Condensation cyclization reactions of electron deficient aromatics. 4: Tricyclic nitropropene nitronates from the reaction of phloroglucinol and cycloalkanones with sym-trinitrobenzene

Interesting similarities have been shown between the reactions of sym-trinitrobenzene with cycloalkanones, and with phloroglucinol. Previously unsuspected common intermediates have been shown to intervene. The structurally similar products in each case are tricyclic nitropropene nitronates. Protonation of these yields the corresponding nitronic acids in certain instances

Manipulation of plants by transformation with sequences promoting cell division

Polynucleotides encode polypeptides for increasing the rate of growth of plants. Introduction of the polynucleotides into plants produces plants having altered characteristics, such as increased growth, increased leaf area and reduced fertility. Expression of polypeptides in plants or plant cells promotes cell division. Expression of the polynucleotides in plants in the antisense orientation produces plants that are sterile or have smaller leaves.https://digitalcommons.mtu.edu/patents/1012/thumbnail.jp

Carbon choices determine US cities committed to futures below sea level

Anthropogenic carbon emissions lock in long-term sea-level rise that greatly exceeds projections for this century, posing profound challenges for coastal development and cultural legacies. Analysis based on previously published relationships linking emissions to warming and warming to rise indicates that unabated carbon emissions up to the year 2100 would commit an eventual global sea-level rise of 4.3–9.9 m. Based on detailed topographic and population data, local high tide lines, and regional long-term sea-level commitment for different carbon emissions and ice sheet stability scenarios, we compute the current population living on endangered land at municipal, state, and national levels within the United States. For unabated climate change, we find that land that is home to more than 20 million people is implicated and is widely distributed among different states and coasts. The total area includes 1,185–1,825 municipalities where land that is home to more than half of the current population would be affected, among them at least 21 cities exceeding 100,000 residents. Under aggressive carbon cuts, more than half of these municipalities would avoid this commitment if the West Antarctic Ice Sheet remains stable. Similarly, more than half of the US population-weighted area under threat could be spared. We provide lists of implicated cities and state populations for different emissions scenarios and with and without a certain collapse of the West Antarctic Ice Sheet. Although past anthropogenic emissions already have caused sea-level commitment that will force coastal cities to adapt, future emissions will determine which areas we can continue to occupy or may have to abandon

A discrete time relativistic Toda lattice

Four integrable symplectic maps approximating two Hamiltonian flows from the relativistic Toda hierarchy are introduced. They are demostrated to belong to the same hierarchy and to examplify the general scheme for symplectic maps on groups equiped with quadratic Poisson brackets. The initial value problem for the difference equations is solved in terms of a factorization problem in a group. Interpolating Hamiltonian flows are found for all the maps.Comment: 32 pages, LaTe

MST Resistive Wall Tearing Mode Simulations

The Madison Symmetric Torus (MST) is a toroidal device that, when operated as a tokamak, is resistant to disruptions. Unlike most tokamaks, the MST plasma is surrounded by a close fitting highly conducting wall, with a resistive wall penetration time two orders of magnitude longer than in JET or DIII-D, and three times longer than in ITER. The MST can operate with edge q_a < 2, unlike standard tokamaks. Simulations presented here indicate that the MST is unstable to resistive wall tearing modes (RWTMs) and resistive wall modes (RWMs). They could in principle cause disruptions, but the predicted thermal quench time is much longer than the experimental pulse time. If the MST thermal quench time were comparable to measurements in JET and DIII-D, theory and simulations predict that disruptions would have been observed in MST. This is consistent with the modeling herein, predicting that disruptions are caused by RWTMs and RWMs. In the low q_a regime of MST, the RWTM asymptotically satisfies the RWM dispersion relation. The transition from RWTM to RWM occurs smoothly at q_a = m/n, where m,n are poloidal and toroidal mode numbers

Testing of High Voltage Surge Protection Devices for Use in Liquid Argon TPC Detectors

In this paper we demonstrate the capability of high voltage varistors and gas discharge tube arrestors for use as surge protection devices in liquid argon time projection chamber detectors. The insulating and clamping behavior of each type of device is characterized in air (room temperature), and liquid argon (90~K), and their robustness under high voltage and high energy surges in cryogenic conditions is verified. The protection of vulnerable components in liquid argon during a 150 kV high voltage discharge is also demonstrated. Each device is tested for argon contamination and light emission effects, and both are constrained to levels where no significant impact upon liquid argon time projection chamber functionality is expected. Both devices investigated are shown to be suitable for HV surge protection applications in cryogenic detectors.Comment: 22 pages, 18 figures v2: reduced file size for journal submissio