Polymer Translocation througha Pore in a Membrane

We construct a new statistical physical model of polymer translocation through a pore in a membrane treated as the diffusion process across a free energy barrier. We determine the translocation time in terms of chain flexibility yielding an entropic barrier, as well as in terms of the driving mechanisms such as transmembrane chemical potential difference and Brownian ratchets. It turns out that, while the chemical potential differences induce pronounced effects on translocation due to the long-chain nature of the polymer, the ratchets suppress this effect and chain flexibility.Comment: 4 pages, 5 figures, published in Phys. Rev. Lett. 77, 783(1996

Thermo-viscoplastic analysis of hypersonic structures subjected to severe aerodynamic heating

A thermoviscoplastic computational method for hypersonic structures is presented. The method employs unified viscoplastic constitutive model implemented in a finite element approach for quasi-static thermal-structural analysis. Applications of the approach to convectively cooled hypersonic structures illustrate the effectiveness of the approach and provide insight into the transient inelastic structural behavior at elevated temperatures

Glacial cycles drive variations in the production of oceanic crust

Glacial cycles redistribute water between oceans and continents causing pressure changes in the upper mantle, with consequences for melting of Earth's interior. Using Plio-Pleistocene sea-level variations as a forcing function, theoretical models of mid-ocean ridge dynamics that include melt transport predict temporal variations in crustal thickness of hundreds of meters. New bathymetry from the Australian-Antarctic ridge shows significant spectral energy near the Milankovitch periods of 23, 41, and 100 ky, consistent with model predictions. These results suggest that abyssal hills, one of the most common bathymetric features on Earth, record the magmatic response to changes in sea level. The models and data support a link between glacial cycles at the surface and mantle melting at depth, recorded in the bathymetric fabric of the sea floor.Comment: 30 pages, 6 figures (including supplementary information). Resubmitted to Science on 12 December 201

Polymerization of ethylene oxide using yttrium isopropoxide

Well defined poly(ethylene oxide)s were prepared using yttrium isopropoxide as an initiator. End group analysis using 1H- and 13C NMR spectroscopy revealed that only polymers with isopropyl ether and hydroxyl end groups were produced. The molecular weight is controlled by the initial amount of initiator added and low polydispersity polymer (Mw/Mn ≈ 1.1) was isolated. Sequential polymerization indicated the suitability of this initiator for macromolecular engineering

"Dark" Z implications for Parity Violation, Rare Meson Decays, and Higgs Physics

General consequences of mass mixing between the ordinary Z boson and a relatively light Z_d boson, the "dark" Z, arising from a U(1)_d gauge symmetry, associated with a hidden sector such as dark matter, are examined. New effects beyond kinetic mixing are emphasized. Z-Z_d mixing introduces a new source of low energy parity violation well explored by possible future atomic parity violation and planned polarized electron scattering experiments. Rare K (B) meson decays into pi (K) l^+ l^- (l = e, mu) and pi (K) nu anti-nu are found to already place tight constraints on the size of Z-Z_d mixing. Those sensitivities can be further improved with future dedicated searches at K and B factories as well as binned studies of existing data. Z-Z_d mixing can also lead to the Higgs decay H -> Z Z_d, followed by Z -> l_1^+ l_1^- and Z_d -> l_2^+ l_2^- or "missing energy", providing a potential hidden sector discovery channel at the LHC. An illustrative realization of these effects in a 2 Higgs doublet model is presented.Comment: Version to appear in PR

What drives the translocation of stiff chains?

We study the dynamics of the passage of a stiff chain through a pore into a cell containing particles that bind reversibly to it. Using Brownian Molecular Dynamics simulations we investigate the mean-first-passage time as a function of the length of the chain inside, for different concentrations of binding particles. As a consequence of the interactions with these particles, the chain experiences a net force along its length whose calculated value from the simulations accounts for the velocity at which it enters the cell. This force can in turn be obtained from the solution of a generalized diffusion equation incorporating an effective Langmuir adsorption free energy for the chain plus binding particles. These results suggest a role of binding particles in the translocation process which is in general quite different from that of a Brownian ratchet. Furthermore, non-equilibrium effects contribute significantly to the dynamics, \emph{e.g.}, the chain often enters the cell faster than particle binding can be saturated, resulting in a force several times smaller than the equilibrium value.Comment: 7 pages, 4 figure

Analysis of Oil Production Behavior for the Fractured Basement Reservoir Using Hybrid Discrete Fractured Network Approach

Unlike naturally fractured reservoir, fractured basement reservoir (FBR) has almost non-permeable matrix and flow is strongly dependent upon fracture network. This might cause the rapid changing behavior on oil production whether fracture near wellbore is saturated with either oil or water. In this aspect, realistic representation of fracture network is essential in FBR. Therefore the simulation of FBR is generally applied by dual-porosity (DP) continuum approach because discrete fractured network (DFN) simulator with multiphase flow is not commercially available except in-house model. In this paper, hybrid DFN approach is applied, which is continuum model coupled with local grid refinement (LGR). LGR is adapted at the cells which are passing through fractures, in order to represent fracture width less than 0.1 ft. Up to now, LGR is mostly used for well block rather than the fracture. In this approach, well control volume can not be described by LGR cell, thus, four-leg horizontal well concept substitutes the vertical well with the use of equivalent wellbore radius for overcoming the numerical convergence problem. The application of hybrid DFN approach for FBR is discussed about investigation of the possibility for drastic change on oil production. Based on the results, in fractured reservoir using hybrid DFN approach, oil production is not found to be proportional to the magnitude of matrix permeability, not as in porous system with dual-porosity approach. Also, we realized that oil production is once dropped it can not be recovered back to previous level in FBR. This is because oil-saturated fracture near well is once changed to water-saturated, then, there was not anymore changes occurred within the same fracture.Key words: Dual-porosity; Hybrid DFN; Fractured basement reservoir; Local grid refinemen

UBVI Surface Photometry of the Spiral Galaxy NGC 300 in the Sculptor Group

We present UBVI surface photometry for 20.'5 X 20.'5 area of a late-type spiral galaxy NGC 300. In order to understand the morphological properties and luminosity distribution characteristics of NGC 300, we have derived isophotal maps, surface brightness profiles, ellipticity profiles, position angle profiles, and color profiles. By merging the I-band data of our surface brightness measurements with those of Boeker et al. (2002) based on Hubble Space Telescope observations, we have made combined I-band surface brightness profiles for the region of 0."02 < r < 500" and decomposed the profiles into three components: a nucleus, a bulge, and an exponential disk.Comment: 16 pages(cjaa209.sty), Accepted by the Chinese J. Astron. Astrophys., Fig 2 and 8 are degraded to reduce spac