Photoluminescence transient study of surface defects in ZnO nanorods grown by chemical bath deposition

Two deep level defects (2.25 and 2.03 eV) associated with oxygen vacancies (V$_o$) were identified in ZnO nanorods (NRs) grown by low cost chemical bath deposition. A transient behaviour in the photoluminescence (PL) intensity of the two V$_o$ states was found to be sensitive to the ambient environment and to NR post-growth treatment. The largest transient was found in samples dried on a hot plate with a PL intensity decay time, in air only, of 23 and 80 s for the 2.25 and 2.03 eV peaks, respectively. Resistance measurements under UV exposure exhibited a transient behaviour in full agreement with the PL transient indicating a clear role of atmospheric O$_2$ on the surface defect states. A model for surface defect transient behaviour due to band bending with respect to the Fermi level is proposed. The results have implications for a variety of sensing and photovoltaic applications of ZnO NRs

Carbon nanotube-guided thermopower waves

Thermopower waves are a new concept for the direct conversion of chemical to electrical energy. A nanowire with large axial thermal diffusivity can accelerate a self-propagating reaction wave using a fuel coated along its length. The reaction wave drives electrical carriers in a thermopower wave, creating a high-power pulse of as much as 7 kW/kg in experiments using carbon nanotubes. We review nanomaterials designed to overcome limitations of thermoelectricity and explore the emerging scientific and practical outlook for devices using thermopower waves

Correlating densities of centrality and activities in cities : the cases of Bologna (IT) and Barcelona (ES)

This paper examines the relationship between street centrality and densities of commercial and service activities in cities. The aim is to verify whether a correlation exists and whether some 'secondary' activities, i.e. those scarcely specialized oriented to the general public and ordinary daily life, are more linked to street centrality than others. The metropolitan area of Barcelona (Spain) is investigated, and results are compared with those found in a previous work on the city of Bologna (Italy). Street centrality is calibrated in a multiple centrality assessment (MCA) model composed of multiple measures such as closeness, betweenness and straightness. Kernel density estimation (KDE) is used to transform data sets of centrality and activities to one scale unit for correlation analysis between them. Results indicate that retail and service activities in both Bologna and Barcelona tend to concentrate in areas with better centralities, and that secondary activities exhibit a higher correlation

Buckling, Crumpling, and Tumbling of Semiflexible Sheets in Simple Shear Flow

As 2D materials such as graphene, transition metal dichalcogenides, and 2D polymers become more prevalent, solution processing and colloidal-state properties are being exploited to create advanced and functional materials. However, our understanding of the fundamental behavior of 2D sheets and membranes in fluid flow is still lacking. In this work, we perform numerical simulations of athermal semiflexible sheets with hydrodynamic interactions in shear flow. For sheets initially oriented in the flow-gradient plane, we find buckling instabilities of different mode numbers that vary with bending stiffness and can be understood with a quasi-static model of elasticity. For different initial orientations, chaotic tumbling trajectories are observed. Notably, we find that sheets fold or crumple before tumbling but do not stretch again upon applying greater shear, which is in distinct contrast to polymer chains.Comment: Movies can be found at https://dx.doi.org/10.6084/m9.figshare.1323844

Trend Analysis of Air Quality Index in Catania from 2010 to 2014

Abstract Information on air quality in urban areas represents an important objective to raise awareness and participation of citizens towards those measures aimed at containing and reducing vehicular traffic. For several years at the international level, evaluation procedures have been adopted by indices. One of the first synthetic indices, adopted by the United States Environmental Protection Agency (US-EPA), was the Pollution Standard Index (PSI). In 1999, the EPA replaced the PSI index with Air Quality Index (AQI), which includes two new sub-indices, the ozone at ground level and fine particulate. Despite the European Decisions 97/101/EC and 2001/752/EC, have established an exchange of information from networks and individual stations measuring ambient air pollution in Member States, the use of a single index has not yet been defined that allows you to compare different realities. This heterogeneity emerges in Italy as well, where only a few Environmental Protection Agencies disclose indexes to inform citizens. In this article, the Air Quality Index (AQI) currently used by the United States Environmental Protection Agency has been applied to the metropolitan city of Catania, in order to analyze the level of pollution daily from 2010 to 2014. Through the use of the AQI it was possible to synthesize in a single daily value, concentrations of major pollutants in urban areas (NO2, O3, CO, SO2, PM10) for the entire period. For the calculation procedure of the AQI, the data concentrations were provided by Municipal Ecology and Environment Office. The data relates to three monitoring stations, whose locations have not changed over the years. This also made it possible to evaluate the change in frequency of AQI agglomerations where the monitoring units have been positioned. The value obtained by the AQI for each station has been ranked in six levels of pollution; each level has been associated with a particular coloring allowing this information to be more intuitive. Lastly, it was possible to reach the air quality assessment in urban environment from the frequency variations of each level derived from the year 2010 until 2014

Exciton binding energies in carbon nanotubes from two-photon photoluminescence

One- and two-photon luminescence excitation spectroscopy showed a series of distinct excitonic states in single-walled carbon nanotubes. The energy splitting between one- and two-photon-active exciton states of different wavefunction symmetry is the fingerprint of excitonic interactions in carbon nanotubes. We determine exciton binding energies of 0.3-0.4 eV for different nanotubes with diameters between 0.7 and 0.9 nm. Our results, which are supported by ab-initio calculations of the linear and non-linear optical spectra, prove that the elementary optical excitations of carbon nanotubes are strongly Coulomb-correlated, quasi-one dimensionally confined electron-hole pairs, stable even at room temperature. This alters our microscopic understanding of both the electronic structure and the Coulomb interactions in carbon nanotubes, and has direct impact on the optical and transport properties of novel nanotube devices.Comment: 5 pages, 4 figure

In Vivo Delivery of Nitric Oxide-Sensing, Single-Walled Carbon Nanotubes

Detection of nitric oxide (NO) in vivo by single-walled carbon nanotubes (SWNT) is based on the fluorescent properties of SWNT and the ability of NO to quench the fluorescence signal. Alterations of the signal can be utilized to detect a small molecule in vivo that has not previously been possible by other assay techniques. The protocols described here explain the techniques used to prepare NO-detecting SWNTs and to administer them to mice by both intravenous and subcutaneous routes. These techniques can also be utilized with other SWNT sensors as well as non-SWNT sensorNational Institutes of Health (T32 Training Grant in Environmental Toxicology ES007020

PM10 Dispersion Modeling by Means of CFD 3D and Eulerian–Lagrangian Models: Analysis and Comparison with Experiments☆

Abstract This research deals with the analysis of the dispersion of PM10 by using fluid-dynamic simulation framework. Firstly, an experimental campaign was made in a wind tunnel. A cylindrical emitter of PM10 was characterized in terms of PM10 mass flow rate and outlet velocity. It was positioned in the wind tunnel chamber where several sensors were also placed downwind. The use of different sensor configurations allowed the evaluation of the PM10 concentrations in several locations. The experimental campaign was reproduced in ANSYS-Fluent, by recreating in Design-Model, a 3D geometries of the test case. Different calculation grids were tested in order to find the proper balance between computing time and accuracy. The CFD 3D model was based on the Eulerian approach for the continuous phase and Lagrangian approach for the dispersion phase setting the DPM for the evaluation and dispersion of particulate matters. The turbulence was solved by using a k-ɛ RANS approach and a quite advanced unsteady DES model. Several simulations were carried out by varying the flow inlet velocities in configurations with and without obstacles. The results obtained from the post-processing phase were then compared with the experimental campaign. With obstacles a PM concentration increment is observed at all imposed air velocity because of recirculation phenomena generated around the obstacles

A network based kernel density estimator applied to Barcelona economic activities

This paper presents a methodology to compute an innovative density indicator of spatial events. The methodology is based on a modified Kernel Density Estimator (KDE) that operates along road networks, and named Network based Kernel Density Estimator (NetKDE). In this research, retail and service economic activities are projected on the road network whose edges are weighted by a set of centrality values calculated with a Multiple Centrality Assessment (MCA). First, this paper calculate a density indicator for the point pattern analysis on human activities in a network constrained environment. Then, this indicator is modified to evaluate network performance in term of centrality. The methodology is applied to the city of Barcelona to explore the potential of the approach on more than 11,000 network edges and 166,000 economic activities