Kinetics & Mechanism of Ag+-catalysed Oxidation of Glyoxal & Glyoxaiic Acid by Peroxydisulphate in Aqueous Medium

1117-111

Kinetics of Ag(I) Catalysed Oxidation of Isoamyl Alcohol by Peroxydisulphate

40-4

Phase diagram and magnetic collective excitations of the Hubbard model in graphene sheets and layers

We discuss the magnetic phases of the Hubbard model for the honeycomb lattice both in two and three spatial dimensions. A ground state phase diagram is obtained depending on the interaction strength U and electronic density n. We find a first order phase transition between ferromagnetic regions where the spin is maximally polarized (Nagaoka ferromagnetism) and regions with smaller magnetization (weak ferromagnetism). When taking into account the possibility of spiral states, we find that the lowest critical U is obtained for an ordering momentum different from zero. The evolution of the ordering momentum with doping is discussed. The magnetic excitations (spin waves) in the antiferromagnetic insulating phase are calculated from the random-phase-approximation for the spin susceptibility. We also compute the spin fluctuation correction to the mean field magnetization by virtual emission/absorpion of spin waves. In the large $U$ limit, the renormalized magnetization agrees qualitatively with the Holstein-Primakoff theory of the Heisenberg antiferromagnet, although the latter approach produces a larger renormalization

Impact of OKT3 therapy on cytomegalovirus and herpes simplex virus infections after liver transplantation

The purpose of this study was to analyze the impact of OKT3 on the frequency and severity of CMV and herpes simplex virus (HSV) infections in adult liver transplant recipients. OKT3 treatment is associated with a higher risk of disseminated CMV infection, particularly in patients with primary CMV infection. It also increased the frequency of symptomatic HSV infection in HSV-seropositive liver transplant recipients

A review of crust and upper mantle structure beneath the Indian subcontinent

This review presents an account of the variations in crustal and upper mantle structure beneath the Indian subcontinent and its environs, with emphasis on passive seismic results supplemented by results using controlled seismic sources. Receiver function results from more than 600 seismic stations, and over 10,000 km of deep seismic profiles have been exploited to produce maps of average crustal velocities and thickness across the region. The crustal thickness varies from 29 km at the southern tip of India to 88 km under the Himalayan collision zone, and the patterns of variation show significant deviations from the predictions of global models. The average crustal shear velocity (Vs) is low in the Himalaya–Tibet collision zone compared to Indian shield. Major crustal features are as follows: (a) the Eastern Dharwar Craton has a thinner and simpler crustal structure crust than the Western Dharwar Craton, (b) Himalayan crustal thickness picks clearly follow a trend with elevation, (c) the rift zones of the Godavari graben and Narmada–Son Lineament show deeper depths of crust than their surroundings, and (d) most of the Indian cratonic fragments, Bundelkhand, Bhandara and Singhbhum, show thick crust in comparison to the Eastern Dharwar Craton. Heat flow and crustal thickness estimates do not show any positive correlations for India. Estimates of the thickness of the lithosphere show large inconsistencies among various techniques not only in terms of thickness but also in the nature of the transition to the asthenosphere (gradual or sharp). The lithosphere beneath India shows signs of attrition and preservation in different regions, with a highly heterogeneous nature, and does not appear to have been thinned on broader scale during India's rapid motion north towards Asia. The mantle transition zone beneath India is predominantly normal with some clear variations in the Himalayan region (early arrivals) and Southwest Deccan Volcanic Province and Southern Granulite Terrain (delayed arrivals). No clear patterns on influence on the mantle transition zone discontinuities can be associated with lithospheric thickness. Over 1000 anisotropic splitting parameters from SKS/SKKS phases and 139 using direct S waves are available from various studies. The shear-wave splitting results clearly show the dominance of absolute-plate-motion related strain of a highly anisotropic Indian lithospheric mantle with delay times between the split S phases close to 1 s. There are still many parts of India where there is, at best, limited information on the character of the crust and the mantle beneath. It is to be hoped that further installations of permanent and temporary stations will fill these gaps and improve understanding of the geodynamic environment of the Indian subcontinent.This study has been supported by a grant from the Ministry of Earth Sciences (MoES), IITKGP/CKH

Fungal infections after liver transplantation

The risk factors for development of invasive fungal infections after liver transplantation were (1) longer duration of treatment with nonprophylactic IV antibiotics, (2) longer cumulative surgical time and a higher number of laparotomies, (3) an increased number of units of RBCs and fresh-frozen plasma, and (4) a series of pretransplant laboratory findings: thrombocytopenia, low T lymphocyte levels, low CD4 helper cell and lower helper/suppressor cell ratios and IgA serum levels. The significance of some of these findings is still unclear. Attention to the risk factors outlined earlier may aid both in preventing and in the early detection of invasive fungal infections after liver transplantation

On the Measurement of Atmospheric Density Using Dial in the O2 A-Band (770 Nm)

Differential Absorption Lidar (DIAL) measurements in the A-band of molecular oxygen were suggested as a means of profiling atmospheric density. Progress towards this capability is reported

Stochastic Development Regression on Non-Linear Manifolds

We introduce a regression model for data on non-linear manifolds. The model describes the relation between a set of manifold valued observations, such as shapes of anatomical objects, and Euclidean explanatory variables. The approach is based on stochastic development of Euclidean diffusion processes to the manifold. Defining the data distribution as the transition distribution of the mapped stochastic process, parameters of the model, the non-linear analogue of design matrix and intercept, are found via maximum likelihood. The model is intrinsically related to the geometry encoded in the connection of the manifold. We propose an estimation procedure which applies the Laplace approximation of the likelihood function. A simulation study of the performance of the model is performed and the model is applied to a real dataset of Corpus Callosum shapes