9 research outputs found
Line formation in convective stellar atmospheres. I. Granulation corrections for solar photospheric abundances
In an effort to estimate the largely unknown effects of photospheric
temperature fluctuations on spectroscopic abundance determinations, we have
studied the problem of LTE line formation in the inhomogeneous solar
photosphere based on detailed 2-dimensional radiation hydrodynamics simulations
of the convective surface layers of the Sun. By means of a strictly
differential 1D/2D comparison of the emergent equivalent widths, we have
derived "granulation abundance corrections" for individual lines, which have to
be applied to standard abundance determinations based on homogeneous 1D model
atmospheres in order to correct for the influence of the photospheric
temperature fluctuations. In general, we find a line strengthening in the
presence of temperature inhomogeneities as a consequence of the non-linear
temperature dependence of the line opacity. For many lines of practical
relevance, the magnitude of the abundance correction may be estimated from
interpolation in the tables and graphs provided with this paper. The
application of abundance corrections may often be an acceptable alternative to
a detailed fitting of individual line profiles based on hydrodynamical
simulations. The present study should be helpful in providing upper bounds for
possible errors of spectroscopic abundance analyses, and for identifying
spectral lines which are least sensitive to the influence of photospheric
temperature inhomogeneities.Comment: Accepted by A&
Rapid Alloy Development of Extremely High-Alloyed Metals Using Powder Blends in Laser Powder Bed Fusion
The design of new alloys by and for metal additive manufacturing (AM) is an emerging field of research. Currently, pre-alloyed powders are used in metal AM, which are expensive and inflexible in terms of varying chemical composition. The present study describes the adaption of rapid alloy development in laser powder bed fusion (LPBF) by using elemental powder blends. This enables an agile and resource-efficient approach to designing and screening new alloys through fast generation of alloys with varying chemical compositions. This method was evaluated on the new and chemically complex materials group of multi-principal element alloys (MPEAs), also known as high-entropy alloys (HEAs). MPEAs constitute ideal candidates for the introduced methodology due to the large space for possible alloys. First, process parameters for LPBF with powder blends containing at least five different elemental powders were developed. Secondly, the influence of processing parameters and the resulting energy density input on the homogeneity of the manufactured parts were investigated. Microstructural characterization was carried out by optical microscopy, electron backscatter diffraction (EBSD), and energy-dispersive X-ray spectroscopy (EDS), while mechanical properties were evaluated using tensile testing. Finally, the applicability of powder blends in LPBF was demonstrated through the manufacture of geometrically complex lattice structures with energy absorption functionality
On atomic mechanisms governing the oxidation of Bi2 Te3
Oxidation of Bi2Te3 (space group R (3) over barm) has been investigated using experimental and theoretical means. Based on calorimetry, x-ray photoelectron spectroscopy and thermodynamic modelling, Bi2Te3 is at equilibrium with Bi2O3 and TeO2, whereby the most stable compound is Bi2Te3, followed by Bi2O3. The reactivity of Bi towards oxygen is expected to be higher than that of Te. This notion is supported by density functional theory. The strongest bond is formed between Bi and Te, followed by Bi-O. This gives rise to unanticipated atomic processes. Dissociatively adsorbed oxygen diffuses through Bi and Te basal planes of Bi2Te3(0 0 0 1) and preferably interacts with Bi. The Te termination considerably retards this process. These findings may clarify conflicting literature data. Any basal plane off-cut or Bi terminations trigger oxidation, but a perfect basal cleavage, where only Te terminations are exposed to air, may be stable for a longer period of time. These results are of relevance for applications in which surfaces are of key importance, such as nanostructured Bi2Te3 thermoelectric devices
NF135.C10: a new Plasmodium falciparum clone for controlled human malaria infections
Item does not contain fulltextWe established a new field clone of Plasmodium falciparum for use in controlled human malaria infections and vaccine studies to complement the current small portfolio of P. falciparum strains, primarily based on NF54. The Cambodian clone NF135.C10 consistently produced gametocytes and generated substantial numbers of sporozoites in Anopheles mosquitoes and diverged from NF54 parasites by genetic markers. In a controlled human malaria infection trial, 3 of 5 volunteers challenged by mosquitoes infected with NF135.C10 and 4 of 5 challenged with NF54 developed parasitemia as detected with microscopy. The 2 strains induced similar clinical signs and symptoms as well as cellular immunological responses. CLINICAL TRIALS REGISTRATION: NCT01002833