1,067 research outputs found
Preparation and properties of a composite charged membrane
In order to develop a low pressure desalination membrane with fixed ionic charges, we made use of the normally unwanted crosslinking tendency in preparing the polyelectrolyte poly(styrenesulfonate) by sulfonation of polystyrene. After dipcoating a poly(sulfone) or poly(phenylene oxide) UF membrane with a dilute soluton of this polyelectrolyte in water in the presence of some free sulfuric acid and silversulfate, fixation and cross-linking of the coating polymer took place by a heat treatment.\ud
\ud
Different membrane properties could be obtained by varying the pore size of the supporting UF membranes, and by variation in the coating polymer (M.W., concentration) and sulfuric acid concentration. We found that fluxes sometimes decline drastically in comparison with the original pure water flux; salt rejection values (at 1.5 g/l NaCl concentration and 0.5 MPa) never are very high (≤60% for monovalent anions). The most important potential application for these membranes lies in their non-fouling properties
Thermoreversible gelation of cellulose acetate solutions studied by differential scanning calorimetry
Thermoreversible gels of cellulose acetate can be obtained by cooling concentrated cellulose acetate solutions in solvent-nonsolvent mixtures of dioxane and water. Upon heating the gels, endothermic effects were observed with differential scanning calorimetry. The heat effects are ascribed to the melting of a crystalline phase consisting of cellulose triacetate units. The endothermic peaks appear only after long aging periods of up to several days. Melting points generally decrease and heats of melting increase with increasing polymer concentration and with increasing nonsolvent content. The maximum degree of crystallinity is estimated as 8%. The kinetic effects of varying the water content in the solvent mixture are discussed
Fluidized beds as turbulence promoters in the concentration of food liquids by reverse osmosis
Fluidized beds offer a potential improvement of reverse osmosis processes for food liquids, less fouling of the membrane, and reduced energy consumption. Our experiments were concerned with tubular systems in which fluidized beds of glass, steel, and lead beads were used. Glass beads appeared to be preferable, since they caused little damage to the membrane. Only with the larger glass beads (3 mm) did the membrane skin become corrugated, so that the rejection decreased. The permeate flux for Gouda cheese whey was almost equal to that of an empty tube for which the velocity was about thirty times higher. The erosive action of the glass beads on the fouling layer was partially responsible for this effect. For reverse osmosis of skim milk and potato fruit water the bed did not reduce the fouling layer to a sufficient extent and, therefore, had a lower permeate flux than an empty tube
Translating biomonitoring data into risk management and policy implementation options for a European Network on Human Biomonitoring
<p>Abstract</p> <p>Background</p> <p>The "European Environment & Health Action Plan 2004–2010" originates from the concern of the European Commission on the well-being of individuals and the general population. Through this plan, the Commission has set the objectives to improve the information chain for a better understanding of the link between sources of pollution and health effects, to better identify existing knowledge gaps, and improve policy making and communication strategies. Human biomonitoring (HBM) has been included as one of the tools to achieve these objectives. As HBM directly measures the amount of a chemical substance in a person's body, taking into account often poorly understood processes such as bioaccumulation, excretion, metabolism and the integrative uptake variability through different exposure pathways, HBM data are much more relevant for risk assessment than extrapolations from chemical concentrations in soil, air, and water alone. However, HBM primarily is a stepping stone between environmental and health data, and the final aim should be an integrated and holistic systematic risk assessment paradigm where HBM serves as a pivotal point between environment and health, on the one hand leaning on environmental data to provide detailed information on the sources and pathways of pollutants that enter the human body, and on the other hand clarifying new and existing hypotheses on the relationship between environmental pollutants and the prevalence of diseases. With the large amount of data that is being gathered in the different national survey projects, and which is expected to become available in Europe in the near future through the expected European Pilot Project on HBM, a framework to optimize data interpretation from such survey projects may greatly enhance the usefulness of HBM data for risk managers and policy makers.</p> <p>Results</p> <p>This paper outlines an hierarchic approach, based on the stepwise formulation of 4 subsequent steps, that will eventually lead to the formulation of a variety of policy relevant risk reduction options.</p> <p>Conclusion</p> <p>Although the usefulness of this approach still needs to be tested, and potential fine-tuning of the procedure may be necessary, approaching the policy implications of HBM in an objective framework will prove to be essential.</p
Analysis of the polarization properties of dual polarized inverted vee dipole antennas over a ground plane
This paper presents the derivation of an explicit closed-form expression of dual-polarized inverted-vee dipole antenna behavior based upon electromagnetic theory and physical explanations. The expression is used to determine the intrinsic cross-polarization ratio (IXR) as function of the droop angle, position of the sky-vector, the height above a ground plane and frequency. The expression is verified using full-wave simulations with a Method-of-Moments solver, and shows excellent agreement with simulations. It explains the increase observed in IXR if an infinite perfect electric conductor ground plane is deployed
A morphological algorithm for improving radio-frequency interference detection
A technique is described that is used to improve the detection of
radio-frequency interference in astronomical radio observatories. It is applied
on a two-dimensional interference mask after regular detection in the
time-frequency domain with existing techniques. The scale-invariant rank (SIR)
operator is defined, which is a one-dimensional mathematical morphology
technique that can be used to find adjacent intervals in the time or frequency
domain that are likely to be affected by RFI. The technique might also be
applicable in other areas in which morphological scale-invariant behaviour is
desired, such as source detection. A new algorithm is described, that is shown
to perform quite well, has linear time complexity and is fast enough to be
applied in modern high resolution observatories. It is used in the default
pipeline of the LOFAR observatory.Comment: Accepted for publication in A&
An asteroseismic study of the O9V star HD 46202 from CoRoT space-based photometry
The O9V star HD 46202, which is a member of the young open cluster NGC 2244,
was observed by the CoRoT satellite in October/November 2008 during a short run
of 34 days. From the very high-precision light curve, we clearly detect beta
Cep-like pulsation frequencies with amplitudes of ~0.1 mmag and below. A
comparison with stellar models was performed using a chi^2 as a measure for the
goodness-of-fit between the observed and theoretically computed frequencies.
The physical parameters of our best-fitting models are compatible with the ones
deduced spectroscopically. A core overshooting parameter alpha_ov = 0.10 +-
0.05 pressure scale height is required. None of the observed frequencies are
theoretically excited with the input physics used in our study. More
theoretical work is thus needed to overcome this shortcoming in how we
understand the excitation mechanism of pulsation modes in such a massive star.
A similar excitation problem has also been encountered for certain pulsation
modes in beta Cep stars recently modelled asteroseismically.Comment: Accepted for publication in Astronomy and Astrophysics on 17/12/2010,
9 pages, 7 figures, 4 table
- …