Colorants Detected by HPLC-PDA in Textiles from 13th Century Lieto Ristinpelto, Finland

Organic colorants of textiles found in the female burial of Lieto Ristinpelto, SW Finland, were analyzed by HPLC-PDA. The textiles’ visible colors varied from different brownish shades to blueish, greenish, and reddish hues. The aim of the chromatographic analysis was to deepen the current understandings of the dyes used in Finland at the transition between the 12th and 13th centuries AD, i.e., at the beginning of the local Medieval period, and to contribute important new information about dyes and clothing from this less-known period of textile history of Finland. The textile finds consisted of a bronze spiral ornamented shawl, an apron tied at the waist, two tablet-woven bands, and a diagonally plaited band with plaited tassels. A unique find was a textile possibly made using the sprang technique. Other textile finds were an orange wool tabby and twill fragments. Analysis of thirty samples from fourteen different textiles indicated that woad colorants were present in most samples, accompanied with lichen compounds, and dyer’s madder was in two visually orange fragments. The visually reddish samples contained luteolin, but no red colorants

Wide-angle X-ray scattering studies on contemporary and ancient bast fibres used in textiles - ultrastructural studies on stinging nettle

Stinging nettle (Urtica dioica) is a potential source material for industrial applications. However, systematic research on the ultrastructural properties of nettle fibres is lacking. Determining the ultrastructure of nettle and the other bast fibres also provides new insights into the studies of archaeological fibres and their usage. In this study, the nanostructure of modern and ancient nettle samples was studied using wide-angle X-ray scattering (WAXS) and compared to other bast fibres. The culturo-historical fibre samples consisted of nettle, flax, and hemp from White Karelian textiles collected 1894 as well as of 800-900-year-old archaeological textile fragments from Ravattula Ristimaki burial site, Finland. Using WAXS, the average cellulose crystallite widths, relative crystallinities and orientational order (including microfibril angle for the modern fibres) were determined and compared. The results also revealed the suitability of the WAXS analysis for fibre identification. The crystallite widths were of the similar size for all modern fibres (3.4-4.8 nm). Subtle differences in the relative crystallinities in descending order (from flax to nettle, and finally hemp) were observed. Also, subtle differences in the mean MFAs were observed (10 +/- 1 degrees for flax, 12 +/- 1 degrees for nettle, and 14 +/- 1 degrees for hemp). For the culturo-historical fibres, the values for crystallite widths and relative crystallinities were larger compared to the corresponding modern references. In addition, features due to the presence of non-cellulosic, crystalline substances (e.g., calcium oxalates) were detected in the WAXS patterns of all the modern nettle fibres. These features could potentially be used as a tool for identification purposes.Peer reviewe

Examining the White Karelian textile tradition of the late nineteenth century – focus on plant fibers

Collection SU4522 in the Finno-Ugric Collections of the National Museum of Finland consists of 143 items, mainly textiles from nineteenth-century White Karelia, now part of the current Russia. Forty-one linen textiles were chosen for closer examination, with the aim of evaluating the area's textile culture and identifying the materials using microscopic methods. Flax, hemp and nettle have all been traditional materials for clothing in northern Europe. Additionally, cotton became established in the region during the nineteenth century. Previous research lacked such a deep examination of the textile materials used, leaving room for speculation. Stinging nettle has not been shown before to have been used as a textile material in the Karelian area. Our results show that it appeared commonly in ratsina-shirts and kaspaikka-towels. Against the consensus hemp was rare and appeared only in one of the items. The results are mirrored by concurrent pictorial and written material from I. K. Inha who visited the region in 1894 and collected most of the items in the collection. White Karelian textile traditions from clothing to fabrics, weaving, spinning and fiber production are discussed in the article. Nevertheless, questions concerning the origins of the materials and the effects of the peddling tradition would need further research.Peer reviewe

Nikolaus Rungius : Lifestyle and Status of an Early Seventeenth-Century Northern Finnish Vicar

Vicar Nikolaus Rungius's (ca. 1560-1629) mummified remains have been the subject of research that has provided a wide variety of information on his life. This article examines the ways Rungius's health and lifestyle highlight his status as a vicar, and this status is visible in his burial and funerary clothing. He was a relatively large man for his time. CT scans even include indications of certain conditions related to being overweight. Likewise, stable-isotope analyses of his nail keratin support the hypothesis that he was consuming a rather heavy, protein-rich diet. Given his status as the vicar of Kemi parish in northern Finland, he likely made sumptuous use of the rich local natural resources of fish, game, and domestic animals as part of his regular diet. In addition to his diet and health, the vicar's high-quality clothes, while fragmentary, also open an avenue to extend the exploration of his social status and wealth.Peer reviewe

Seeking Nettle Textiles – Utilizing a Combination of Microscopic Methods for Fibre Identification

Bast fibres have been commonly used as a textile material in Northern Europe since Neolithic times. However, the process of identifying the different species has been problematic, and many important questions related to their cultural history are still unanswered. For example, a modified Herzog test and the presence of calcium oxalate crystals have both been used in identification. In order to generate more reliable results, further research and advancement in multi-methodological methods is required. This paper introduces a combination of methods which can be used to identify and distinguish flax (Linum usitatissimum), hemp (Cannabis sativa), and stinging nettle (Urtica dioica). The research material consisted of reference fibres and 25 fibre samples obtained from 12 textiles assumed to be made of nettle. The textiles were from the Finno-Ugric and Historical Collections of The National Museum of Finland. The fibre samples were studied by observing the surface characteristics and cross sections with transmitted light microscopy, and by using a modified Herzog test with polarized light, in order to identify the distinguishable features in their morphological structures. The study showed that five out of 25 samples were cotton, 16 nettle, one flax, and one hemp. Findings from two samples were inconsistent. The results show that it is possible to distinguish common north European bast fibres from each other by using a combination of microscopic methods. Furthermore, by utilizing these combined methods, new and more reliable information could be obtained from historical ethnographic textiles, which creates new vistas for the interpretation of their cultural history.Peer reviewe

Colorants Detected by HPLC-PDA in Textiles from 13th Century Lieto Ristinpelto, Finland

Organic colorants of textiles found in the female burial of Lieto Ristinpelto, SW Finland, were analyzed by HPLC-PDA. The textiles’ visible colors varied from different brownish shades to blueish, greenish, and reddish hues. The aim of the chromatographic analysis was to deepen the current understandings of the dyes used in Finland at the transition between the 12th and 13th centuries AD, i.e., at the beginning of the local Medieval period, and to contribute important new information about dyes and clothing from this less-known period of textile history of Finland. The textile finds consisted of a bronze spiral ornamented shawl, an apron tied at the waist, two tablet-woven bands, and a diagonally plaited band with plaited tassels. A unique find was a textile possibly made using the sprang technique. Other textile finds were an orange wool tabby and twill fragments. Analysis of thirty samples from fourteen different textiles indicated that woad colorants were present in most samples, accompanied with lichen compounds, and dyer’s madder was in two visually orange fragments. The visually reddish samples contained luteolin, but no red colorants

Research methods for heritage cotton fibres: case studies from archaeological and historical finds in a Finnish context

Abstract Cotton (Gossypium species) was used as textile fibre already in the early Indus culture, and since then it has been cultivated in Tropical and Subtropical regions around the whole planet. The species G. hirsutum is nowadays the dominant cotton crop with more than 90% of the world market, while G. barbadense, G. herbaceum and G. arboreum combined, the other cultivated species of Gossypium genus total a minor part of world’s cotton production. Even in places where cotton was not cultivated, it could be an important trade item and income source for local textile centres, with the imported raw cotton lint being spun, woven and for some part exported from such sites around the globe. This all occurred far away from Finland, until changes brought by the development of long-distance trade and the Industrial Revolution. Based on archaeological finds, cotton as a textile material reached Finland relatively late, in the early Middle Ages. The article focuses on the problematic nature of identifying these cotton finds: whereas modern cotton fibres are easy to identify, the archaeological finds can at first sight be confused with bast or un-degummed silk fibres. This issue will be approached through reviewing recent Finnish cotton finds in heritage textiles. Additionally, the article examines whether the four cultivated cotton species could be differentiated using both classical and newly developed fibre identification methods, such as optical microscopy methods, a Scanning Electron Microscope (SEM), Fourier-transform infrared spectroscopy (FTIR) or Wide-Angle X-ray Scattering (WAXS)

Research methods for heritage cotton fibres:case studies from archaeological and historical finds in a Finnish context

Abstract Cotton (Gossypium species) was used as textile fibre already in the early Indus culture, and since then it has been cultivated in Tropical and Subtropical regions around the whole planet. The species G. hirsutum is nowadays the dominant cotton crop with more than 90% of the world market, while G. barbadense, G. herbaceum and G. arboreum combined, the other cultivated species of Gossypium genus total a minor part of world’s cotton production. Even in places where cotton was not cultivated, it could be an important trade item and income source for local textile centres, with the imported raw cotton lint being spun, woven and for some part exported from such sites around the globe. This all occurred far away from Finland, until changes brought by the development of long-distance trade and the Industrial Revolution. Based on archaeological finds, cotton as a textile material reached Finland relatively late, in the early Middle Ages. The article focuses on the problematic nature of identifying these cotton finds: whereas modern cotton fibres are easy to identify, the archaeological finds can at first sight be confused with bast or un-degummed silk fibres. This issue will be approached through reviewing recent Finnish cotton finds in heritage textiles. Additionally, the article examines whether the four cultivated cotton species could be differentiated using both classical and newly developed fibre identification methods, such as optical microscopy methods, a Scanning Electron Microscope (SEM), Fourier-transform infrared spectroscopy (FTIR) or Wide-Angle X-ray Scattering (WAXS)