Positron-molecule bound states and positive ion production

The interaction was studied of low energy positrons with large molecules such as alkanes. These data provide evidencce for the existence of long lived resonances and bound states of positrons with neutral molecules. The formation process and the nature of these resonances are discussed. The positive ions produced when a positron annihilates with an electron in one of these resonances were observed and this positive ion formation process is discussed. A review is presented of the current state of the understanding of these positron-molecule resonances and the resulting positive ion formation. A number of outstanding issues in this area is also discussed

The Buffer-Gas Positron Accumulator and Resonances in Positron-Molecule Interactions

This is a personal account of the development of our buffer-gas positron trap and the new generation of cold beams that these traps enabled. Dick Drachman provided much appreciated advice to us from the time we started the project. The physics underlying trap operation is related to resonances (or apparent resonances) in positron-molecule interactions. Amusingly, experiments enabled by the trap allowed us to understand these processes. The positron-resonance "box score" to date is one resounding "yes," namely vibrational Feshbach resonances in positron annihilation on hydrocarbons; a "probably" for positron-impact electronic excitation of CO and NZ;an d a "maybe" for vibrational excitation of selected molecules. Two of these processes enabled the efficient operation of the trap, and one almost killed it in infancy. We conclude with a brief overview of further applications of the trapping technology discussed here, such as "massive" positron storage and beams with meV energy resolution

Vibrational Feshbach Resonances Mediated by Nondipole Positron-Molecule Interactions

Measurements of energy-resolved positron-molecule annihilation show the existence of positron binding and vibrational Feshbach resonances. The existing theory describes this phenomenon successfully for the case of infrared-active vibrational modes which allow dipole coupling between the incident positron and the vibrational motion. Presented here are measurements of positron-molecule annihilation made using a recently developed cryogenic positron beam capable of significantly improved energy resolution. The results provide evidence of resonances associated with infrared-inactive vibrational modes, indicating that positron-molecule bound states may be populated by nondipole interactions. The anticipated ingredients for a theoretical description of such interactions are discussed.Comment: 5 pages, 2 figures, Phys. Rev. Lett. (in press

Mode coupling and multiquantum vibrational excitations in Feshbach-resonant positron annihilation in molecules

The dominant mechanism of low-energy positron annihilation in polyatomic molecules is through positron capture in vibrational Feshbach resonances (VFR). In this paper we investigate theoretically the effect of anharmonic terms in the vibrational Hamiltonian on the positron annihilation rates. Such interactions enable positron capture in VFRs associated with multiquantum vibrational excitations, leading to enhanced annihilation. Mode coupling can also lead to faster depopulation of VFRs, thereby reducing their contribution to the annihlation rates. To analyze this complex picture, we use coupled-cluster methods to calculate the anharmonic vibrational spectra and dipole transition amplitudes for chloroform, chloroform-$d_1$, 1,1-dichloroethylene, and methanol, and use these data to compute positron resonant annihilation rates for these molecules. Theoretical predictions are compared with the annihilation rates measured as a function of incident positron energy. The results demonstrate the importance of mode coupling in both enhancement and suppression of the VFR. There is also experimental evidence for the direct excitation of multimode VFR. Their contribution is analyzed using a statistical approach, with an outlook towards more accurate treatment of this phenomenon.Comment: 16 pages, 10 figures, submitted to Phys. Rev.

Configuration Interaction calculations of positron binding to Be(3Po)

The Configuration Interaction method is applied to investigate the possibility of positron binding to the metastable beryllium (1s^22s2p 3Po) state. The largest calculation obtained an estimated energy that was unstable by 0.00014 Hartree with respect to the Ps + Be^+(2s) lowest dissociation channel. It is likely that positron binding to parent states with non-zero angular momentum is inhibited by centrifugal barriers.Comment: 12 pages, 2 figures, Elsevier tex format, In press Nucl.Instrum.Meth.Phys.Res.B positron issu

Calculations of liquid helium and neon VUV emission spectra, self-absorption and scattering for a neutrino detector

To evaluate the feasibility of the recently proposed detection scheme of low energy neutrinos released from the Sun and supernovae called CLEAN, Cryogenic Low Energy Astrophysics with Noble Gases, which relies on the transparency of noble-gas cryogenic liquids to VUV radiation produced by neutrinos, we analyze theoretically VUV emission, self-absorption, and scattering of liquid helium and neon, primary candidates for CLEAN. Owing to strong repulsion of noble-gas atoms in the ground states at the equilibrium distance of the relevant excited state, the emission spectrum is substantially shifted from the absorption spectrum, and in principle the absorption is expected very small, allowing building large detectors. Our analysis, however, shows that the self-absorption and Rayleigh scattering are comparable to the size of the proposed detector. Our theoretical emission spectra are found in agreement with experimental observations although some deviation exists due to binary-interaction approximation, and our ab initio Rayleigh scattering lengths are found in agreement with other calculations based on the extrapolation of experimental refraction indices. The absorption process can result in either re-emission, which conserves the number of photons but delays their escape from the liquid, or in non-radiative quenching

Are Antiprotons Forever?

Up to one million antiprotons from a single LEAR spill have been captured in a large Penning trap. Surprisingly, when the antiprotons are cooled to energies significantly below 1 eV, the annihilation rate falls below background. Thus, very long storage times for antiprotons have been demonstrated in the trap, even at the compromised vacuum conditions imposed by the experimental set up. The significance for future ultra-low energy experiments, including portable antiproton traps, is discussed.Comment: 12 pages, latex; 4 figures, uufiled. Slightly expanded discussion of expected energy dependence of annihilation cross section and rate, and of estimates of trap pressure, plus minor text improvement