94 research outputs found
Polarization-preserving confocal microscope for optical experiments in a dilution refrigerator with high magnetic field
We present the design and operation of a fiber-based cryogenic confocal
microscope. It is designed as a compact cold-finger that fits inside the bore
of a superconducting magnet, and which is a modular unit that can be easily
swapped between use in a dilution refrigerator and other cryostats. We aimed at
application in quantum optical experiments with electron spins in
semiconductors and the design has been optimized for driving with, and
detection of optical fields with well-defined polarizations. This was
implemented with optical access via a polarization maintaining fiber together
with Voigt geometry at the cold finger, which circumvents Faraday rotations in
the optical components in high magnetic fields. Our unit is versatile for use
in experiments that measure photoluminescence, reflection, or transmission, as
we demonstrate with a quantum optical experiment with an ensemble of
donor-bound electrons in a thin GaAs film.Comment: 9 pages, 7 figure
Electromagnetically Induced Transparency with an Ensemble of Donor-Bound Electron Spins in a Semiconductor
We present measurements of electromagnetically induced transparency with an
ensemble of donor- bound electrons in low-doped n-GaAs. We used optical
transitions from the Zeeman-split electron spin states to a bound trion state
in samples with optical densities of 0.3 and 1.0. The electron spin dephasing
time T* \approx 2 ns was limited by hyperfine coupling to fluctuating nuclear
spins. We also observe signatures of dynamical nuclear polarization, but find
these effects to be much weaker than in experiments that use electron spin
resonance and related experiments with quantum dots.Comment: 4 pages, 4 figures; Improved analysis of data in Fig. 3, corrected
factors of 2 and p
Mathematical model for investigation of alkylbenzenes sulfonation
The relevance. Lack of experimental data that allow developing a scientifically based method for calculating and designing film-type reactors, which are also used to produce alkylbenzenesulfonic acids. These acids, in their turn, are currently the main components of synthetic detergents. The issue of increasing reactor equipment efficiency can be most effectively solved using mathematical models built on a physical and chemical basis. The aim. Development of a mathematical model of alkylbenzenes sulfonation, taking into account a substance mass transfer from a gas phase to a liquid phase. Software implementation of the developed model, as well as the use of the developed mathematical model for studying the influence of the process parameters on its efficiency. Object. Alkylbenzenes sulfonation with sulfuric anhydride in a multitube film reactor. Methods. Mathematical modeling is used to perform all computational operations, a modern high-level general-purpose programming language with automatic memory management is used. The quantum-chemical methods for determining thermodynamic parameters of chemical reactions were used. Results. The paper considers the principles of constructing a mathematical model of sulfonation. The authors have developed the calculation program in the Python programming language and assessed the accuracy of description of a real process and the influence of the system technological parameters on a product yield and quality, taking into account a substance interfacial transfer. The system of practical recommendations for improving the alkylbenzenes sulfonation resource efficiency was developed. The mathematical model adequately describes the process. The calculated data are compared with the real data from the operating unit for alkylbenzenes sulfonation with sulfuric anhydride
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