72 research outputs found
New functionalised polymeric microspheres for multicomponent solid phase extraction of phenolic compounds
Lateral variability in strain along a mass-transport deposit (MTD) toewall: a case study from the Makassar Strait, offshore Indonesia
Contractional features characterise the toe domain of mass-transport deposits (MTDs). Their frontal geometry is typically classified as frontally-confined or frontally-emergent. However, it remains unclear how frontal emplacement style and contractional strain within an MTD can vary along strike. We use bathymetry and 3D seismic reflection data to investigate lateral variability of frontal emplacement and strain within the toe domain of the Haya Slide in the Makassar Strait. The slide originated from an anticline flank collapse, and the toe domain is characterised by a radial fold-and-thrust belt that reflects southwestwards emplacement. The frontal geometry of the slide changes laterally. In the S, it is frontally-confined, associated with a deep, c. 200 mbsf, and planar basal shear surface. The frontal geometry gradually changes to frontally-emergent in the W, associated with a shallow, c. 120 mbsf, and NE-dipping, c. 3o, basal shear surface. Strain analysis shows c. 8-14% shortening, with cumulative throw of the thrusts that increases along strike westwards from c. 20-40 to c. 40-80 m. We show that even minor horizontal translation of MTDs (c. 1 km) can result in marked lateral variability in frontal geometry and strain within the failed body, which may influence their seal potential in petroleum systems
Phosphorus, nitrogen and oxygen co-doped polymer-based core-shell carbon sphere for high-performance hybrid supercapacitors
Co-doping heteroatoms of the carbon lattice has been proven as an efficient strategy that can improve the capacitive performance, due to the synergetic effect of several dopants. Herein, a series of phosphorus, nitrogen and oxygen, co-doped polymer-based carbon spheres were prepared by the suspension polymerization method and chemical activation with phosphoric acid at different temperatures. The presence of heteroatoms was confirmed by X-ray photoelectron spectroscopy and elemental analysis. The structure of the carbons was characterized by scanning electron microscopy, Raman spectroscopy and nitrogen adsorption. Carbon obtained at 800 degrees C with a P, N and O doping level of 11.17 at%, 2.79 at% and 11.77 at% respectively, shows a capacitance of 157 F g(-1) at the current density of 0.05 A g(-1). Moreover, the electrode can survive at a wide potential window of 1.5 V with only 15% decrease in capacity after 10000 cycles at a current density of 5 A g(-1), providing a high energy density of 10 Wh kg(-1) and a high power density of 750 W kg(-1). For the outstanding features, it is expected that the phosphorus, nitrogen and oxygen co-doped carbons will be a very suitable material not only for supercapacitors, but also for lithium batteries and oxygen reduction reaction. In addition, the co-doping method described here might be extended to the preparation of other kinds of porous carbon materials. (c) 2018 Elsevier Ltd. All rights reserved
Transferrin changes in haemodialysed patients
Transferrin (Tf) is a glycoprotein responsible for iron transport in the human body. Physiologically in reaction with Concanavalin A, Tf occurs in four distinct variants Tf1, Tf2, Tf3 (apo-Tf) and Tf4. It was reported recently that Tf is changing, particularly during acute phase response, taking place among others in end-stage renal disease. In this study, we wanted to find the answer to three main questions: firstly, how Tf is changing in patients treated with maintenance haemodialysis (mHD), secondly, whether there are any Tf changes in the course of mHD treatment, and thirdly, what factors can affect Tf microheterogeneity in these patients. Studies were performed on 80 haemodialysed patients and 21 healthy volunteers. The Tf concentration was determined by the rocket immunoelectrophoresis, and its microheterogeneity was assessed by the ConA crossed immunoaffinity electrophoresis. During the annual observation of the distribution of the Tf variants, we have found both changes of the percentage contents of all Tf variants in the whole Tf concentration and a significant decrease in Tf2, Tf3 and Tf4 serum concentrations. Moreover, we found that decrease in the renal function, duration of mHD, and inflammation may contribute to these above-mentioned changes, which are probably the factors that should be taken into account when explaining the mechanisms of persistence of anaemia in haemodialysed patients
Evaluation of site effects in the Aterno river valley (Central Italy) from aftershocks of the 2009 L'Aquila earthquake
A temporary network of 33 seismic stations was deployed in the area struck by the 6th April 2009, Mw 6.3, L’Aquila earthquake (central Italy), with the aim to investigate the site amplification within the Aterno river Valley. The seismograms of 18 earthquakes recorded by 14 of the 33 stations were used to evaluate the average horizontal to vertical spectral ratio (HVSR) for each site and the standard horizontal spectral ratio (SSR) between a site and a reference station. The obtained results have been compared to the geological and geophysical information in order to explain the resonance frequencies and the amplification levels with respect to surface geology of the valley.
The result indicate that there is no uniform pattern of amplification, due to the complex geologic setting, as the thickness and degree of cementation of the deposits is highly variable. As consequence, a large number of the local site response is observed, therefore it is very difficult to elaborate a unique model that can explain such a variability of the amplification.Published697-7154.1. Metodologie sismologiche per l'ingegneria sismicaJCR Journalpartially_ope
Evaluation of the local site effects in the upper and middle Aterno valley
In the months following the April 6th, 2009, L’Aquila earthquake, several Italian and foreign research institutions installed dozens of seismic stations to monitor more than 100 localities with the aim of studying the local site effects in the epicentral area (upper and middle Aterno valley).
The stations (accelerometers and velocimeters) have been deployed inside or very close to the inhabited areas. Among the investigated sites there are Onna, where almost the totality of the buildings collapsed, and the historic centre of L’Aquila, both towns suffering many casualties. The preliminary results for the examined sites show an extreme variability of ground motion and significant amplification for the most damaged localities.In press4.1. Metodologie sismologiche per l'ingegneria sismicaN/A or not JCRope
Copper(II) complexes with derivatives of pyrazole as potential antioxidant enzyme mimics
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