ALTICORE: an initiative for coastal altimetry

ALTICORE (value-added ALTImetry for COastal REgions) is an international initiative whose main objective is to encourage the operational use of altimetry over coastal areas, by improving the quality and availability of coastal altimetry data. The ALTICORE proposal has recently been submitted for funding to the INTAS scheme (www.intas.be) by a consortium of partners from Italy, France, UK, Russia and Azerbaijan. ALTICORE is also meant as a contribution to the ongoing International Altimeter Service effort. In this work we will describe the anticipated project stages, namely: 1) improvement of the most widely distributed, 1 Hz, data by analyzing the corrective terms and providing the best solutions, including those derived from appropriate local modelling; 2) development of a set of algorithms to automate quality control and gap-filling functions for the coastal regions; 3) development of testing strategies to ensure a thorough validation of the data. The improved products will be delivered to ALTICORE users via Grid-compliant technology; this makes it easier to integrate the local data holdings, allows access from a range of services, e.g. directly into model assimilation or GIS systems and should therefore facilitate a widespread and complete assessment of the 1Hz data performance and limitations. We will also outline the design and implementation of the Grid-compliant system for efficient access to distributed archives of data; this consists of regional data centres, each having primary responsibility for regional archives, local corrections and quality control, and operating a set of web-services allowing access to the full functionality of data extraction. We will conclude by discussing a follow-on phase of the project; this will investigate further improvements on the processing strategy, including the use of higher frequency (10 or 20 Hz) data. Phenomena happen at smaller spatial scales near the coast, so this approach is necessary to match the required resolution. The whole project will hopefully promote the 15-year sea surface height from altimetry to the rank of operational record for the coastal areas

Evidence and implications for exciton dissociation in lead halide perovskites

We have employed ultrafast transient-grating and two- dimensional electronic spectroscopy to probe dynamics of photo-excited CH3NH3PbI3 thin films with 16-fs temporal resolution. We distinctly capture the 30-fs decay of excitons, weakly coupled to the phonons

On the spacing distribution of the Riemann zeros: corrections to the asymptotic result

It has been conjectured that the statistical properties of zeros of the Riemann zeta function near z = 1/2 + \ui E tend, as $E \to \infty$, to the distribution of eigenvalues of large random matrices from the Unitary Ensemble. At finite $E$ numerical results show that the nearest-neighbour spacing distribution presents deviations with respect to the conjectured asymptotic form. We give here arguments indicating that to leading order these deviations are the same as those of unitary random matrices of finite dimension $N_{\rm eff}=\log(E/2\pi)/\sqrt{12 \Lambda}$, where $\Lambda=1.57314 ...$ is a well defined constant.Comment: 9 pages, 3 figure

Equivariant comparison of quantum homogeneous spaces

We prove the deformation invariance of the quantum homogeneous spaces of the q-deformation of simply connected simple compact Lie groups over the Poisson-Lie quantum subgroups, in the equivariant KK-theory with respect to the translation action by maximal tori. This extends a result of Neshveyev-Tuset to the equivariant setting. As applications, we prove the ring isomorphism of the K-group of Gq with respect to the coproduct of C(Gq), and an analogue of the Borsuk-Ulam theorem for quantum spheres.Comment: 21 page

Randomized double-blind placebo-controlled trial of 40 mg/day of atorvastatin in reducing the severity of sepsis in ward patients (ASEPSIS Trial)

Introduction: Several observational studies suggest that statins modulate the pathophysiology of sepsis and may prevent its progression. The aim of this study was to determine if the acute administration of atorvastatin reduces sepsis progression in statin naïve patients hospitalized with sepsis. Methods: A single centre phase II randomized double-blind placebo-controlled trial. Patients with sepsis were randomized to atorvastatin 40 mg daily or placebo for the duration of their hospital stay up to a maximum of 28-days. The primary end-point was the rate of sepsis progressing to severe sepsis during hospitalization. Results: 100 patients were randomized, 49 to the treatment with atorvastatin and 51 to placebo. Patients in the atorvastatin group had a significantly lower conversion rate to severe sepsis compared to placebo (4% vs. 24% p = 0.007.), with a number needed to treat of 5. No significant difference in length of hospital stay, critical care unit admissions, 28-day and 12-month readmissions or mortality was observed. Plasma cholesterol and albumin creatinine ratios were significantly lower at day 4 in the atorvastatin group (p < 0.0001 and p = 0.049 respectively). No difference in adverse events between the two groups was observed (p = 0.238). Conclusions: Acute administration of atorvastatin in patients with sepsis may prevent sepsis progression. Further multi-centre trials are required to verify these findings. Trial Registration: International Standard Randomized Control Trial Registry ISRCTN64637517

Using remote substituents to control solution structure and anion binding in lanthanide complexes.

A study of the anion-binding properties of three structurally related lanthanide complexes, which all contain chemically identical anion-binding motifs, has revealed dramatic differences in their anion affinity. These arise as a consequence of changes in the substitution pattern on the periphery of the molecule, at a substantial distance from the binding pocket. Herein, we explore these remote substituent effects and explain the observed behaviour through discussion of the way in which remote substituents can influence and control the global structure of a molecule through their demands upon conformational space. Peripheral modifications to a binuclear lanthanide motif derived from α,α′-bis(DO3 Ayl)-m-xylene are shown to result in dramatic changes to the binding constant for isophthalate. In this system, the parent compound displays considerable conformational flexibility, yet can be assumed to bind to isophthalate through a well-defined conformer. Addition of steric bulk remote from the binding site restricts conformational mobility, giving rise to an increase in binding constant on entropic grounds as long as the ideal binding conformation is not excluded from the available range of conformers

Reduced ascending/descending pass bias in SMOS salinity data demonstrated by observing westward-propagating features in the South Indian Ocean

The European Space Agency (ESA) Soil Moisture and Ocean Salinity (SMOS) satellite has been providing data, including sea surface salinity (SSS) measurements, for more than five years. However, the operational ESA Level 2 SSS data are known to have significant spatially and temporally varying biases between measurements from ascending passes (SSSA) and measurements from descending passes (SSSD). This paper demonstrates how these biases are reduced through the use of SSS anomalies. Climatology products are constructed using SMOS Level 2 data to provide daily, one-degree by one-degree climatologies separately for ascending and descending passes using a moving window approach (in time and space). The daily, one-degree products can then be averaged to provide values of climatological SSS at different spatial and/or temporal resolutions. The averaged values of the SMOS climatology products are in good general agreement with data from the World Ocean Atlas 2013. However, there are significant differences at high latitudes, as well as in coastal and dynamic regions, as found by previous studies. Both the mean and standard deviation of the differences between data from ascending passes and data from descending passes for the anomalies are reduced compared with those obtained using the original salinity values. Geophysical signals are clearly visible in the anomaly products and an example is shown in the Southern Indian Ocean of westward-propagating signals that we conclude represent the surface expression of Rossby waves or large-scale non-linear eddies. The signals seen in salinity data agree (in speed) with those from sea surface temperature and sea surface height and are consistent with previous studies

Pore Filling of Spiro-OMeTAD in Solid-State Dye-Sensitized Solar Cells Determined Via Optical Reflectometry

A simple strategy is presented to determine the pore-filling fraction of the hole-conductor 2,2-7,7-tetrakis-N,N-di-pmethoxyphenylamine-9,9-spirobifluorene (spiro-OMeTAD) into mesoporous photoanodes in solid-state dye-sensitized solar cells (ss-DSCs). Based on refractive index determination by the film’s reflectance spectra and using effective medium approximations the volume fractions of the constituent materials can be extracted, hence the pore-filling fraction quantified. This non-destructive method can be used with complete films and does not require detailed model assumptions. Pore-filling fractions of up to 80% are estimated for optimized solid-state DSC photoanodes, which is higher than that previously estimated by indirect methods. Additionally, transport and recombination lifetimes as a function of the pore-filling fraction are determined using photovoltage and photocurrent decay measurements. While extended electron lifetimes are observed with increasing pore-filling fractions, no trend is found in the transport kinetics. The data suggest that a pore-filling fraction of greater than 60% is necessary to achieve optimized performance in ss-DSCs. This degree of pore-filling is even achieved in 5 mu m thick mesoporous photoanodes. It is concluded that pore-filling is not a limiting factor in the fabrication of “thick” ss-DSCs with spiro-OMeTAD as the hole-conductor