2,791 research outputs found
Enhanced Raman and photoluminescence response in monolayer MoS due to laser healing of defects
Bound quasiparticles, negatively charged trions and neutral excitons, are
associated with the direct optical transitions at the K-points of the Brillouin
zone for monolayer MoS. The change in the carrier concentration,
surrounding dielectric constant and defect concentration can modulate the
photoluminescence and Raman spectra. Here we show that exposing the monolayer
MoS in air to a modest laser intensity for a brief period of time enhances
simultaneously the photoluminescence (PL) intensity associated with both trions
and excitons, together with 3 to 5 times increase of the Raman intensity
of first and second order modes. The simultaneous increase of PL from trions
and excitons cannot be understood based only on known-scenario of depletion of
electron concentration in MoS by adsorption of O and HO molecules.
This is explained by laser induced healing of defect states resulting in
reduction of non-radiative Auger processes. This laser healing is corroborated
by an observed increase of intensity of both the first order and second order
2LA(M) Raman modes by a factor of 3 to 5. The A mode hardens by
1.4 cm whereas the E mode softens by 1 cm.
The second order 2LA(M) Raman mode at 440 cm shows an increase in
wavenumber by 8 cm with laser exposure. These changes are a
combined effect of change in electron concentrations and oxygen-induced lattice
displacements.Comment: 15 pages, 5 figures, Journal of Raman Spectroscopy, 201
Pneumothorax and Pneumomediastinum in a Sputum Positive Tuberculosis Patient: The Continuous Diaphragm Sign
Secondary pneumothorax is a very common medical emergency. At times it is associated with pneumomediastinum, which could be fatal at times if not identified. We present a case of a 11 years old sputum positive child who presented with both these conditions and was diagnosed on chest x ray
Phonon Anomalies, Orbital-Ordering and Electronic Raman Scattering in iron-pnictide Ca(Fe0.97Co0.03)2As2: Temperature-dependent Raman Study
We report inelastic light scattering studies on Ca(Fe0.97Co0.03)2As2 in a
wide spectral range of 120-5200 cm-1 from 5K to 300K, covering the tetragonal
to orthorhombic structural transition as well as magnetic transition at Tsm ~
160K. The mode frequencies of two first-order Raman modes B1g and Eg, both
involving displacement of Fe atoms, show sharp increase below Tsm.
Concomitantly, the linewidths of all the first-order Raman modes show anomalous
broadening below Tsm, attributed to strong spin-phonon coupling. The high
frequency modes observed between 400-1200 cm-1 are attributed to the electronic
Raman scattering involving the crystal field levels of d-orbitals of Fe2+. The
splitting between xz and yz d-orbital levels is shown to be ~ 25 meV which
increases as temperature decreases below Tsm. A broad Raman band observed at ~
3200 cm-1 is assigned to two-magnon excitation of the itinerant Fe 3d
antiferromagnet.Comment: Accepted for Publication in JPC
Symmetry-dependent phonon renormalization in monolayer MoS2 transistor
Strong electron-phonon interaction which limits electronic mobility of
semiconductors can also have significant effects on phonon frequencies. The
latter is the key to the use of Raman spectroscopy for nondestructive
characterization of doping in graphene-based devices. Using in-situ Raman
scattering from single layer MoS electrochemically top-gated field effect
transistor (FET), we show softening and broadening of A phonon with
electron doping whereas the other Raman active E mode remains
essentially inert. Confirming these results with first-principles density
functional theory based calculations, we use group theoretical arguments to
explain why A mode specifically exhibits a strong sensitivity to
electron doping. Our work opens up the use of Raman spectroscopy in probing the
level of doping in single layer MoS-based FETs, which have a high on-off
ratio and are of enormous technological significance.Comment: 5 pages, 3 figure
Metallic monoclinic phase in VO induced by electrochemical gating: in-situ Raman study
We report in-situ Raman scattering studies of electrochemically top gated
VO thin film to address metal-insulator transition (MIT) under gating. The
room temperature monoclinic insulating phase goes to metallic state at a gate
voltage of 2.6 V. However, the number of Raman modes do not change with
electrolyte gating showing that the metallic phase is still monoclinic. The
high frequency Raman mode A(7) near 616 cm ascribed to V-O vibration
of bond length 2.06 \AA~ in VO octahedra hardens with increasing gate
voltage and the B(3) mode near 654 cm softens. This shows that the
distortion of the VO octahedra in the monoclinic phase decreases with
gating. The time dependent Raman data at fixed gate voltages of 1 V (for 50
minute, showing enhancement of conductivity by a factor of 50) and 2 V (for 130
minute, showing further increase in conductivity by a factor of 5) show similar
changes in high frequency Raman modes A(7) and B(3) as observed in
gating. This slow change in conductance together with Raman frequency changes
show that the governing mechanism for metalization is more likely to the
diffusion controlled oxygen vacancy formation due to the applied electric
field.Comment: 5 pages, 6 figure
Early diagnosis of Carpal Tunnel Syndrome (CTS) in Indian patients by nerve conduction studies
The present study was carried out for early confirmation of clinicallydiagnosed patients of Carpal Tunnel Syndrome (CTS) by electro-diagnostic tests which included motor conduction, sensory conduction studies and F-wave studies. The aim of the study was early confirmation of clinically suspected patients of CTS by motor and sensory conduction studies of median and ulnar nerves. Eighty subjects of age group 30-50 years (40 clinically suspected patients of CTS, 40 as control group) were studied. Motor and Sensory conduction velocities, distal motor and sensory latencies and F wave latencies of median and ulnar nerves were performed using RMS EMG EP Mark –II. Statistically significant (P < 0.001) slowing of motor conduction velocities for both nerves was seen in the CTS group as compared to control group. Decrease in sensory conduction velocity wasmore pronounced in CTS group as compared to Control group. Statistically significant (P < 0.001) increase in distal motor and sensory latencies was also observed for both median and ulnar nerves in the CTS group as compared to Control group, with more increase in distal motor latency than sensory latency. Increase in F wave latencies of both nerves was seen in the CTS group. Electrophysiological studies confirmed the early diagnosis of CTS with a high degree of sensitivity. Present results confirm selective slowing of sensory & motor conduction within wrist to palm segment in patients of CTS which is attributable to compression by the transverse carpal ligament or to a disease process of the terminal segment.KEY WORDS: Nerve entrapments; Median neuropathy; Electro-physiological diagnosis; Distal and motor sensory latencies; Palm wrist conductio
Sharp Raman Anomalies and Broken Adiabaticity at a Pressure Induced Transition from Band to Topological Insulator in Sb2Se3
The nontrivial electronic topology of a topological insulator is thus far
known to display signatures in a robust metallic state at the surface. Here, we
establish vibrational anomalies in Raman spectra of the bulk that signify
changes in electronic topology: an E2 g phonon softens unusually and its
linewidth exhibits an asymmetric peak at the pressure induced electronic
topological transition (ETT) in Sb2Se3 crystal. Our first-principles
calculations confirm the electronic transition from band to topological
insulating state with reversal of parity of electronic bands passing through a
metallic state at the ETT, but do not capture the phonon anomalies which
involve breakdown of adiabatic approximation due to strongly coupled dynamics
of phonons and electrons. Treating this within a four-band model of topological
insulators, we elucidate how nonadiabatic renormalization of phonons
constitutes readily measurable bulk signatures of an ETT, which will facilitate
efforts to develop topological insulators by modifying a band insulator
Raman anomalies as signatures of pressure induced electronic topological and structural transitions in black phosphorus: Experiments and Theory
We report high pressure Raman experiments of Black phosphorus up to 24 GPa.
The line widths of first order Raman modes A, B and A of the
orthorhombic phase show a minimum at 1.1 GPa. Our first-principles density
functional analysis reveals that this is associated with the anomalies in
electron-phonon coupling at the semiconductor to topological insulator
transition through inversion of valence and conduction bands marking a change
from trivial to nontrivial electronic topology. The frequencies of B and
A modes become anomalous in the rhombohedral phase at 7.4 GPa, and new
modes appearing in the rhombohedral phase show anomalous softening with
pressure. This is shown to originate from unusual structural evolution of black
phosphorous with pressure, based on first-principles theoretical analysis.Comment: 13pages, 12figure
Multimodal Magnetic Resonance and Near-Infrared-Fluorescent Imaging of Intraperitoneal Ovarian Cancer Using a Dual-Mode-Dual-Gadolinium Liposomal Contrast Agent.
The degree of tumor removal at surgery is a major factor in predicting outcome for ovarian cancer. A single multimodality agent that can be used with magnetic resonance (MR) for staging and pre-surgical planning, and with optical imaging to aid surgical removal of tumors, would present a new paradigm for ovarian cancer. We assessed whether a dual-mode, dual-Gadolinium (DM-Dual-Gd-ICG) contrast agent can be used to visualize ovarian tumors in the peritoneal cavity by multimodal MR and near infra-red imaging (NIR). Intraperitoneal ovarian tumors (Hey-A8 or OVCAR3) in mice enhanced on MR two days after intravenous DM-Dual Gd-ICG injection compared to controls (SNR, CNR, p < 0.05, n = 6). As seen on open abdomen and excised tumors views and confirmed by optical radiant efficiency measurement, Hey-A8 or OVCAR3 tumors from animals injected with DM-Dual Gd-ICG had increased fluorescence (p < 0.05, n = 6). This suggests clinical potential to localize ovarian tumors by MR for staging and surgical planning, and, by NIR at surgery for resection
- …