Appearance of effective surface conductivity - an experimental and analytic study

Surface conductance measurements on p-type doped germanium show a small but systematic change to the surface conductivity at different length scales. This effect is independent of the structure of the surface states. We interpret this phenomenon as a manifestation of conductivity changes beneath the surface. This hypothesis is confirmed by an analysis of the classical current flow equation. We derive an integral formula for calculating of the effective surface conductivity as a function of the distance from a point source. Furthermore we derive asymptotic values of the surface conductivity at small and large distances. The actual surface conductivity can only be sampled close to the current source. At large distances, the conductivity measured on the surface corresponds to the bulk value.Comment: 11 pages, 8 figure

Adsorption behavior of 9-anthracenecarboxylic acid on (110) rutile TiO2TiO_{2}

The adsorption behavior of 9-anthracenecarboxylic acid (AnCA) on a rutile TiO$_{2}$ (110) surface has been investigated with scanning tunneling microscopy (STM) at room temperature. Upon deposition, the molecules adsorb, resulting in a commensurate herringbone c-(2 × 2) structure, as confirmed by low-energy electron diffraction (LEED). Annealing of the sample below the desorption point causes irreversible superstructure derangement. Thermally programmed desorption (TPD) reveals that, after prior decomposition on the surface, AnCA molecules desorb into anthracenes and carboxyl acid derivatives

Fermi level pinning at the Ge(001) surface - A case for non-standard explanation

To explore the origin of the Fermi level pinning in germanium we investigate the Ge(001) and Ge(001):H surfaces. The absence of relevant surface states in the case of Ge(001):H should unpin the surface Fermi level. This is not observed. For samples with donors as majority dopants the surface Fermi level appears close to the top of the valence band regardless of the surface structure. Surprisingly, for the passivated surface it is located below the top of the valence band allowing scanning tunneling microscopy imaging within the band gap. We argue that the well known electronic mechanism behind band bending does not apply and a more complicated scenario involving ionic degrees of freedom is therefore necessary. Experimental techniques involve four point probe electric current measurements, scanning tunneling microscopy and spectroscopy.Comment: 5 pages, 4 figure

Scanning probe microscopy studies on the adsorption of selected molecular dyes on titania

Titanium dioxide, or titania, sensitized with organic dyes is a very attractive platform for photovoltaic applications. In this context, the knowledge of properties of the titania–sensitizer junction is essential for designing efficient devices. Consequently, studies on the adsorption of organic dyes on titania surfaces and on the influence of the adsorption geometry on the energy level alignment between the substrate and an organic adsorbate are necessary. The method of choice for investigating the local environment of a single dye molecule is high-resolution scanning probe microscopy. Microscopic results combined with the outcome of common spectroscopic methods provide a better understanding of the mechanism taking place at the titania–sensitizer interface. In the following paper, we review the recent scanning probe microscopic research of a certain group of molecular assemblies on rutile titania surfaces as it pertains to dye-sensitized solar cell applications. We focus on experiments on adsorption of three types of prototypical dye molecules, i.e., perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA), phtalocyanines and porphyrins. Two interesting heteromolecular systems comprising molecules that are aligned with the given review are discussed as well