116 research outputs found

    Analisis Portofolio Optimal Dengan Single Index Model Untuk Meminimumkan Risiko Bagi Investor Di Bursa Efek Indonesia (Studi Pada Saham Indeks Kompas 100 Periode Februari 2010-juli 2014)

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    Investments can be made in the capital market, capital market instruments which are mostly attractive for investors is stock. Stock provides a return in the form of capital gains and dividends yield, not only noticing the return, investors need to pay attention to the investments risk. Unsystematis risk can be minimized by forming the optimal portfolio using one of the methods that is single index model. Study purpose is to knowing the stocks forming the optimal portfolio, the proportion of funds allocated to each stocks, the level of expectation return and risk.The method used in this research is descriptive research method with a quantitative approach. The samples used were 46 stocks in Kompas 100 Index, which meets the criteria for sampling. The results showed that 12 stocks of forming optimal portfolio, the stocks of which are UNVR, TRAM, MNCN, BHIT, JSMR, BMTR, GJTL, KLBF, AALI, CPIN, AKRA, and ASRI. Stock with highest proportion of funds is TRAM (23,52%), stock with lowest proportion of funds is AALI (0,62%). Portfolio which are formed will give return expectations by 3,05477% and carry the risk for about 0,1228%

    A Simple Strategy for Fabrication of “Plum-Pudding” Type Pd@CeO<sub>2</sub> Semiconductor Nanocomposite as a Visible-Light-Driven Photocatalyst for Selective Oxidation

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    The Pd@CeO<sub>2</sub> semiconductor nanocomposite with “plum-pudding” structure has been fabricated successfully via a facile low-temperature hydrothermal reaction of polyvinylpyrrolidone (PVP)-capped Pd colloidal particles and cerium chloride precursor followed by a calcination process in air. Different characterization techniques, including X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), transmission scanning electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), UV–vis diffuse reflectance spectra (DRS), X-ray photoelectron spectra (XPS), photoluminescence spectra (PL), nitrogen adsorption–desorption, and electron spin resonance spectra (ESR), have been used to investigate the structure and properties of the Pd@CeO<sub>2</sub> nanocomposite. It is found that the nanosized Pd particles are evenly dispersed into the matrix of CeO<sub>2</sub>, thus forming a plum-pudding structure, i.e., multi-Pd core@CeO<sub>2</sub> shell configuration. This unique nanostructure endows the Pd@CeO<sub>2</sub> nanocomposite with enhanced activity and selectivity toward the visible-light-driven oxidation of various benzylic alcohols to corresponding aldehydes using dioxygen as oxidant at room temperature and ambient pressure compared with a supported Pd/CeO<sub>2</sub> nanocomposite and nanosized CeO<sub>2</sub> powder. The formation of the multi-Pd core@CeO<sub>2</sub> shell structure can be understood by a synergistic interaction of heterogeneous seeded growth process, monolayer-capped core coalescence, and shell re-encapsulation. Together with the previous report, it can be concluded that the intrinsic structure nature of noble metal colloids is able to play a key role in affecting the formation process of noble metal core@semiconductor shell nanocomposites, by which we can realize the design and preparation of different specific core–shell nanostructures with atomic scale accuracy. It is hoped that our current work could open promising prospects of the fabrication of multimetal core@semiconductor shell nanocomposites and their application to visible-light-driven selective organic transformations

    Synthesis of One-Dimensional CdS@TiO<sub>2</sub> Core–Shell Nanocomposites Photocatalyst for Selective Redox: The Dual Role of TiO<sub>2</sub> Shell

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    One-dimensional (1D) CdS@TiO<sub>2</sub> core–shell nanocomposites (CSNs) have been successfully synthesized via a two-step solvothermal method. The structure and properties of 1D CdS@TiO<sub>2</sub> core–shell nanocomposites (CdS@TiO<sub>2</sub> CSNs) have been characterized by a series of techniques, including X-ray diffraction (XRD), ultraviolet–visible-light (UV-vis) diffuse reflectance spectra (DRS), field-emission scanning electron microscopy (FESEM), photoluminescence spectra (PL), and electron spin resonance (ESR) spectroscopy. The results demonstrate that 1D core–shell structure is formed by coating TiO<sub>2</sub> onto the substrate of CdS nanowires (NWs). The visible-light-driven photocatalytic activities of the as-prepared 1D CdS@TiO<sub>2</sub> CSNs are evaluated by selective oxidation of alcohols to aldehydes under mild conditions. Compared to bare CdS NWs, an obvious enhancement of both conversion and yield is achieved over 1D CdS@TiO<sub>2</sub> CSNs, which is ascribed to the prolonged lifetime of photogenerated charge carriers over 1D CdS@TiO<sub>2</sub> CSNs under visible-light irradiation. Furthermore, it is disclosed that the photogenerated holes from CdS core can be stuck by the TiO<sub>2</sub> shell, as evidenced by controlled radical scavenger experiments and efficiently selective reduction of heavy-metal ions, Cr­(VI), over 1D CdS@TiO<sub>2</sub> CSNs, which consequently leads to the fact that the reaction mechanism of photocatalytic oxidation of alcohols over 1D CdS@TiO<sub>2</sub> CSNs is apparently different from that over 1D CdS NWs under visible-light irradiation. It is hoped that our work could not only offer useful information on the fabrication of various specific 1D core–shell nanostructures, but also open a new doorway of such 1D core–shell semiconductors as visible-light photocatalysts in the promising field of selective transformations

    Synthesis of Uniform CdS Nanospheres/Graphene Hybrid Nanocomposites and Their Application as Visible Light Photocatalyst for Selective Reduction of Nitro Organics in Water

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    We report the self-assembly of uniform CdS nanospheres/graphene (CdS NSPs/GR) hybrid nanocomposites via electrostatic interaction of positively charged CdS nanospheres (CdS NSPs) with negatively charged graphene oxide (GO), followed by GO reduction via a hydrothermal treatment. During this facile two-step wet chemistry process, reduced graphene oxide (RGO, also called GR) and the intimate interfacial contact between CdS NSPs and the GR sheets are achieved. Importantly, the CdS NSPs/GR nanocomposites exhibit a much higher photocatalytic performance than bare CdS NSPs toward selective reduction of nitro organics to corresponding amino organics under visible light irradiation. The superior photocatalytic performance of the CdS NSPs/GR nanocomposites can be attributed to the intimate interfacial contact between CdS NSPs and the GR sheets, which would maximize the excellent electron conductivity and mobility of GR that in turn markedly contributes to improving the fate and transfer of photogenerated charge carriers from CdS NSPs under visible light irradiation. Moreover, the photocorrosion of CdS and the photodegradation of GR can be efficiently inhibited. The excellent reusability of the CdS NSPs/GR nanocomposites can be attributed to the synergetic effect of the introduction of GR into the matrix of CdS NSPs and the addition of ammonium formate as quencher for photogenerated holes. It is hoped that our current work could promote us to efficiently harness such a simple and efficient self-assembly strategy to synthesize GR-based semiconductor composites with controlled morphology and, more significantly, widen the application of CdS/GR nanocomposite photocatalysts and offer new inroads into exploration and utilization of GR-based semiconductor nanocomposites as visible light photocatalysts for selective organic transformations

    Structure and Entanglement Factors on Dynamics of Polymer-Grafted Nanoparticles

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    Nanoparticles functionalized with long polymer chains at low graft density are interesting systems to study structure–dynamic relationships in polymer nanocomposites since they are shown to aggregate into strings in both solution and melts and also into spheres and branched aggregates in the presence of free polymer chains. This work investigates structure and entanglement effects in composites of polystyrene-grafted iron oxide nanoparticles by measuring particle relaxations using X-ray photon correlation spectroscopy. Particles within highly ordered strings and aggregated systems experience a dynamically heterogeneous environment displaying hyperdiffusive relaxation commonly observed in jammed soft glassy systems. Furthermore, particle dynamics is diffusive for branched aggregated structures which could be caused by less penetration of long matrix chains into brushes. These results suggest that particle motion is dictated by the strong interactions of chains grafted at low density with the host matrix polymer

    Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts

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    Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalyst
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