Research on Multiprincipals Selecting Effective Agency Mode in the Student Loan System

An effective agency mode is the key to solve incentive problems in Chinese student loan system. Principal-agent frameworks are considered in which two principals share one common agent that is performing one single task but each prefers the different aspect of the task. Three models are built and decision mechanisms are given. The studies show that the three modes have different effects. Exclusive dealing mode is not good for long-term effect because sometimes it guides agent ignoring repayment. If effort proportionality coefficient and observability are both unchanged, principals all prefer common agency, but independent contracting mode may be more efficient in reality because not only the total outputs under that mode are larger than those under cooperation one, but also preferring independent contracting mode can stimulate the bank participating in the game

Convergence analysis of environmental efficiency from the perspective of environmental regulation: evidence from China

The aim of this paper is to analyze the impact of environmental regulation on regional environmental efficiency convergence using the fixed effects model and threshold regression model. The results show that the differences in environmental efficiency have a convergence trend in China, as well as in the eastern, central and western regions. The effect of environmental regulation on regional environmental efficiency is inhibition first and then promotion, research and development investment and outward foreign direct investment have a positive transmission effect; when environmental regulation intensity exceeds a certain threshold, the growth rate of environmental efficiency in the central and western regions will be significantly higher than that in the eastern regions

Cellulose Nanocrystals Induced Loose and Porous Graphite Phase Carbon Nitride/Porous Carbon Composites for Capturing and Determining of Organochlorine Pesticides from Water and Fruit Juice by Solid-Phase Microextraction

Herein, novel, loose, and porous graphite phase carbon nitride/porous carbon (g-C3N4@PC) composites were prepared by decorating cellulose nanocrystals (CNCs). The characterization results demonstrate that the as-prepared composites presented high specific surface areas, porous structures, and abundant chemical groups, with the modification of CNCs. In view of the unique advantages, g-C3N4@PC was used as the coating material for the solid-phase microextraction (SPME) of organochlorine pesticides (OCPs) in water and juice samples. The g-C3N4@PC-coated fibers showed better extraction efficiencies than commercial fibers (100/7 μm PDMS and PA) toward the OCPs, with the enrichment factors of the g-C3N4@PC-coated fibers 5–30 times higher than the latter. Using a gas chromatography–mass spectrometry (GC-MS) instrument, the g-C3N4@PC-coated fibers exhibited a gratifying analytical performance for determining low concentrations of OCPs, with a wide linear range (0.1–1600 ng L−1 for water; 0.1–1000 ng L−1 for juice), low limits of detection (0.0141–0.0942 ng L−1 for water; 0.0245–0.0777 ng L−1 for juice), and good reproducibility and repeatability in optimal conditions. The established method showed good sensitivity and recovery in the determination of OCPs in the water and fruit juice samples, which displayed broad prospects for analyzing organic pollutants from environmental samples

Sheet-like Skeleton Carbon Derived from Shaddock Peels with Hierarchically Porous Structures for Ultra-Fast Removal of Methylene Blue

To remove the pollutant methylene blue (MB) from water, a sheet-like skeleton carbon derived from shaddock peels (SPACs) was prepared by NaOH activation followed by a calcination procedure under nitrogen protection in this study. Characterization results demonstrated that the as-prepared SPACs displayed a hierarchically porous structure assembled with a thin sheet-like carbon layer, and the surface area of SPAC-8 (activated by 8 g NaOH) was up to 782.2 m2/g. The as-prepared carbon material presented an ultra-fast and efficient adsorption capacity towards MB due to its macro-mesoporous structure, high surface area, and abundant functional groups. SPAC-8 showed ultrafast and efficient removal capacity for MB dye. Adsorption equilibrium was reached within 1 min with a removal efficiency of 99.6% at an initial concentration of 100 mg/g under batch adsorption model conditions. The maximum adsorption capacity for MB was up to 432.5 mg/g. A pseudo-second-order kinetic model and a Langmuir isotherm model described the adsorption process well, which suggested that adsorption rate depended on chemisorption and the adsorption process was controlled by a monolayer adsorption, respectively. Furthermore, column adsorption experiments showed that 96.58% of MB was removed after passing through a SPAC-8 packed column with a flow rate of 20 mL/min, initial concentration of 50 mg/L, and adsorbent dosage of 5 mg. The as-prepared adsorbent displays potential value in practical applications for dye removal due to its ultrafast and efficient adsorption capacity

Carbon Dot-Decorated Graphite Carbon Nitride Composites for Enhanced Solid-Phase Microextraction of Chlorobenzenes from Water

In this work, carbon dot-decorated graphite carbon nitride composites (CDs/g-C3N4) were synthesized and innovatively used as a SPME coating for the sensitive determination of chlorobenzenes (CBs) from water samples, coupled with gas chromatography–mass spectrometry. The CDs/g-C3N4 coating presented superior extraction performance in comparison to pristine g-C3N4, owing to the enhancement of active groups by CDs. The extraction capacities of as-prepared SPME coatings are higher than those of commercial coatings due to the functions of nitrogen-containing and oxygen-containing group binding, π–π stacking, and hydrophobic interactions. Under optimized conditions, the proposed method exhibits a wide linearity range (0.25–2500 ng L−1), extremely low detection of limits (0.002–0.086 ng L−1), and excellent precision, with relative standard deviations of 5.3–9.7% for a single fiber and 7.5–12.6% for five fibers. Finally, the proposed method was successfully applied for the analysis of CBs from real river water samples, with spiked recoveries ranging from 73.4 to 109.1%. This study developed a novel and efficient SPME coating material for extracting organic pollutants from environmental samples