12,934 research outputs found
Optimal control of electromagnetic field using metallic nanoclusters
The dielectric properties of metallic nanoclusters in the presence of an
applied electromagnetic field are investigated using non-local linear response
theory. In the quantum limit we find a non-trivial dependence of the induced
field and charge distribution on the spatial separation between the clusters
and on the frequency of the driving field. Using a genetic algorithm, these
quantum functionalities are exploited to custom-design sub-wavelength lenses
with a frequency controlled switching capability.Comment: accepted for publication in New Journal of Physic
Thermal noise of whispering gallery resonators
By direct application of the fluctuation-dissipation theorem, we numerically
calculate the fundamental dimensional fluctuations of crystalline CaF2
whispering gallery resonators in the case of structural damping, and the limit
that this noise imposes on the frequency stability of such resonators at both
room and cryogenic temperatures. We analyze elasto-optic noise - the effect of
Brownian dimensional fluctuation on frequency via the strain-dependence of the
refractive index - a noise term that has so far not been considered for
whispering-gallery resonators. We find that dimensional fluctuation sets a
lower limit of 1E-16 to the Allan deviation for a 10-millimeter-radius sphere
at 5 K, predominantly via induced fluctuation of the refractive index.Comment: 7 pages, 3 figure
Adaptive Design of Excitonic Absorption in Broken-Symmetry Quantum Wells
Adaptive quantum design is used to identify broken-symmetry quantum well
potential profiles with optical response properties superior to previous ad-hoc
solutions. This technique performs an unbiased stochastic search of
configuration space. It allows us to engineer many-body excitonic wave
functions and thus provides a new methodology to efficiently develop optimized
quantum confined Stark effect device structures.Comment: 4 pages, 3 encapsulated postscript figure
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Palladium-Catalyzed Oxidation of β-C(sp3)-H Bonds of Primary Alkylamines through a Rare Four-Membered Palladacycle Intermediate.
Site-selective functionalizations of C-H bonds are often achieved with a directing group that leads to five- or six-membered metallacyclic intermediates. Analogous reactions that occur through four-membered metallacycles are rare. We report a challenging palladium-catalyzed oxidation of primary C-H bonds β to nitrogen in an imine of an aliphatic amine, a process that occurs through a four-membered palladacyclc intermediate. The success of the reaction relies on the identification, by H/D exchange, of a simple directing group (salicylaldehyde) capable of inducing the formation of this small ring. To gain insight into the steps of the catalytic cycle of this unusual oxidation reaction, a series of mechanistic experiments and density functional theory (DFT) calculations were conducted. The experimental studies showed that cleavage of the C-H bond is rate-limiting and formation of the strained four-membered palladacycle is thermodynamically uphill. DFT calculations corroborated these conclusions and suggested that the presence of an intramolecular hydrogen bond between the oxygen of the directing group and hydroxyl group of the ligating acetic acid is crucial for stabilization of the palladacyclic intermediate
Exact results for SU(3) spin chains: trimer states, valence bond solids, and their parent Hamiltonians
We introduce several exact models for SU(3) spin chains: (1) a
translationally invariant parent Hamiltonian involving four-site interactions
for the trimer chain, with a three-fold degenerate ground state. We provide
numerical evidence that the elementary excitations of this model transform
under representation 3bar of SU(3) if the original spins of the model transform
under rep. 3. (2) a family of parent Hamiltonians for valence bond solids of
SU(3) chains with spin reps. 6, 10, and 8 on each lattice site. We argue that
of these three models, only the latter two exhibit spinon confinement and a
Haldane gap in the excitation spectrum
Influence of coating on the thermal resistance of a Ni-Based superalloy
In this paper, the influence of M-CrAlY polycrystalline coating on the thermal fatigue behavior of a Nickel-base superalloy has been investigated. A special device using a rotating bending machine and two thermal sources has been used to perform thermo-mechanical tests. The two thermal sources have been set to obtain temperature variations between 750 and 1120 °C in the central part of the specimens, with a frequency of 0.1 Hz. The results showed a deleterious effect of the coating on the fatigue resistance. Numerical simulations have been carried out on SAMCEF to determine the thermo-mechanical field of the so-tested specimens. Calculated thermo-mechanical cycles of critical sites are associated with microstructure evolution and damage by cracking observed on the specimens. Damage mechanisms related to the presence of coating are discussed
A survey of users of earth resources remote sensing data
The results of a NASA supported Battelle survey to obtain user views on the nature and value of LANDSAT data use, on current LANDSAT capabilities, and on ways to improve data use were summarized. Questionnaire and interview responses from over 1000 private and public sector users were analyzed and discussed
Adaptive design of nano-scale dielectric structures for photonics
Using adaptive algorithms, the design of nano-scale dielectric structures for
photonic applications is explored. Widths of dielectric layers in a linear
array are adjusted to match target responses of optical transmission as a
function of energy. Two complementary approaches are discussed. The first
approach uses adaptive local random updates and progressively adjusts
individual dielectric layer widths. The second approach is based on global
updating functions in which large subgroups of layers are adjusted
simultaneously. Both schemes are applied to obtain specific target responses of
the transmission function within selected energy windows, such as discontinuous
cut-off or power-law decay filters close to a photonic band edge. These
adaptive algorithms are found to be effective tools in the custom design of
nano-scale photonic dielectric structures.Comment: 4 pages Revtex, 4 embedded EPS figure
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