2,847 research outputs found
Non-monotonous crossover between capillary condensation and interface localisation/delocalisation transition in binary polymer blends
Within self-consistent field theory we study the phase behaviour of a
symmetric binary AB polymer blend confined into a thin film. The film surfaces
interact with the monomers via short range potentials. One surface attracts the
A component and the corresponding semi-infinite system exhibits a first order
wetting transition. The surface interaction of the opposite surface is varied
as to study the crossover from capillary condensation for symmetric surface
fields to the interface localisation/delocalisation transition for
antisymmetric surface fields. In the former case the phase diagram has a single
critical point close to the bulk critical point. In the latter case the phase
diagram exhibits two critical points which correspond to the prewetting
critical points of the semi-infinite system. The crossover between these
qualitatively different limiting behaviours occurs gradually, however, the
critical temperature and the critical composition exhibit a non-monotonic
dependence on the surface field.Comment: to appear in Europhys.Let
Deviations from the mean field predictions for the phase behaviour of random copolymers melts
We investigate the phase behaviour of random copolymers melts via large scale
Monte Carlo simulations. We observe macrophase separation into A and B--rich
phases as predicted by mean field theory only for systems with a very large
correlation lambda of blocks along the polymer chains, far away from the
Lifshitz point. For smaller values of lambda, we find that a locally
segregated, disordered microemulsion--like structure gradually forms as the
temperature decreases. As we increase the number of blocks in the polymers, the
region of macrophase separation further shrinks. The results of our Monte Carlo
simulation are in agreement with a Ginzburg criterium, which suggests that mean
field theory becomes worse as the number of blocks in polymers increases.Comment: 6 pages, 4 figures, Late
A Study on the Modeling and Simulation of Bio-inspired Hedgehog Spines Structures for More Efficient Use Digital Manufacturing Processes
Direct digital manufacture and additive manufacture have allowed designers the ability to design components without the design limitations witnessed in subtractive manufacturing process routes. In particular, designers can now design parts that fully utilize material usage resulting in a more sustainable and environmentally friendly application of manufacturing technology. Within this context, designing and manufacturing bio-inspired components have the potential to increase both component functionality and optimize material usage. One such area of biomimicry with advantageous strength-to-weight ratio can be found in hedgehog spines. Within this study, hedgehog spines were redesigned to facilitate production through additive manufacture. In addition, with the use of finite element analysis to quantify the resulting compressive characteristics, the optimal internal geometry and septa spacing were determined. Also, a design of experiments study was conducted to determine which design features have the greatest influence on the resulting stress in the spine. The analysis concluded that the combination of longitudinal stiffeners and equally spaced septa give the spine its superior compressive strength
Theoretical Analysis of the "Double-q" Magnetic Structure of CeAl2
A model involving competing short-range isotropic Heisenberg interactions is
developed to explain the "double-q" magnetic structure of CeAl. For
suitably chosen interactions, terms in the Landau expansion quadratic in the
order parameters explain the condensation of incommensurate order at
wavevectors in the star of (1/2 , 1/2 , 1/2), where
is the cubic lattice constant. We show that the fourth order terms in the
Landau expansion lead to the formation of the so-called "double-q" magnetic
structure in which long-range order develops simultaneously at two
symmetry-related wavevectors, in striking agreement with the magnetic structure
determinations. Based on the value of the ordering temperature and of the
Curie-Weiss of the susceptibility, we estimate that the nearest
neighbor interaction is ferromagnetic, with K and the
next-nearest neighbor interaction is antiferromagnetic with K.
We also briefly comment on the analogous phenomenon seen in the similar system
TmS.Comment: 22 pages, 6 figure
Degeneracy Algorithm for Random Magnets
It has been known for a long time that the ground state problem of random
magnets, e.g. random field Ising model (RFIM), can be mapped onto the
max-flow/min-cut problem of transportation networks. I build on this approach,
relying on the concept of residual graph, and design an algorithm that I prove
to be exact for finding all the minimum cuts, i.e. the ground state degeneracy
of these systems. I demonstrate that this algorithm is also relevant for the
study of the ground state properties of the dilute Ising antiferromagnet in a
constant field (DAFF) and interfaces in random bond magnets.Comment: 17 pages(Revtex), 8 Postscript figures(5color) to appear in Phys.
Rev. E 58, December 1st (1998
Verbal autopsy of 80,000 adult deaths in Tamilnadu, South India
BACKGROUND: Registration of the fact of death is almost complete in the city of Chennai and not so in the rural Villupuram district in Tamilnadu, India. The cause of death is often inadequately recorded on the death certificate in developing countries like India. A special verbal autopsy (VA) study of 48 000 adult (aged ≥ 25 yrs) deaths in the city of Chennai (urban) during 1995–97 and 32 000 in rural Villupuram during 1997–98 was conducted to arrive at the probable underlying cause of death to estimate cause specific mortality. METHODS: A ten day training on writing verbal autopsy (VA) report for adult deaths was given to non-medical graduates with at least 15 years of formal education. They interviewed surviving spouse/close associates of the deceased to write a verbal autopsy report in local language (Tamil) on the complaints, symptoms, signs, duration and treatment details of illness prior to death. Each report was reviewed centrally by two physicians independently. Random re-interviewing of 5% of the VA reports was done to check the reliability and reproducibility of the VA report. The validity of VA diagnosis was assessed only for cancer deaths. RESULTS: Verbal autopsy reduced the proportion of deaths attributed to unspecified and unknown causes from 54% to 23% (p < 0.0001) in urban and from 41% to 26% (p < 0.0001) in rural areas in Tamilnadu for adult deaths (≥ 25). The sensitivity of VA to identify cancer was 95% in the age group 25–69. CONCLUSION: A ten day training programme to write verbal autopsy report with adequate feed back sessions and random sampling of 5% of the verbal autopsy reports for re-interview worked very well in Tamilnadu, to arrive at the probable underlying cause of death reliably for deaths in early adult life or middle age (25–69 years) and less reliably for older ages (70+). Thus VA is practicable for deaths in early adult life or middle age and is of more limited value in old age
The second and third Sonine coefficients of a freely cooling granular gas revisited
In its simplest statistical-mechanical description, a granular fluid can be
modeled as composed of smooth inelastic hard spheres (with a constant
coefficient of normal restitution ) whose velocity distribution
function obeys the Enskog-Boltzmann equation. The basic state of a granular
fluid is the homogeneous cooling state, characterized by a homogeneous,
isotropic, and stationary distribution of scaled velocities, .
The behavior of in the domain of thermal velocities ()
can be characterized by the two first non-trivial coefficients ( and
) of an expansion in Sonine polynomials. The main goals of this paper are
to review some of the previous efforts made to estimate (and measure in
computer simulations) the -dependence of and , to report new
computer simulations results of and for two-dimensional systems,
and to investigate the possibility of proposing theoretical estimates of
and with an optimal compromise between simplicity and accuracy.Comment: 12 pages, 5 figures; v2: minor change
Whirling Hexagons and Defect Chaos in Hexagonal Non-Boussinesq Convection
We study hexagon patterns in non-Boussinesq convection of a thin rotating
layer of water. For realistic parameters and boundary conditions we identify
various linear instabilities of the pattern. We focus on the dynamics arising
from an oscillatory side-band instability that leads to a spatially disordered
chaotic state characterized by oscillating (whirling) hexagons. Using
triangulation we obtain the distribution functions for the number of pentagonal
and heptagonal convection cells. In contrast to the results found for defect
chaos in the complex Ginzburg-Landau equation and in inclined-layer convection,
the distribution functions can show deviations from a squared Poisson
distribution that suggest non-trivial correlations between the defects.Comment: 4 mpg-movies are available at
http://www.esam.northwestern.edu/~riecke/lit/lit.html submitted to New J.
Physic
The equation of state of solid nickel aluminide
The pressure-volume-temperature equation of state of the intermetallic
compound NiAl was calculated theoretically, and compared with experimental
measurements. Electron ground states were calculated for NiAl in the CsCl
structure, using density functional theory, and were used to predict the cold
compression curve and the density of phonon states. The Rose form of
compression curve was found to reproduce the ab initio calculations well in
compression but exhibited significant deviations in expansion. A
thermodynamically-complete equation of state was constructed for NiAl. Shock
waves were induced in crystals of NiAl by the impact of laser-launched Cu
flyers and by launching NiAl flyers into transparent windows of known
properties. The TRIDENT laser was used to accelerate the flyers to speeds
between 100 and 600m/s. Point and line-imaging laser Doppler velocimetry was
used to measure the acceleration of the flyer and the surface velocity history
of the target. The velocity histories were used to deduce the stress state, and
hence states on the principal Hugoniot and the flow stress. Flyers and targets
were recovered from most experiments. The effect of elasticity and plastic flow
in the sample and window was assessed. The ambient isotherm reproduced static
compression data very well, and the predicted Hugoniot was consistent with
shock compression data
Electrical conduction by interface states in semiconductor heterojunctions
peer reviewedaudience: researcher, professionalElectrical conduction in semiconductor heterojunctions containing defect states in the interface region is studied. As the classical drift-diffusion mechanism cannot in any case explain electrical conduction in semiconductor heterojunctions, tunnelling involving interface states is often considered as a possible conduction path. A theoretical treatment is made where defect states in the interface region with a continuous energy distribution are included. Electrical conduction through this defect band then allows the transit of electrons from the conduction band of one semiconductor to the valence band of the second component. The analysis is initiated by electrical measurements on n-CdS/p-CdTe heterojunctions obtained by chemical vapour deposition of CdS on (111) oriented CdTe single crystals, for which current--voltage and capacitance--frequency results are shown. The theoretical analysis is based on the numerical resolution of Poisson's equation and the continuity equations of electrons, holes and defect states, where a current component corresponding to the defect band conduction is explicitly included. Comparison with the experimental curves shows that this formalism yields an efficient tool to model the conduction process through the interface region. It also allows us to determine critical values of the physical parameters when a particular step in the conduction mechanism becomes dominant
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