5 research outputs found
Combustion of the butanol isomers: reaction pathways at elevated pressures from low-to-high temperatures
Deep Lake: a Lakehouse for Deep Learning
Traditional data lakes provide critical data infrastructure for analytical
workloads by enabling time travel, running SQL queries, ingesting data with
ACID transactions, and visualizing petabyte-scale datasets on cloud storage.
They allow organizations to break down data silos, unlock data-driven
decision-making, improve operational efficiency, and reduce costs. However, as
deep learning takes over common analytical workflows, traditional data lakes
become less useful for applications such as natural language processing (NLP),
audio processing, computer vision, and applications involving non-tabular
datasets. This paper presents Deep Lake, an open-source lakehouse for deep
learning applications developed at Activeloop. Deep Lake maintains the benefits
of a vanilla data lake with one key difference: it stores complex data, such as
images, videos, annotations, as well as tabular data, in the form of tensors
and rapidly streams the data over the network to (a) Tensor Query Language, (b)
in-browser visualization engine, or (c) deep learning frameworks without
sacrificing GPU utilization. Datasets stored in Deep Lake can be accessed from
PyTorch, TensorFlow, JAX, and integrate with numerous MLOps tools
Shock tube measurements of the rate constant for the reaction cyclohexene→ethylene+1,3-butadiene
Shock Tube Measurements of the <i>tert</i>-Butanol + OH Reaction Rate and the <i>tert</i>-C<sub>4</sub>H<sub>8</sub>OH Radical β‑Scission Branching Ratio Using Isotopic Labeling
The overall rate constant for the
reaction <i>tert</i>-butanol + OH → products was
determined experimentally behind
reflected shock waves by using <sup>18</sup>O-substituted <i>tert</i>-butanol (<i>tert</i>-butan<sup>18</sup>ol)
and <i>tert</i>-butyl hydroperoxide (TBHP) as a fast source
of <sup>16</sup>OH. The data were acquired from 900 to 1200 K near
1.1 atm and are best fit by the Arrhenius expression 1.24 × 10<sup>–10</sup> expÂ(−2501/<i>T</i> [K])
cm<sup>3</sup> molecule<sup>–1</sup> s<sup>–1</sup>.
The products of the title reaction include the <i>tert</i>-C<sub>4</sub>H<sub>8</sub>OH radical that is known to have two major
β-scission decomposition channels, one of which produces OH
radicals. Experiments with the isotopically labeled <i>tert</i>-butan<sup>18</sup>ol also lead to an experimental determination
of the branching ratio for the β-scission pathways of the <i>tert</i>-C<sub>4</sub>H<sub>8</sub>OH radical by comparing the
measured pseudo-first-order decay rate of <sup>16</sup>OH in the presence
of excess <i>tert</i>-butan<sup>16</sup>ol with the respective
decay rate of <sup>16</sup>OH in the presence of excess <i>tert</i>-butan<sup>18</sup>ol. The two decay rates of <sup>16</sup>OH as
a result of reactions with the two forms of <i>tert</i>-butanol
differ by approximately a factor of 5 due to the absence of <sup>16</sup>OH-producing pathways in experiments with <i>tert</i>-butan<sup>18</sup>ol. This indicates that 80% of the <sup>16</sup>OH molecules
that react with <i>tert</i>-butan<sup>16</sup>ol will reproduce
another <sup>16</sup>OH molecule through β-scission of the resulting <i>tert</i>-C<sub>4</sub>H<sub>8</sub><sup>16</sup>OH radical. <sup>16</sup>OH mole fraction time histories were measured using narrow-line-width
laser absorption near 307 nm. Measurements were performed at the line
center of the R<sub>22</sub>(5.5) transition in the A–XÂ(0,0)
band of <sup>16</sup>OH, a transition that does not overlap with any
absorption features of <sup>18</sup>OH, hence yielding a measurement
of <sup>16</sup>OH mole fraction that is insensitive to any production
of <sup>18</sup>OH