Knudsen Diffusion in Silicon Nanochannels

Measurements on helium and argon gas flow through an array of parallel, linear channels of 12 nm diameter and 200 micrometer length in a single crystalline silicon membrane reveal a Knudsen diffusion type transport from 10^2 to 10^7 in Knudsen number Kn. The classic scaling prediction for the transport diffusion coefficient on temperature and mass of diffusing species,D_He ~ sqrt(T), is confirmed over a T range from 40 K to 300 K for He and for the ratio of D_He/D_Ar ~ sqrt(m_Ar/m_He). Deviations of the channels from a cylindrical form, resolved with transmission electron microscopy down to subnanometer scales, quantitatively account for a reduced diffusivity as compared to Knudsen diffusion in ideal tubular channels. The membrane permeation experiments are described over 10 orders of magnitude in Kn, encompassing the transition flow regime, by the unified flow model of Beskok and Karniadakis.Comment: 4 pages, 3 figure

Imbibition in mesoporous silica: rheological concepts and experiments on water and a liquid crystal

We present, along with some fundamental concepts regarding imbibition of liquids in porous hosts, an experimental, gravimetric study on the capillarity-driven invasion dynamics of water and of the rod-like liquid crystal octyloxycyanobiphenyl (8OCB) in networks of pores a few nanometers across in monolithic silica glass (Vycor). We observe, in agreement with theoretical predictions, square root of time invasion dynamics and a sticky velocity boundary condition for both liquids investigated. Temperature-dependent spontaneous imbibition experiments on 8OCB reveal the existence of a paranematic phase due to the molecular alignment induced by the pore walls even at temperatures well beyond the clearing point. The ever present velocity gradient in the pores is likely to further enhance this ordering phenomenon and prevent any layering in molecular stacks, eventually resulting in a suppression of the smectic phase in favor of the nematic phase.Comment: 18 pages, 8 figure

Locked nailing for the treatment of displaced articular fractures of the calcaneus: description of a new procedure with calcanail®

Although open reduction and internal fixation is considered the best method for treating displaced articular fractures of the calcaneus, lateral approach is at high risk for wound healing complications. For this reason, the authors developed a posterior approach and a new implant to perform both intrafocal reduction and internal fixation. The aim of this technical note is to describe this method of treatment for displaced articular fractures of the calcaneus, which offered the following advantages: (a) the creation of a working channel that provides also a significant bone autograft, (b) the intrafocal reduction of the displaced articular surface, (c) the insertion of a locking nail that maintains the reduced articular surface at the right height, (d) the possibility to switch from an ORIF to a reconstruction arthrodesis with the same approach and instrumentation in case of severely damaged posterior facet

Impact of Node Ablation on the Morphogenesis of the Body Axis and the Lateral Asymmetry of the Mouse Embryo during Early Organogenesis

AbstractThe node of the mouse gastrula is the major source of the progenitor cells of the notochord, the floor plate, and the gut endoderm. The node may also play a morphogenetic role since it can induce a partial body axis following heterotopic transplantation. The impact of losing these progenitor cells and the morphogenetic activity on the development of the body axes was studied by the ablation of the node at late gastrulation. In the ablated embryo, an apparently intact anterior–posterior body axis with morphologically normal head folds, neural tube, and primitive streak developed during early organogenesis. Cell fate analysis revealed that the loss of the node elicits de novo recruitment of neural ectoderm and somitic mesoderm from the surrounding germ-layer tissues. This leads to the restoration of the neural tube and the paraxial mesoderm. However, the body axis of the embryo was foreshortened and somite formation was retarded. Histological and gene expression studies reveal that in most of the node-ablated embryos, the notochord in the trunk was either absent or interrupted, and the floor plate was absent in the ventral region of the reconstituted neural tube. The loss of the node did not affect the differentiation of the gut endoderm or the formation of the mid- and hindgut. In the node-ablated embryo, expression of the Pitx2 gene in the lateral plate mesoderm was no longer restricted to the left side but was found on both sides of the body or was completely absent from the lateral plate mesoderm. Therefore, the loss of the node results in the failure to delineate the laterality of the body axis. The node and its derivatives therefore play a critical role in the patterning of the ventral neural tube and lateral body axis but not of the anterior–posterior axis during early organogenesis

Signatures in a Giant Radio Galaxy of a Cosmological Shock Wave at Intersecting Filaments of Galaxies

Sensitive images of low-level, Mpc-sized radio cocoons offer new opportunities to probe large scale intergalactic gas flows outside clusters of galaxies. New radio images of high surface brightness sensitivity at strategically chosen wavelengths of the giant radio galaxy NGC 315 (Mack et al. 1997,1998) reveal significant asymmetries and particularities in the morphology, radio spectrum and polarization of the ejected radio plasma. We argue that the combination of these signatures provides a sensitive probe of an environmental shock wave. Analysis of optical redshifts in NGC 315 vicinity confirms its location to be near, or at a site of large-scale flow collisions in the 100 Mpc sized Pisces-Perseus Supercluster region. NGC 315 resides at the intersection of several galaxy filaments, and its radio plasma serves there as a `weather station' (Burns 1998) probing the flow of the elusive and previously invisible IGM gas. If our interpretation is correct, this is the first indication for a shock wave in flows caused by the cosmological large scale structure formation, which is located in a filament of galaxies. The possibility that the putative shock wave is a source of gamma-rays and ultra high energy cosmic rays is briefly discussed.Comment: accepted by Astrophysical Journal Letters, 4 pages, 3 figures (incl. 2 color), uses emulateapj5.sty (included), aastex.sty (included) and psfig.st

Otolith geochemistry discriminates among estuarine nursery areas of Solea solea and S. senegalensis over time

Author Posting. © The Author(s), 2012. This is the author's version of the work. It is posted here by permission of Inter-Research for personal use, not for redistribution. The definitive version was published in Marine Ecology Progress Series 452 (2012): 193-203, doi:10.3354/meps09621.Otolith geochemistry is used increasingly as a natural tag to retrospectively determine habitat use in marine fishes. It is necessary to first conduct a thorough assessment of spatio-temporal variability before attempting to use the approach to determine estuarine residency or natal origins. In particular, knowledge of temporal variation at different scales is important when such variability may confound spatial discrimination. We assayed elements and calculated the elemental ratios to Ca (Li:Ca, Mg:Ca, Mn:Ca, Cu:Ca, Sr:Ca, Ba:Ca, Pb:Ca) in otoliths of juvenile Solea solea and Solea senegalensis, collected over several months in 2006 and 2009 in Portuguese estuaries, using laser ablation inductively coupled plasma mass spectrometry (LA ICP-MS). The elemental compositions of the otoliths varied significantly between and within years in both of the species, although the within-year variability did not interfere in spatial discrimination. The overall classification accuracy of juveniles to their estuaries of origin varied among the years and species, ranging from 71.0% to 80.1%. Established elemental signatures constitute the baseline data for future assessments of connectivity between juvenile and adult populations of the two sole species.This study was funded by the ‘Fundação para a Ciência e a Tecnologia’ (FCT), PEst-OE/MAR/UI0199/2011. S. E. Tanner was funded with a PhD grant from FCT (SFRH/BD/40313/2007)

Magellan Spectroscopy of AGN Candidates in the COSMOS Field

We present spectroscopic redshifts for the first 466 X-ray and radio-selected AGN targets in the 2 deg^2 COSMOS field. Spectra were obtained with the IMACS instrument on the Magellan (Baade) telescope, using the nod-and-shuffle technique. We identify a variety of Type 1 and Type 2 AGN, as well as red galaxies with no emission lines. Our redshift yield is 72% down to i_AB=24, although the yield is >90% for i_AB<22. We expect the completeness to increase as the survey continues. When our survey is complete and additional redshifts from the zCOSMOS project are included, we anticipate ~1100 AGN with redshifts over the entire COSMOS field. Our redshift survey is consistent with an obscured AGN population that peaks at z~0.7, although further work is necessary to disentangle the selection effects.Comment: 19 pages, 14 figures. Accepted to ApJS special COSMOS issue. The full electronic version of Table 2 can be found at http://shaihulud.as.arizona.edu/~jtrump/tab2.tx