3 research outputs found
<i>Hevea brasiliensis</i> (Rubber Seed) Oil: Extraction, Characterization, and Kinetics of Thermo-oxidative Degradation Using Classical Chemical Methods
In the present study,
nonedible seed oils from underutilized Nigerian
NIG800 clonal rubber seeds were extracted using a solvent method to
obtain a yield of 43 wt % after extraction for 1 h using a 0.5 mm
kernel particle size. The oil was characterized by GC-MS, FT-IR, and
NMR analyses, and found to possess several potential industrial applications.
The physicochemical properties determined agreed with reported values
in the literature. The low ash content (0.001 wt %) indicates the
absence of trace metals that catalyze oxidation reactions. The low
moisture (1.73 wt %) and carbon residue (0.4 wt %) contents, high
volatile matter (97.869 wt %), and low freezing point (−18
°C) properties of the oil indicate a better source material for
biodiesel synthesis for use in cold regions compared to other vegetable
oils. The higher heating value
of 39.37 kJ/kg for the oil is within the range of values reported
by researchers for other nonedible vegetable oils. The high content
of saturated fatty acids (30.67 wt %) and moderately low monounsaturated
fatty acids (69.33 wt %) confer a good shelf life compared to other
oils. A closer examination of results of the NMR and GC-MS show a
satisfactory agreement that these genetically modified rubber seeds
have an insignificant proportion of polyunsaturated fatty acids (linoleic,
linolenic, etc.). This insignificant presence of polyunsaturated fatty
acids supports higher thermal stability, and slower rate of oxidation
of the oil compared to other vegetable oils. The kinetics of thermal
oxidative degradation follows a first-order reaction. The activation
energy of 13.07 kJ/mol was obtained within the temperature range 100–250
°C
Transesterification of Rubber Seed Oil to Biodiesel over a Calcined Waste Rubber Seed Shell Catalyst: Modeling and Optimization of Process Variables
In
the present study, waste rubber seed shell (RSS) obtained from
our previous study was investigated as a plausible solid base catalyst
for the transesterification of esterified rubber seed oil (RSO) to
biodiesel. TGA, XRF, XRD, SEM, and N<sub>2</sub> adsorption/desorption
analysis (BET) were used to characterize the catalyst. Central composite
design (CCD) was employed to design the experiments conducted to study
the influence of the process variables (reaction time, methanol/oil
ratio, and catalyst loading) on biodiesel yield. Response surface
methodology (RSM) technique, was used to optimize the process, and
the quadratic model developed was statistically significant with <i>F</i>-value of 12.38 and <i>p</i>-value (<0.05).
The optimum conditions obtained from RSM are as follows: reaction
time (60 min), methanol/oil ratio (0.20 vol/vol), and catalyst loading
(2.2 g) with a maximum biodiesel yield of 83.11% which was validated
experimentally as 83.06 ± 0.013%. Reusability test of the catalyst
at optimum conditions shows that the biodiesel yield was over 80%
after fourth cycle of usage and the leached Ca<sup>2+</sup> ion content
of biodiesel was 3.26 mg/kg (ppm). The ester content determined by
a precalibrated gas chromatography and the oxidation stability of
the biodiesel are 96.7% and 7.8 h, respectively. The characterized
biodiesel complied with ASTM D 6751 and EN 14214 biodiesel standards
Transesterification of Rubber Seed Oil to Biodiesel over a Calcined Waste Rubber Seed Shell Catalyst: Modeling and Optimization of Process Variables
In
the present study, waste rubber seed shell (RSS) obtained from
our previous study was investigated as a plausible solid base catalyst
for the transesterification of esterified rubber seed oil (RSO) to
biodiesel. TGA, XRF, XRD, SEM, and N<sub>2</sub> adsorption/desorption
analysis (BET) were used to characterize the catalyst. Central composite
design (CCD) was employed to design the experiments conducted to study
the influence of the process variables (reaction time, methanol/oil
ratio, and catalyst loading) on biodiesel yield. Response surface
methodology (RSM) technique, was used to optimize the process, and
the quadratic model developed was statistically significant with <i>F</i>-value of 12.38 and <i>p</i>-value (<0.05).
The optimum conditions obtained from RSM are as follows: reaction
time (60 min), methanol/oil ratio (0.20 vol/vol), and catalyst loading
(2.2 g) with a maximum biodiesel yield of 83.11% which was validated
experimentally as 83.06 ± 0.013%. Reusability test of the catalyst
at optimum conditions shows that the biodiesel yield was over 80%
after fourth cycle of usage and the leached Ca<sup>2+</sup> ion content
of biodiesel was 3.26 mg/kg (ppm). The ester content determined by
a precalibrated gas chromatography and the oxidation stability of
the biodiesel are 96.7% and 7.8 h, respectively. The characterized
biodiesel complied with ASTM D 6751 and EN 14214 biodiesel standards