Prognostics for an actuator with the combination of support vector regression and particle filter

The accurate prognostics for actuator malfunctions is a challenging task. Developing reliable prognostic methods is vital for providing reasonable preventive maintenance schedules and preventing unexpected failures. Particle filter has been proved to be a traditional approach to deal with actuator prognostic problems. However, the measurement function in the particle filter algorithm cannot be obtained in the prediction process, this paper presents a hybrid framework combining support vector regression (SVR) and particle filter (PF). The SVR output prediction results are employed as the “measurements” for the subsequent PF algorithm. To accomplish the accurate prognostics for actuator fault of civil aircraft, an improved PF based on Kendall correlation coefficient is put forward to solve the problem of particles’ degeneracy. The experimental results are presented, demonstrating that the SVR-PF hybrid approach has satisfactory performance with better prognostics accuracy and higher fault resolution than traditional approaches

Effect of different proportions of glycerol and D-mannitol as plasticizer on the properties of extruded corn starch

In this study, thermoplastic starch (TPS) was prepared by melt extrusion process, in which glycerol and/or D-mannitol were used as plasticizers, and the effect of different glycerol/D-mannitol ratios (4:0, 3:1, 2:2, 1:3, and 0:4) on the physicochemical properties of the extruded starch samples was investigated. The short-range molecular order, crystallization, gelatinization, thermal stability, and thermal properties of the TPS samples were analyzed through attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy, X-ray diffraction (XRD), rapid visco analysis (RVA), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The results showed that the crystallinity and short-range molecular order of the TPS samples increased with increasing glycerol content. Conversely, the water absorption index (WAI) and water solubility index (WSI) of the TPS samples decreased with increasing glycerol content. In addition, the TPS samples with higher glycerol content exhibited higher gel and thermal stabilities. This study provides a theoretical basis for starch extrusion and plasticization in the preparation of TPS-based materials with specific properties

Prognostics for an actuator with the combination of support vector regression and particle filter

The accurate prognostics for actuator malfunctions is a challenging task. Developing reliable prognostic methods is vital for providing reasonable preventive maintenance schedules and preventing unexpected failures. Particle filter has been proved to be a traditional approach to deal with actuator prognostic problems. However, the measurement function in the particle filter algorithm cannot be obtained in the prediction process, this paper presents a hybrid framework combining support vector regression (SVR) and particle filter (PF). The SVR output prediction results are employed as the “measurements” for the subsequent PF algorithm. To accomplish the accurate prognostics for actuator fault of civil aircraft, an improved PF based on Kendall correlation coefficient is put forward to solve the problem of particles’ degeneracy. The experimental results are presented, demonstrating that the SVR-PF hybrid approach has satisfactory performance with better prognostics accuracy and higher fault resolution than traditional approaches

Structural basis of energy transfer in Porphyridium purpureum phycobilisome

The cryo-electron microscopy structure of a phycobilisome from the red alga Porphyridium purpureum reveals how aromatic interactions between the linker proteins and the chromophores drive a unidirectional transfer of energy. Photosynthetic organisms have developed various light-harvesting systems to adapt to their environments(1). Phycobilisomes are large light-harvesting protein complexes found in cyanobacteria and red algae(2-4), although how the energies of the chromophores within these complexes are modulated by their environment is unclear. Here we report the cryo-electron microscopy structure of a 14.7-megadalton phycobilisome with a hemiellipsoidal shape from the red alga Porphyridium purpureum. Within this complex we determine the structures of 706 protein subunits, including 528 phycoerythrin, 72 phycocyanin, 46 allophycocyanin and 60 linker proteins. In addition, 1,598 chromophores are resolved comprising 1,430 phycoerythrobilin, 48 phycourobilin and 120 phycocyanobilin molecules. The markedly improved resolution of our structure compared with that of the phycobilisome of Griffithsia pacifica(5) enabled us to build an accurate atomic model of the P. purpureum phycobilisome system. The model reveals how the linker proteins affect the microenvironment of the chromophores, and suggests that interactions of the aromatic amino acids of the linker proteins with the chromophores may be a key factor in fine-tuning the energy states of the chromophores to ensure the efficient unidirectional transfer of energy

Hydrogen Bonding Regulated Flexibility and Disorder in Hydrazone-Linked Covalent Organic Frameworks

Covalent organic framework (COF) chemistry is experiencing unprecedented development in recent decades. The current studies on COF chemistry are mainly focused on the discovery of novel covalent linkages, new topological structures, synthetic methodologies, and potential applications. However, despite the fact that noncovalent interactions are ubiquitous in COF chemistry, relatively little attention has been given to the role of noncovalent bonds on COF structures and their properties. In this work, a series of hydrazone-linked COFs involving noncovalent hydrogen bonds have been constructed, where the hydrogen-bonding interaction plays critical roles in the COF crystallinity and structures. The regulation of structural flexibility, the reversible transition between order and disorder, and the variety of host–guest interactions have been demonstrated in succession for the first time in COFs. The results obtained by the hydrogen-bonding-regulated strategy may also be extendable to other noncovalent interactions, such as π–π interactions, metal coordination interactions, Lewis acid–base interactions, etc. These findings will inspire future developments in the design, synthesis, structural regulation, and applications of COFs by manipulating noncovalent interactions

Hydrogelation and Crystallization of Sodium Deoxycholate Controlled by Organic Acids

The gelation and crystallization behavior of a biological surfactant, sodium deoxycholate (NaDC), mixed with l-taric acid (L-TA) in water is described in detail. With the variation of molar ratio of L-TA to NaDC (<i>r</i> = <i>n</i>_L‑TA/<i>n</i>_NaDC) and total concentration of the mixtures, the transition from sol to gel was observed. SEM images showed that the density of nanofibers gradually increases over the sol–gel transition. The microstructures of the hydrogels are three-dimensional networks of densely packed nanofibers with lengths extending to several micrometers. One week after preparation, regular crystallized nanospheres formed along the length of the nanofibers, and it was typical among the transparent hydrogels induced by organic acids with p<i>K</i>_a₁ value <3.4. Small-angle X-ray diffraction demonstrated differences in the molecular packing between transparent and turbid gels, indicating a variable hydrogen bond mode between NaDC molecules

The structural basis for light acclimation in phycobilisome light harvesting systems systems in Porphyridium purpureum

Abstract Photosynthetic organisms adapt to changing light conditions by manipulating their light harvesting complexes. Biophysical, biochemical, physiological and genetic aspects of these processes are studied extensively. The structural basis for these studies is lacking. In this study we address this gap in knowledge by focusing on phycobilisomes (PBS), which are large structures found in cyanobacteria and red algae. In this study we focus on the phycobilisomes (PBS), which are large structures found in cyanobacteria and red algae. Specifically, we examine red algae (Porphyridium purpureum) grown under a low light intensity (LL) and a medium light intensity (ML). Using cryo-electron microscopy, we resolve the structure of ML-PBS and compare it to the LL-PBS structure. The ML-PBS is 13.6 MDa, while the LL-PBS is larger (14.7 MDa). The LL-PBS structure have a higher number of closely coupled chromophore pairs, potentially the source of the red shifted fluorescence emission from LL-PBS. Interestingly, these differences do not significantly affect fluorescence kinetics parameters. This indicates that PBS systems can maintain similar fluorescence quantum yields despite an increase in LL-PBS chromophore numbers. These findings provide a structural basis to the processes by which photosynthetic organisms adapt to changing light conditions