6 research outputs found
Formation of material prescribed phase composition from refractory filler silica powder modified with alkoxide and sol-gel composite
Creation of ceramics and refractories with improved physicomechanical properties is possible with use of
nanomaterials in their technology. Introduction of SiC nanoparticles into a ceramic material charge by using
modified filler powders is proposed. Fillers modified with tetraethoxysilane during grinding leads to powder
crystal structure breakdown and SiC mechanochemical synthesis. The amount of -SiC synthesized in this
way depends on the amount of modifying additive. Results are provided for modified filler phase composition
before and after heat treatment at 1000°C, and mechanochemically synthesized SiC thermal stability is established. It is shown that sintering of modified electro-corundum worsens with an increase in amount of synthesized silicon carbide nanoparticles. The difference is demonstrated in phase composition formation with heat treatment of a mixture of modified and normal finely ground electrocorundum with a sol-gel binder and firing up to 1600°C. Silicon carbide nanoparticle synthesis does not exceed 3 – 7 % in both cases. Recommendations are given for use of corundum filler with a different amount of modifying additive
Synthesis of β-SiC in the intermediate layer of corundum coatings based on a sol-gel binder for protecting graphite objects from oxidation
A coating is developed for protecting graphite from oxidation at 2023 – 2223 K. The efficiency of the protective action of a corundum coating based on a sol-gel binder increases due to creating a dense intermediate layer between the graphite substrate and the coating as a result of its self-reinforcement with fibers of mullite crystals and -SiC nanoparticles. Components of a modifier and sol-gel binder, but not carbon of the graphite substrate, provide synthesis of β-SiC
Features of high-strength composite material structure creation
The basis of technology proposed is use of a sol-gel method for preventing polycrystalline corundum fiber
from crystallization during heating to high temperature and for low-temperature synthesis of prescribed
phases in a corundum matrix with the aim of improving the operating properties of composite materials based
on corundum. As a result of firing a charge based on corundum powder modified with tetraethoxysilane and
polycrystalline corundum fiber modified with ethylsilicate-32 at 1360°C materials are created with very good
strength properties. The materials exhibit electrical insulation properties and are stable in ionized gas streams
at the level of known analogs as a result of creating self-reinforced mullite and β-SiC corundum matrix, reinforced with polycrystalline fiber and rapidly sintered due to presence of silicon oxynitride
Oxidation-resistant nano-reinforced PC-refractories of modified phenol formaldehyde resin. Part 3. Formation mechanism of organic-inorganic complexes during low-temperature synthesis of nanoparticles of additional antioxidants and their effectiveness
SiC nanoparticles that could be used as an antioxidant for periclase-carbon (PC) refractories were synthesized from the organic—inorganic complex (‒СН₃)‒(SiO₂)n that formed during heating of silicon alkoxide and thermal destruction of its gels. Use of phenolformaldehyde resins modified with silicon alkoxide and its sols was proposed and enabled the formation of an organic—inorganic complex (-СН₃)‒(SiO₂)n‒С with a high C content. This increased the yield of SiC synthesized in the carbon binder. The addition of Ni precursors (additional antioxidant) formed an even more complicated organic—inorganic complex. Use of the complex (‒СН₃)‒(SiO₂)n‒Ni(NiO)‒С together with Al improved the operating characteristics of the PC refractories. It was found that their resistance to oxidation was increased after the complex antioxidant Al + SiC + Ni(NiO) formed
Oxidation resistance of nano-reinforced PC-refractories modified with phenol formaldehyde resin. Part 4. Thermodynamic evaluation of phase formation within Mg–O–C–Al, Mg–O–C–Ni and МgO‒Al₂O₃‒NiO‒SiO₂ systems using SiC + Al + Ni (NiO) complex antioxidant
Results are given for the synthesis and co-existence of phases formed from components of complex organic-
inorganic antioxidant formed during modification of phenol-formaldehyde resin (PFR) and graphite with silica alkoxide and inorganic or organic nickel precursors. Thermodynamic analysis is given for the Mg–Al–C and Mg–O–Ni–C systems. It is shown that the periclase and carbon can coexist with aluminum and nickel, and also that oxidized antioxidants Al₂O₃ and NiO can interact respectively with the periclase and with the synthesized SiC formed during modification of PFR with silica. In considering the NiO‒MgO‒Al₂O₃‒SiO₂ system it is established that during service noble spinel will be synthesized from the complex antioxidant components, facilitating an increase in PC-refractory durability in service