14 research outputs found
Droplet Memory on Liquid-Infused Surfaces
The knowledge of droplet friction on liquid-infused surfaces
(LIS)
is of paramount importance for applications involving liquid manipulation.
While the possible dissipation mechanisms are well-understood, the
effect of surface texture has thus far been mainly investigated on
LIS with highly regular solid topographies. In this work, we aim to
address this experimental gap by studying the friction experienced
by water droplets on LIS based on both random and regular polysilsesquioxane
nanostructures. We show that the available models apply to the tested
surfaces, but we observe a previously unreported droplet memory effect:
as consecutive droplets travel along the same path, their velocity
increases up to a plateau value before returning to the original state
after a sufficiently long time. We study the features of this phenomenon
by evaluating the motion of droplets when they cross the path of a
previous sequence of droplets, discovering that moving droplets create
a low-friction trace in their wake, whose size matches their base
diameter. Finally, we attribute this to the temporary smoothing out
of an initially conformal lubricant layer by means of a Landau–Levich–Derjaguin
liquid film deposition behind the moving droplet. The proposed mechanism
might apply to any LIS with a conformal lubricant layer
Measurement of sub-4 nm particle emission from FFF-3D printing with the TSI Nano Enhancer and the Airmodus Particle Size Magnifier
The emission of ultrafine particles from small desktop Fused Filament Fabrication (FFF) 3D printers has been frequently investigated in the past years. However, the vast majority of FFF emission and exposure studies have not considered the possible occurrence of particles below the typical detection limit of Condensation Particle Counters and could have systematically underestimated the total particle emission as well as the related exposure risks. Therefore, we comparatively measured particle number concentrations and size distributions of sub-4 nm particles with two commercially available diethylene glycol-based instruments – the TSI 3757 Nano Enhancer and the Airmodus A10 Particle Size Magnifier. Both instruments were evaluated for their suitability of measuring FFF-3D printing emissions in the sub-4 nm size range while operated as a particle counter or as a particle size spectrometer. For particle counting, both instruments match best when the Airmodus system was adjusted to a cut-off of 1.5 nm. For size spectroscopy, both instruments show limitations due to either the fast dynamics or rather low levels of particle emissions from FFF-3D printing in this range. The effects are discussed in detail in this article. The findings could be used to implement sub-4 nm particle measurement in future emission or exposure studies, but also for the development of standard test protocols for FFF-3D printing emissions.</p
Three-Dimensional Organization of Surface-Bound Silicone Nanofilaments Revealed by Focused Ion Beam Nanotomography
One-dimensional (1D) nanostructures
have been identified as key
technology for future devices and integrated into surface-bound materials.
The roughness of surface-bound 1D silicone nanofilaments (SNFs) has
been used extensively to create surfaces with extreme wetting properties
and as carrier material. Electron microscopy has shown that this material
is made of individual filaments with diameters spanning tens of nanometers
and a length of several micrometers which arrange into a highly entangled
quasi-porous network. However, a comprehensive analysis of the three-dimensional
(3D) superstructure has remained elusive so far. In this study, focused
ion beam nanotomography (FIB-nt) is used to quantify the otherwise
hardly accessible structural parameters roughness (12.68) and volume
fraction (2.80). The volume fraction is anisotropic, and two major
species of SNFs are quantified to contribute equally to the overall
surface area. Spatial statistics reveals a self-avoiding growth pattern
of SNFs over the substrate, and a 3D model of the data is rendered.
The presented analysis therefore significantly advances the understanding
of SNF surface coatings with regard to their structure at the nano-
and microscale. Finally, the described procedure may serve as a useful
tool to analyze other surface-bound 1D nanostructures of similar complex
arrangement
Superficial Dopants Allow Growth of Silicone Nanofilaments on Hydroxyl-Free Substrates
We
report new types of silicone nanostructures by a gas-phase reaction
of trichloromethylsilane: 1-D silicone nanofilaments with a raveled
end and silicone nanoteeth. Filaments with a raveled end are obtained
on poly(vinyl chloride), which is superficially doped with the detergent
Span 20. Silicone nanoteeth grow on sodium chloride using dibutyl
phthalate as superficial dopant. Without dopants, no structures are
observed. The dopants are identified by mass spectroscopy and the
silicone nanostructures are analyzed by infrared spectroscopy and
energy-dispersive analysis of X-rays. The growth of silicone nanostructures
on a hydrophobic substrate (poly(vinyl chloride)/Span 20) and a substrate
free of hydroxyl groups (sodium chloride/dibutyl phthalate) questions
the currently discussed mechanisms for the growth of 1-D silicone
nanofilaments, which is discussed. We suggest superficial doping as
an alternative pretreatment method to oxidizing activation and prove
this principle by the successful coating of copper, which is superficially
doped with Span 20
Life Cycle Assessment of a New Technology To Extract, Functionalize and Orient Cellulose Nanofibers from Food Waste
A new technology for the production
of cellulose nanofibers from
vegetable food waste has been developed. The fibers are liberated
enzymatically, given a functionalized coating and oriented using spinning
techniques. We performed a laboratory-scale life cycle assessment
(LCA) to assess the various routes of the entire production process
from an environmental perspective. The results indicate that the electrospinning
process has a higher impact than the alternative wet spinning process
under the conditions described. Furthermore, to improve the liberation
process of the microfibrillated cellulose, the enzymatic treatment
step requires development; this could be through optimization of energy
use in the heating process, mainly by reducing heat loss and water
use. A comparative LCA with the results of other published studies,
using different starting materials and chemical processes to obtain
nanocellulose, provides a deeper understanding of our processes. From
this comparison, we conclude that our technology has the potential
to become a competitive alternative, outperforming other nanocellulose
technologies from an environmental perspective
Polysiloxane Nanotubes
The
synthesis of polysiloxane nanotubes using trifunctional organosilanes
is reported. Tubular nanostructures were formed via a chemical vapor
deposition technique at room temperature when ethyltrichlorosilane
is used or via a liquid phase method when methyltriethoxysilane is
used as precursor. In the chemical vapor deposition process the shape
of the tubes was controlled by changing the water content in the reaction
chamber prior to coating. The diameter varied between 60 and 4000
nm. While in the case of the liquid phase method nanotubes with very
high aspect ratios of 800 are produced. Parameters, such as length
and diameter of the various tubes, were investigated using scanning
electron microscopy and transmission electron microscopy. Additionally,
the chemical composition of produced structures was analyzed using
attenuated total reflectance-infrared and energy-dispersive X-ray
spectroscopy. Glass substrates coated with such structures exhibit
extreme superhydrophobic properties
Polysiloxane Nanotubes
The
synthesis of polysiloxane nanotubes using trifunctional organosilanes
is reported. Tubular nanostructures were formed via a chemical vapor
deposition technique at room temperature when ethyltrichlorosilane
is used or via a liquid phase method when methyltriethoxysilane is
used as precursor. In the chemical vapor deposition process the shape
of the tubes was controlled by changing the water content in the reaction
chamber prior to coating. The diameter varied between 60 and 4000
nm. While in the case of the liquid phase method nanotubes with very
high aspect ratios of 800 are produced. Parameters, such as length
and diameter of the various tubes, were investigated using scanning
electron microscopy and transmission electron microscopy. Additionally,
the chemical composition of produced structures was analyzed using
attenuated total reflectance-infrared and energy-dispersive X-ray
spectroscopy. Glass substrates coated with such structures exhibit
extreme superhydrophobic properties
Evaporation-Induced Transition from <i>Nepenthes</i> Pitcher-Inspired Slippery Surfaces to Lotus Leaf-Inspired Superoleophobic Surfaces
The newly developed <i>Nepenthes</i> pitcher (NP)-inspired
slippery surfaces, formed by immobilizing fluoroliquids on lotus leaf
(LL)-inspired superoleophobic surfaces, are of great general interest,
whereas there are many interesting phenomena and fundamental scientific
issues remaining to be unveiled. Here we present our findings of the
effects of evaporation of the fluoroliquid, an inevitable process
in most cases, -induced transition from NP-inspired to LL-inspired
surfaces on the wettability, transparency, and self-cleaning property
of the surfaces. The transition is controlled by regulating the evaporation
temperature of the model fluoroliquid, Krytox100. The evaporation
of Krytox100 has great a influence on the wettability, transparency,
and self-cleaning property. An intermediate “sticky”
state is observed in the transition process. We believe that our findings
in the transition process are helpful in understanding the similarities
and differences between the NP-inspired and LL-inspired surfaces and
in designing new bioinspired antiwetting surfaces and exploring their
potential applications
Protein Biomineralized Nanoporous Inorganic Mesocrystals with Tunable Hierarchical Nanostructures
Mesocrystals
with the symmetry defying morphologies and highly
ordered superstructures composed of primary units are of particular
interest, but the fabrication has proved extremely challenging. A
novel strategy based on biomineralization approach for the synthesis
of hematite mesocrystals is developed by using silk fibroin as a biotemplate.
The resultant hematite mesocrystals are uniform, highly crystalline,
and porous nanostructures with tunable size and morphologies by simply
varying the concentration of the silk fibroin and iron(III) chloride
in this biomineralization system. In particular, we demonstrate a
complex mesoscale biomineralization process induced by the silk fibroin
for the formation of hematite mesocrystals. This biomimetic strategy
features precisely tunable, high efficiency, and low-cost and opens
up an avenue to access new novel functional mesocrystals with hierarchical
structures in various practical applications
Superwetting Double-Layer Polyester Materials for Effective Removal of Both Insoluble Oils and Soluble Dyes in Water
Inspired
by the mussel adhesive protein and the lotus leaf, Ag-based
double-layer polyester (DL-PET) textiles were fabricated for effective
removal of organic pollutants in water. The DL-PET textiles are composed
of a top superamphiphilic layer and a bottom superhydrophobic/superoleophilic
layer. First, the PET textiles were modified with a layer of polydopamine
(PDA) and deposited with Ag nanoparticles to form the PET@PDA@Ag textiles.
The top superamphiphilic layer, formed by immobilizing Ag<sub>3</sub>PO<sub>4</sub> nanoparticles on the PET@PDA@Ag textile, shows excellent
visible-light photocatalytic activity. The bottom superhydrophobic/superoleophilic
layer, formed by modifying the PET@PDA@Ag textile using dodecyl mercaptan,
is mechanically, environmentally, and chemically very stable. The
water-insoluble oils with low surface tension can penetrate both layers
of the DL-PET textiles, while the water with soluble organic dyes
can only selectively wet the top layer owing to their unique wettability.
Consequently, the water-soluble organic contaminants in the collected
water can be decomposed by the Ag<sub>3</sub>PO<sub>4</sub> nanoparticles
of the top layer under visible-light irradiation or even sunlight
in room conditions. Thus, the DL-PET textiles can remove various kinds
of organic pollutants in water including both insoluble oils and soluble
dyes. The DL-PET textiles feature unique wettability, high oil/water
separation efficiency, and visible-light photocatalytic activity