26 research outputs found
Demystification of Entangled Mass Action Law
Recently, Gorban (2021) analysed some kinetic paradoxes of the transition
state theory and proposed its revision that gave the ``entangled mass action
law'', in which new reactions were generated as an addition to the reaction
mechanism under consideration. These paradoxes arose due to the assumption of
quasiequilibrium between reactants and transition states.
In this paper, we provided a brief introduction to this theory, demonstrating
how the entangled mass action law equations can be derived in the framework of
the standard quasi steady state approximation in combination with the
quasiequilibrium generalized mass action law for an auxiliary reaction network
including reactants and intermediates. We also proved the basic physical
property (positivity) for these new equations, which was not obvious in the
original approach.Comment: Minor correction
ПРОЕКТ ЕНЕРГЕТИЧНОЇ БЕЗПЕКИ УКРАЇНИ НА ОСНОВІ ВЛАСНИХ ГЕОТЕРМАЛЬНИХ РЕСУРСІВ
The article presents the main components of energy and public safety through the development of geothermal resources in Ukraine. The development of geothermal resources is performed by geothermal power plants construction (GPPC) type, tube in tube "that do not require fuel resources, does not produce harmful emissions into the environment and are able to provide all spheres of society own thermal and electrical energy in sufficient amount. The data from the GPPC theory and technology of construction, industrial feasibility, socio-economic and ecological effectiveness are presented.В статті наведені основні складові енергетичної і екологічної безпеки суспільства на основі освоєння геотермальних ресурсів України. Освоєння геотермальних ресурсів виконується шляхом спорудження геотермальних енергоустановок (ГТЕУ) типу ,,труба в трубі”, що не потребують паливних ресурсів, не виробляють шкідливих викидів у довкілля і здатні забезпечити всі сфери діяльності суспільства власною тепловою і електричною енергією в достатній кількості. Наведені відомості з теорії ГТЕУ, техніки і технології їх спорудження, промислової доцільності, соціально-економічної та екологічної ефективності
Izloženost genotoksičnim agensima iz životnog okoliša tijekom prenatalnog razvoja i djetinjstva
Health disorders and diseases related to environmental exposure in children such as cancer and immunologic disturbances (asthma, allergies) are on the rise. However, complex transplacental and prepubertal genotoxicology is given very limited consideration, even though intrauterine development and early childhood may be critical for elucidating the cancer aetiology. The foetus is transplacentally exposed to contaminants in food and environment such as various chemicals, drugs, radiochemically contaminated water and air. Target organs of xenobiotic action may differ between the mother and the foetus due to specific stage of developmental physiology and enzyme distribution. This in turn may lead to different levels of clastogenic and aneugenic metabolites of the same xenobiotic in the mother and the foetus. Adult’s protective behaviour is not sufficient to isolate children from radioisotopes, pesticides, toxic metals and metalloids, environmental tobacco smoke, endocrine disrupting chemicals, and various food contaminants, which are just a part of the stressors present in a polluted environment. In order to improve legislation related to foetus and child exposure to genotoxic and possibly carcinogenic agents, oncologists, paediatricians, environmental health specialists, and genotoxicologists should work together much more closely to make a more effective use of accumulated scientific data, with the final aim to lower cancer incidence and mortality.Unatoč velikim naporima da se smanji okolišna izloženost u djece se dalje bilježi trend porasta pojavnosti karcinoma i imunosnih poremećaja (astma, alergije). Premda su intrauterini razvoj i rano djetinjstvo kritično razdoblje za tumačenje etiologije nastanka karcinoma, transplacentalna i prepubertetna genotoksikologija
do danas su slabo istražene. Fetus je transplacentalno izložen brojnim fizikalnim i kemijskim čimbenicima: kontaminantima iz hrane i okoliša, radiokemijski kontaminiranoj vodi, zraku te lijekovima. Ciljna tkiva za djelovanje ksenobiotika mogu biti različita u majke i fetusa zbog različitosti u razvojnoj fiziologiji i distribuciji enzima. Zbog toga u organizmu majke i fetusa mogu nastati različite razine klastogenih i aneugenih metabolita istog ksenobiotika.
Zaštitna uloga odraslih u namjeri da spriječe negativne utjecaje onečišćenog okoliša na djetetovo zdravlje često je ograničena jer su radioizotopi, olovo, PCB, pasivno pušenje, živa, endokrino aktivne tvari, pesticidi i kontaminanti prisutni u svim životnim područjima tijekom razvoja i rasta djeteta. Kako bi se poboljšalo zakonodavstvo vezano uz izloženost djece genotoksičnim i vjerojatno kancerogenim tvarima, tijekom razvoja potrebna je bolja suradnja onkologa, pedijatara, stručnjaka zdravstvene ekologije i genotoksikologa.
Na taj način ostvarilo bi se uspješnije iskorištavanje postojećih znanstvenih podataka u cilju smanjenja incidencije karcinoma i mortaliteta
Estudio Parto: postpartum diabetes prevention program for hispanic women with abnormal glucose tolerance in pregnancy: a randomised controlled trial – study protocol
Ukraine Energy Security Project On The Basis Of Own Geothermal Resources
The article presents the main components of energy and public safety through the development of geothermal resources in Ukraine. The development of geothermal resources is performed by geothermal power plants construction (GPPC) type, tube in tube "that do not require fuel resources, does not produce harmful emissions into the environment and are able to provide all spheres of society own thermal and electrical energy in sufficient amount. The data from the GPPC theory and technology of construction, industrial feasibility, socio-economic and ecological effectiveness are presented