Kinetically-controlled thin-film growth of layered β\beta- and γ−\gamma-Nax_{x}CoO2_{2} cobaltate

We report growth characteristics of epitaxial $\beta$-Na$_{0.6}$CoO$_{2}$ and $\gamma$-Na$_{0.7}$CoO$_{2}$ thin films on (001) sapphire substrates grown by pulsed-laser deposition. Reduction of deposition rate could change structure of Na$_{x}$CoO$_{2}$ thin film from $\beta$-phase with island growth mode to $\gamma$-phase with layer-by-layer growth mode. The $\gamma$-Na$_{0.7}$CoO$_{2}$ thin film exhibits spiral surface growth with multiterraced islands and highly crystallized texture compared to that of the $\beta$-Na$_{0.6}$CoO$_{2}$ thin film. This heterogeneous epitaxial film growth can give opportunity of strain effect of physical properties and growth dynamics of Na$_{x}$CoO$_{2}$ as well as subtle nature of structural change.Comment: accepted for publication in Applied Physics Letter

Structural origins of the properties of rare earth nickelate superlattices

NiO6 octahedral tilts in the LaNiO3/SrTiO3 superlattices are quantified using position averaged convergent beam electron diffraction in scanning transmission electron microscopy. It is shown that maintaining oxygen octahedra connectivity across the interface controls the octahedral tilts in the LaNiO3 layers, their lattice parameters and their transport properties. Unlike films and layers that are connected on one side to the substrate, subsequent LaNiO3 layers in the superlattice exhibit a relaxation of octahedral tilts towards bulk values. This relaxation is facilitated by correlated tilts in SrTiO3 layers and is correlated with the conductivity enhancement of the LaNiO3 layers in the superlattices relative to individual films.Comment: Accepted for publication in Physical Review B (Rapid Communication

A variant transfer matrix method suitable for transport through multi-probe systems

We have developed a variant transfer matrix method that is suitable for transport through multi-probe systems. Using this method, we have numerically studied the quantum spin Hall effect (QSHE) on 2D graphene with both intrinsic (Vso) and Rashba (Vr) spin-orbit (SO) couplings. The integer QSHE arises in the presence of intrinsic SO interaction and is gradually destroyed by the Rashba SO interaction and disorder fluctuation. We have numerically determined the phase boundaries separating integer QSHE and spin Hall liquid. We have found that when Vso> 0.2t with t the hopping constant the energy gap needed for the integer QSHE is the largest satisfying |E|<t. For smaller Vso the energy gap decreases linearly. In the presence of Rashba SO interaction or disorders, the energy gap diminishes. With Rashba SO interaction the integer QSHE is robust at the largest energy within the energy gap while at the smallest energy within the energy gap the integer QSHE is insensitive to the disorder

Development of an Integrated DBH Estimation Model Based on Stand and Climatic Conditions

Using Korean National Forest Inventory (NFI) data, our study developed a model to estimate stand mean diameter at breast height (DBH) reflecting the influence of site and climate factors on forest growth for the major tree species in South Korea. A DBH estimation model was developed using stand-level variables (stand age, site index and number of trees per hectare) as independent factors. The spatial autocorrelation of residuals of the model was identified using semi-variogram analysis for each tree species. Further, a residual model, in which residuals were estimated by climatic factors (mean temperature, sum temperature in the growing season and precipitation), was developed assuming that the spatial autocorrelation of residuals reflects the differences in regional climatic conditions. Linear regression analysis showed that residuals of all tree species were significantly correlated with temperature and precipitation. The DBH and residual models were integrated to estimate the current DBH under different climatic factors (temperature and precipitation) and stand-level variables. This model had high reliability (R2 = 0.74–0.79), and no obvious dependencies or patterns in residuals were noted. Our results indicated that temperature increases caused by climate change would negatively affect the DBH estimate of coniferous trees, but not of oak species

Electronic and Magnetic Properties of Partially-Open Carbon Nanotubes

On the basis of the spin-polarized density functional theory calculations, we demonstrate that partially-open carbon nanotubes (CNTs) observed in recent experiments have rich electronic and magnetic properties which depend on the degree of the opening. A partially-open armchair CNT is converted from a metal to a semiconductor, and then to a spin-polarized semiconductor by increasing the length of the opening on the wall. Spin-polarized states become increasingly more stable than nonmagnetic states as the length of the opening is further increased. In addition, external electric fields or chemical modifications are usable to control the electronic and magnetic properties of the system. We show that half-metallicity may be achieved and the spin current may be controlled by external electric fields or by asymmetric functionalization of the edges of the opening. Our findings suggest that partially-open CNTs may offer unique opportunities for the future development of nanoscale electronics and spintronics.Comment: 6 figures, to appear in J. Am. Chem. So

Structural transitions and nonmonotonic relaxation processes in liquid metals

Structural transitions in melts as well as their dynamics are considered. It is supposed that liquid represents the solution of relatively stable solid-like locally favored structures (LFS) in the surrounding of disordered normal-liquid structures. Within the framework of this approach the step changes of liquid Co viscosity are considered as liquid-liquid transitions. It is supposed that this sort of transitions represents the cooperative medium-range bond ordering, and corresponds to the transition of the "Newtonian fluid" to the "structured fluid". It is shown that relaxation processes with oscillating-like time behavior ($\omega \sim 10^{-2}$~$s^{-1}$) of viscosity are possibly close to this point

Computational Study of Tunneling Transistor Based on Graphene Nanoribbon

Tunneling field-effect transistors (FETs) have been intensely explored recently due to its potential to address power concerns in nanoelectronics. The recently discovered graphene nanoribbon (GNR) is ideal for tunneling FETs due to its symmetric bandstructure, light effective mass, and monolayer-thin body. In this work, we examine the device physics of p-i-n GNR tunneling FETs using atomistic quantum transport simulations. The important role of the edge bond relaxation in the device characteristics is identified. The device, however, has ambipolar I-V characteristics, which are not preferred for digital electronics applications. We suggest that using either an asymmetric source-drain doping or a properly designed gate underlap can effectively suppress the ambipolar I-V. A subthreshold slope of 14mV/dec and a significantly improved on-off ratio can be obtained by the p-i-n GNR tunneling FETs

Nonequilibrium spin transport on Au(111) surfaces

The well-known experimentally observed \textit{sp}-derived Au(111) Shockley surface states with Rashba spin splitting are perfectly fit by an effective tight-binding model, considering a two-dimensional hexagonal lattice with $p_{z}$-orbital and nearest neighbor hopping only. The extracted realistic band parameters are then imported to perform the Landauer-Keldysh formalism to calculate nonequilibrium spin transport in a two-terminal setup sandwiching a Au(111) surface channel. Obtained results show strong spin density on the Au(111) surface and demonstrate (i) intrinsic spin-Hall effect, (ii) current-induced spin polarization, and (iii) Rashba spin precession, all of which have been experimentally observed in semiconductor heterostructures, but not in metallic surface states. We therefore urge experiments in the latter for these spin phenomena.Comment: 5 pages, 3 figures, to be published in Phys. Rev.

Fermi point in graphene as a monopole in momentum space

We consider the effective field theory of graphene monolayer with the Coulomb interaction between fermions taken into account. The gauge field in momentum space is introduced. The position of the Fermi point coincides with the position of the corresponding monopole. The procedure of extracting such monopoles during lattice simulations is suggested.Comment: Latex, 12 page

Half-Metallic Graphene Nanoribbons

Electrical current can be completely spin polarized in a class of materials known as half-metals, as a result of the coexistence of metallic nature for electrons with one spin orientation and insulating for electrons with the other. Such asymmetric electronic states for the different spins have been predicted for some ferromagnetic metals - for example, the Heusler compounds- and were first observed in a manganese perovskite. In view of the potential for use of this property in realizing spin-based electronics, substantial efforts have been made to search for half-metallic materials. However, organic materials have hardly been investigated in this context even though carbon-based nanostructures hold significant promise for future electronic device. Here we predict half-metallicity in nanometre-scale graphene ribbons by using first-principles calculations. We show that this phenomenon is realizable if in-plane homogeneous electric fields are applied across the zigzag-shaped edges of the graphene nanoribbons, and that their magnetic property can be controlled by the external electric fields. The results are not only of scientific interests in the interplay between electric fields and electronic spin degree of freedom in solids but may also open a new path to explore spintronics at nanometre scale, based on graphene