Using PUF disk passive samplers to simultaneously measure air concentrations of persistent organic pollutants (POPs) across the Tuscany Region, Italy

Abstract Passive air samplers consisting of polyurethane foam (PUF) disks were deployed simultaneously over 2–4 month periods from April to July 2008 at 19 locations throughout the Tuscany Region at urban (n = 9), rural (n = 7) and agricultural sites (n = 3). The purpose of the study was to assess the gas–phase air concentrations of PCBs, OCPs, PBDEs and PAHs on a local and regional scale. Derived air concentrations (pg m −3 ) ranged from below detection limit (BDL) to 300 for Σ 6 PCBs and from BDL to 30 for Σ 3 PBDEs. As expected, the highest PCB concentrations (pg m −3 ) were observed at urban sites, peaking in Piombino (300). PBDEs, however, exhibited a "reverse gradient" (i.e. rural>agricultural>urban) with highest air concentration at the rural site, Arcidoso (30). Levels of OCPs showed less distinct differences among the three site types. The most frequently detected OCPs were Endosulfan I, γ–HCH and α–HCH. Endosulfan I ranged from BDL to 2 200 pg m −3 , α–HCH from BDL to 610, and γ–HCH from BDL to 1 100. The high air concentrations of HCHs were surprising and possibly due to continued and illegal use – especially at agricultural and urban sites that exhibited the highest levels in air. PAHs showed highest concentrations (pg m −3 ) at agricultural and urban sites, ranging from 290 to 4 700 and were generally consistent with other data sets from Europe. PAHs were dominated by the 3–ring PAHs (76 ± 6)%, with phenanthrene alone accounting for (45 ± 11%) of the total PAHs. This study demonstrates the feasibility of using PUF disks as time–integrating passive air samplers for assessing local and regional scale concentrations of a wide range of POPs in central Italy. Given their low cost and simplicity, passive air samplers are the preferred option for conducting concurrent sampling at multiple sites for monitoring and research purposes

Using PUF disk passive samplers to simultaneously measure air concentrations of persistent organic pollutants (POPs) across the Tuscany Region, Italy

AbstractPassive air samplers consisting of polyurethane foam (PUF) disks were deployed simultaneously over 2–4 month periods from April to July 2008 at 19 locations throughout the Tuscany Region at urban (n=9), rural (n=7) and agricultural sites (n=3). The purpose of the study was to assess the gas–phase air concentrations of PCBs, OCPs, PBDEs and PAHs on a local and regional scale. Derived air concentrations (pg m−3) ranged from below detection limit (BDL) to 300 for Σ6PCBs and from BDL to 30 for Σ3PBDEs. As expected, the highest PCB concentrations (pg m−3) were observed at urban sites, peaking in Piombino (300). PBDEs, however, exhibited a “reverse gradient” (i.e. rural>agricultural>urban) with highest air concentration at the rural site, Arcidoso (30). Levels of OCPs showed less distinct differences among the three site types. The most frequently detected OCPs were Endosulfan I, γ–HCH and α–HCH. Endosulfan I ranged from BDL to 2 200pg m−3, α–HCH from BDL to 610, and γ–HCH from BDL to 1 100. The high air concentrations of HCHs were surprising and possibly due to continued and illegal use – especially at agricultural and urban sites that exhibited the highest levels in air. PAHs showed highest concentrations (pg m−3) at agricultural and urban sites, ranging from 290 to 4 700 and were generally consistent with other data sets from Europe. PAHs were dominated by the 3–ring PAHs (76±6)%, with phenanthrene alone accounting for (45±11%) of the total PAHs. This study demonstrates the feasibility of using PUF disks as time–integrating passive air samplers for assessing local and regional scale concentrations of a wide range of POPs in central Italy. Given their low cost and simplicity, passive air samplers are the preferred option for conducting concurrent sampling at multiple sites for monitoring and research purposes

Monitoring persistent organic chemicals in Antarctica in support of global chemical policy: a horizon scan of priority actions and challenges

Global production and emission of chemicals exceeds societal capacities for assessment and monitoring. This situation calls for improved chemical regulatory policy frameworks and increased support for expedited decision making within existing frameworks. The polar regions of the Earth represent unique sentinel areas for the study of global chemical behaviour, and data arising from these areas can strengthen existing policy frameworks. However, chemical pollution research and monitoring in the Antarctic is underdeveloped, with geopolitical complexities and the absence of legal recognition of international chemical policy serving to neutralise progress made in other global regions. This Personal View represents a horizon scan by the action group Input Pathways of Persistent Organic Pollutants to Antarctica, of the Scientific Committee for Antarctic Research. Four priority research and research facilitation gaps are outlined, with recommendations for Antarctica Treaty parties for strategic action against these priorities

Antarctic: Persistent Organic Pollutants and Environmental Health in the Region

The geographic isolation and extreme climate of Antarctica and the Southern Ocean are responsible for both their late discovery by man and the absence of any human impact (towns, industry, and mining), except for the scientific stations. Unfortunately, many studies have demonstrated that even this remote continent and ocean has been reached by ubiquitous, persistent, and toxic contaminants. The main aim of this article is to review critically the data on the presence of these contaminants in Antarctic organisms, in the framework of the interactions between polar regions and the global changes

Contamination Profile and Temporal Trend of POPs in Antarctic Biota.

CRC Pres

Industrial contaminants in Antarctic biota

A critical review of the levels and patterns of industrial contaminants in biota from Antarctica and the Southern Ocean revealed that concentrations are low with respect to other regions of the world, although in some specimens/species (e.g. leopard seal, some invertebrates) they are occasionally high and comparable to those found in regions with a strong human impact; the highest levels of persistent organic pollutants (POPs) were detected in the vicinity of scientific stations. Bioconcentration prevails at the lower trophic levels of pelagic food webs, while biomagnification can become the main route of contamination at higher levels. In a benthic food web, biomagnification poses a major risk for organisms that accumulate lipids to overwinter, compared to those that accumulate glycogen. Hexachlorobenzene, DDTs and chlordanes showed similar concentrations and patterns in the 1980s-1990s period in organisms from Western and Eastern Antarctica, while the polychlorinated biphenyls time trend was different in a variety of species from the two regions

POPs in Antarctic ecosystems: is climate change affecting their temporal trends?

Climate change is affecting Antarctica and the Southern Ocean and effects have been already reported for the abiotic compartments of the ecosystems, e.g. ice loss and iceberg calving. Global warming can alter also the distribution of persistent organic pollutant (POPs) both at a global scale and in the Antarctic Region, due to their physical–chemical characteristics. Effects of climate changes have been already reported on feeding behaviour and reproductive process of organisms. Another consequence for organisms includes the POP bioaccumulation. Here we review the literature reporting the linkage between recorded effects of climate changes and POP bioaccumulation in resident marine Antarctic species (fish and penguins). Notwithstanding Antarctica is a final sink for persistent contaminants due to the extreme cold climate, a general decreasing POP trend has been observed for some POPs. Their concentrations in biota are reported to be linked to ice melting and large iceberg calving; the peculiar marine Antarctic ecosystems and the pelagic-benthic coupling may also contribute to alterations in the bioaccumulation processes. These effects are similar in polar regions, although the comparison with the Arctic biota is not possible due to the lack of data in the Antarctic Region. It remains an open question if the POP amount accumulated in the Antarctic ecosystems is decreasing or not