Van der Waals interactions: Evaluations by use of a statistical mechanical method

In this work the induced van der Waals interaction between a pair of neutral atoms or molecules is considered by use of a statistical mechanical method. Commonly this interaction is obtained by standard quantum mechanical perturbation theory to second order. However, the latter is restricted to electrostatic interactions between charges and dipole moments. So with radiating dipole-dipole interaction where retardation effects are important for large separations of the particles, other methods are needed, and the resulting induced interaction is the Casimir-Polder interaction usually obtained by field theory. It can also be evaluated, however, by a statistical mechanical method that utilizes the path integral representation. We here show explicitly by use of the statistical mechanical method the equivalence of the Casimir-Polder and van der Waals interactions to leading order for short separations where retardation effects can be neglected. Physically this is well known, but in our opinion the mathematics of this transition process is not so obvious. The evaluations needed mean a transform of the statistical mechanical free energy expression to a form that can be identified with second order perturbation theory. In recent works [H{\o}ye 2010] the Casimir-Polder or Casimir energy has been added as a correction to calculations of systems like the electron clouds of molecules. The equivalence to van der Waals interactions to leading order indicates that the added Casimir energy will improve the accuracy of calculated molecular energies. We here also give numerical estimates of this energy including analysis and estimates for the uniform electron gas

Universal behavior of dispersion forces between two dielectric plates in the low-temperature limit

The universal analytic expressions in the limit of low temperatures (short separations) are obtained for the free energy, entropy and pressure between the two parallel plates made of any dielectric. The analytical proof of the Nernst heat theorem in the case of dispersion forces acting between dielectrics is provided. This permitted us to formulate the stringent thermodynamical requirement that must be satisfied in all models used in the Casimir physics.Comment: 6 pages, iopart.cls is used, to appear in J. Phys. A (special issue: Proceedings of QFEXT05, Barcelona, Sept. 5-9, 2005

Derivation of the Cubic Non-linear Schr\"odinger Equation from Quantum Dynamics of Many-Body Systems

We prove rigorously that the one-particle density matrix of three dimensional interacting Bose systems with a short-scale repulsive pair interaction converges to the solution of the cubic non-linear Schr\"odinger equation in a suitable scaling limit. The result is extended to $k$-particle density matrices for all positive integer $k$.Comment: 72 pages, 17 figures. Final versio

Spatial correlations of vacuum fluctuations and the Casimir-Polder potential

We calculate the Casimir-Polder intermolecular potential using an effective Hamiltonian recently introduced. We show that the potential can be expressed in terms of the dynamical polarizabilities of the two atoms and the equal-time spatial correlation of the electric field in the vacuum state. This gives support to an interesting physical model recently proposed in the literature, where the potential is obtained from the classical interaction between the instantaneous atomic dipoles induced and correlated by the vacuum fluctuations. Also, the results obtained suggest a more general validity of this intuitive model, for example when external boundaries or thermal fields are present.Comment: 7 page

Using atomic interference to probe atom-surface interaction

We show that atomic interference in the reflection from two suitably polarized evanescent waves is sensitive to retardation effects in the atom-surface interaction for specific experimental parameters. We study the limit of short and long atomic de Broglie wavelength. The former case is analyzed in the semiclassical approximation (Landau-Zener model). The latter represents a quantum regime and is analyzed by solving numerically the associated coupled Schroedinger equations. We consider a specific experimental scheme and show the results for rubidium (short wavelength) and the much lighter meta-stable helium atom (long wavelength). The merits of each case are then discussed.Comment: 11 pages, including 6 figures, submitted to Phys. Rev. A, RevTeX sourc

The structure of the atomic helium trimers: Halos and Efimov states

The Faddeev equations for the atomic helium-trimer systems are solved numerically with high accuracy both for the most sophisticated realistic potentials available and for simple phenomenological potentials. An efficient numerical procedure is described. The large-distance asymptotic behavior, crucial for weakly bound three-body systems, is described almost analytically for arbitrary potentials. The Efimov effect is especially considered. The geometric structures of the bound states are quantitatively investigated. The accuracy of the schematic models and previous computations is comparable, i.e. within 20% for the spatially extended states and within 40% for the smaller ^4He-trimer ground state.Comment: 32 pages containing 7 figures and 6 table

A Rigorous Derivation of the Gross-Pitaevskii Energy Functional for a Two-Dimensional Bose Gas

We consider the ground state properties of an inhomogeneous two-dimensional Bose gas with a repulsive, short range pair interaction and an external confining potential. In the limit when the particle number $N$ is large but $\bar\rho a^2$ is small, where $\bar\rho$ is the average particle density and $a$ the scattering length, the ground state energy and density are rigorously shown to be given to leading order by a Gross-Pitaevskii (GP) energy functional with a coupling constant $g\sim 1/|\ln(\bar\rho a^2)|$. In contrast to the 3D case the coupling constant depends on $N$ through the mean density. The GP energy per particle depends only on $Ng$. In 2D this parameter is typically so large that the gradient term in the GP energy functional is negligible and the simpler description by a Thomas-Fermi type functional is adequate.Comment: 14 pages, no figures, latex 2e. References, some clarifications and an appendix added. To appear in Commun. Math. Phy

Semiclassical Estimates of Electromagnetic Casimir Self-Energies of Spherical and Cylindrical Metallic Shells

The leading semiclassical estimates of the electromagnetic Casimir stresses on a spherical and a cylindrical metallic shell are within 1% of the field theoretical values. The electromagnetic Casimir energy for both geometries is given by two decoupled massless scalars that satisfy conformally covariant boundary conditions. Surface contributions vanish for smooth metallic boundaries and the finite electromagnetic Casimir energy in leading semiclassical approximation is due to quadratic fluctuations about periodic rays in the interior of the cavity only. Semiclassically the non-vanishing Casimir energy of a metallic cylindrical shell is almost entirely due to Fresnel diffraction.Comment: 12 pages, 2 figure

Matter-field theory of the Casimir force

A matter-field theory of the Casimir force is formulated in which the electromagnetic field and collective modes of dielectric media are treated on an equal footing. In our theory, the Casimir force is attributed to zero-point energies of the combined matter-field modes. We analyze why some of the existing theories favor the interpretation of the Casimir force as originating from zero-point energies of the electromagnetic field and others from those of the matter.Comment: 12pages, 1 Postscript figur

Retarded long-range potentials for the alkali-metal atoms and a perfectly conducting wall

The retarded long-range potentials for hydrogen and alkali-metal atoms in their ground states and a perfectly conducting wall are calculated. The potentials are given over a wide range of atom-wall distances and the validity of the approximations used is established.Comment: RevTeX, epsf, 11 pages, 2 fig