at 1.57 kPa pressure with 15% replacement of marble powder. However, the addition of the 20% glass powder and 0.5% polypropylene fibers not only improved UCS by 110% and 39%, but also reduced SS by 27% and 86%, respectively. The capital construction cost of 1 km long road with modified subgrade using 15% glass powder was reduced by 16% whereas it increased for marble powder and polypropylene fibers by 22% and 17%, respectively. All modifiers had very low hazard to adjoining aqueous environment. Conclusively, glass powder and polypropylene fibers can be used as environmentally-friendly soil improvement modifiers, leading towards sustainable solutions of the serviceability problems

Development of unified elastic modulus model of natural and recycled aggregate concrete for structural applications

The development of design guidelines for structural recycled aggregate concrete (RAC) is hindered by the absence of a unified elastic modulus model focusing on the properties of diversely-sourced coarse recycled aggregates (CRA). This study develops a unified elastic modulus model of RAC and natural aggregate concrete (NAC) considering four inputs: CRA dosage, coarse aggregates/cement content, effective water/cement content, and coarse aggregates water absorption. Ten machine-learning algorithms are evaluated through various statistical approaches to explore the most suitable algorithm by establishing a database from 72 studies (i.e., 633 test results). Based on the results, CRA properties are significant for the elastic modulus prediction of RAC. All machine learning models perform better than existing models, and GBA, BRA, and XGBA models are the most suitable algorithms. The pioneering unified design equations proposed in this work can efficiently predict the elastic modulus of RAC and NAC, leading toward sustainable and cleaner concrete design

Evaluation of the Impact of Fines on the Performance of Sub-Base Materials

The study aims to evaluate the change in the behavior of sub-base materials being used in road pavements through blending fines of different types in different amounts. Fines are added in aggregate samples as part of gradations proposed by the American Association for State and Highway Transportation Official (AASHTO). Composite samples conforming to AASHTO gradations B and C were prepared by mixing coarse aggregates in varying proportions, ranging from 0 to 15%. Laboratory tests—including aggregate quality tests (abrasion test, flakiness index and elongation Index), physical tests (particle size analysis and specific gravity), and strength test (modified Proctor, California bearing ratio, and permeability test)—were performed on the control as well as the modified samples. It was observed that the material with 0% fines yielded the highest CBR values (greater than 98%) and coefficient of permeability of 4.4 × 10−4 cm/s. However, with the increasing of the fines up to 15%, a substantial reduction in CBR value up to 10% and coefficient of permeability to 1.62 × 10−7 cm/s was noticed. Based on these results, the modulus of rigidity (MR) and the corresponding structural numbers were determined for each layer. Conclusively, the required thickness of the base course was increased from 11 cm for the samples with 0% fines to 24 cm (118%) for the samples with the addition of 15% fines according to the AASHTO Design method

Bond Stress Behavior of a Steel Reinforcing Bar Embedded in Geopolymer Concrete Incorporating Natural and Recycled Aggregates

The rise in greenhouse gases, particularly carbon dioxide (CO2) emissions, in the atmosphere is one of the major causes of global warming and climate change. The production of ordinary Portland cement (OPC) emits harmful CO2 gases, which contribute to sporadic heatwaves, rapid melting of glaciers, flash flooding, and food shortages. To address global warming and climate change challenges, this research study explores the use of a cement-less recycled aggregate concrete, a sustainable approach for future constructions. This study uses fly ash, an industrial waste of coal power plants, as a 100% substitute for OPC. Moreover, this research study also uses recycled coarse aggregates (RCAs) as a partial to complete replacement for natural coarse aggregates (NCAs) to preserve natural resources for future generations. In this research investigation, a total of 60 pull-out specimens were prepared to investigate the influence of steel bar diameter (9.5 mm, 12.7 mm, and 19.1 mm), bar embedment length, db (4db and 6db), and percentage replacements of NCA with RCA (25%, 50%, 75%, and 100%) on the bond stress behavior of cement-less RA concrete. The test results exhibited that the bond stress of cement-less RCA concrete decreased by 6% with increasing steel bar diameter. Moreover, the bond stress decreased by 5.5% with increasing bar embedment length. Furthermore, the bond stress decreased by 7.6%, 7%, 8.8%, and 20.4%, respectively, with increasing percentage replacements (25%, 50%, 75%, and 100%) of NCA with RCA. An empirical model was developed correlating the bond strength to the mean compressive strength of cement-less RCA concrete, which matched well with the experimental test results and predictions of the CEB-FIP model for OPC. The CRAC mixes exhibited higher costs but significantly lower embodied CO2 emissions than OPC concrete