9 research outputs found

    Back in Time? A Temporal Autobiographical Approach to Afghan Return Migration

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    Repatriation programmes for refugees and asylum seekers are based on the assumption that going ‘home’ is the most desirable thing to do to restore the social order that was disrupted by conflict. Yet the often-limited success of these programmes as migration management solutions, shown in poor reintegration results and re-emigration, shows that there is a need for a better understanding of the lived experiences of (return) migrants. This article studies Afghan managed and “spontaneous” return migrants from Europe through an innovative temporal autobiographical approach, using both verbal and creative participatory narrative methods. I find that some migration movements were experienced as disruptive, while others were not, and that return sometimes meant a return to a previous life, sometimes a continuation, and sometimes the start of something new. I conclude that migration management programmes aimed towards “durable solutions” and the wellbeing of returnees should enable rather than constrain post-return mobility

    Examining the Role of Aryldiazonium Salts in Surface Electroinitiated Polymerization

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    Historically, the irreversible reduction of aryldiazonium salts has provided a reliable method to modify surfaces, demonstrating a catalogue of suitable diazonium salts for targeted applications. This work expands the knowledge of diazonium salt chemistry to participate in surface electroinitiated emulsion polymerization (SEEP). The influence of concentration, electronic effects, and steric hindrance/regiochemistry of the diazonium salt initiator on the production of polymeric films is examined. The objective of this work is to determine if a polymer film can be tailored, controlling the thickness, density, and surface homogeneity using specific diazonium chemistry. The data presented herein demonstrate a significant difference in polymer films that can be achieved when selecting a variety of diazonium salts and vinylic monomers. A clear trend aligns with the electron-rich diazonium salt substitution providing the thickest films (up to 70.9 ± 17.8 nm) with increasing diazonium concentration and electron-withdrawing substitution achieving optimal homogeneity for the surface of the film at a 5 mM diazonium concentration.</p

    The antibody paradigm: present and future development as a scaffold for biopharmaceutical drugs.

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    The antibody paradigm: present and future development as a scaffold for biopharmaceutical drugs

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