Study of Lake Baikal ice cover from radar altimetry and in-situ observations

Comparison of ENVISAT and SARAL missions data shows that AltiKa can be successfully used for ice discrimination methodology and extension of ice conditions time series. Due to shorter wavelength and large bandwidth (480 MHz) which leads to a higher sensitivity to different surface conditions, AltiKa shows more clearly the separation between open water and various ice types. We observe significant decrease of backscatter (25–30 dB) in late spring for both ENVISAT and SARAL and discuss it in the context of ice metamorphism. There is a clear need to continue and expand our dedicated field studies of lake Baikal ice cover to better assess influence of ice structure on altimetric signal

Study of Lake Baikal ice cover from radar altimetry and in-situ observations

Comparison of ENVISAT and SARAL missions data shows that AltiKa can be successfully used for ice discrimination methodology and extension of ice conditions time series. Due to shorter wavelength and large bandwidth (480 MHz) which leads to a higher sensitivity to different surface conditions, AltiKa shows more clearly the separation between open water and various ice types. We observe significant decrease of backscatter (25–30 dB) in late spring for both ENVISAT and SARAL and discuss it in the context of ice metamorphism. There is a clear need to continue and expand our dedicated field studies of lake Baikal ice cover to better assess influence of ice structure on altimetric signal

Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate

The development of solvent-free techniques for nanoparticles synthesis is one of the challenges of Green chemistry. In this work, the principled opportunity to obtain copper-containing nanosized particles without use of any solvents was shown. The copper complexes were prepared as precursors by the melting-assisted solvent-free synthesis. The formation of tetra(imidazole)copper(II) nitrate complex was confirmed by XRD, elemental analysis, FTIR spectroscopy, and thermal analysis. It was noted that their thermal decomposition occurs in two stages: (I) the low-temperature step may be related to redox interaction between organic ligands and nitrate-anions; (II) the high-temperature step may be related to the oxidation of the products of incomplete imidazole decomposition. TEM and XRD studies of solid products of complex combustion have shown that they are oxides with particle size less than 40 nm. Thus, the combustion of [Cu(Im)4](NO3)2 complex under air can be considered as a new approach to prepare nanosized particles of copper oxides without the use of solvents

Solvent-Free Method for Nanoparticles Synthesis by Solid-State Combustion Using Tetra(Imidazole)Copper(II) Nitrate

The development of solvent-free techniques for nanoparticles synthesis is one of the challenges of Green chemistry. In this work, the principled opportunity to obtain copper-containing nanosized particles without use of any solvents was shown. The copper complexes were prepared as precursors by the melting-assisted solvent-free synthesis. The formation of tetra(imidazole)copper(II) nitrate complex was confirmed by XRD, elemental analysis, FTIR spectroscopy, and thermal analysis. It was noted that their thermal decomposition occurs in two stages: (I) the low-temperature step may be related to redox interaction between organic ligands and nitrate-anions; (II) the high-temperature step may be related to the oxidation of the products of incomplete imidazole decomposition. TEM and XRD studies of solid products of complex combustion have shown that they are oxides with particle size less than 40 nm. Thus, the combustion of [Cu(Im)4](NO3)2 complex under air can be considered as a new approach to prepare nanosized particles of copper oxides without the use of solvents