Mechanism of Catalytic Behavior and Structure of Active Centers in CuY Zeolite

The experimental and theoretical basis for the activated coppere xchanged Y zeolite system have been studied by the observation and analysis in the electronspin resonanace (ESR) , infrared (IR) and extended X-ray absorption fine structure (EXAFS) spectroscopies

FORMATION OF ACTIVE SITES ON IRON CATALYST

Fischer-Tropsch synthesis over preliminary carburized iron catalyst with CO was investigated in both isothermal and temperature programmed experiments under atmospheric pressure. In comparison with the freshly reduced catalyst, the pre-carburized catalyst showed similar activity for the formation of hydrocarbons at the steady state and shorter period of activation which decreased with the degree of carburization. The pre-carburization was observed to reduce the strength and to raise the amount of the CO adsorption. Since no significant differences were observed between the carburizations with CO/He and CO/H_2, it was confirmed that the role of the carburization during synthesis was not the formation of reaction intermediates but the development of the active surface available for catalysis

Preparation of Highly Dispersed Copper Particles in Zeolite

Temperature programmed reduction and desorption techniques have been used to investigate the reduction process of CuY. The reduction of Cu^2+ ions in zeolite with H_2 occurs via a two-step mechanism in which Cu^+ is first formed and then reduced to metal. In the first step of reduction NH_3 was used as the reducing agent instead of H_2. Cu particles in the reduced CuY with NH_3 pretreatment were uniformly dispersed compared with those of CuY without one. The average particle size of Cu metal was estimated to be 8.4 nm for the former and 18.5 nm for the latter. The detailed mechanism of reduction process of CuY has been discussed by the physico-chemical measurements, such as mass spectrometry, transmission electron microscope, infrared spectroscopy and electron spin resonance

Profiles of Methane Dimerization with a Glow Discharge Plasma System

The dimerization of methane in the absence of oxygen has been investigated in order to evaluate a newly-developed glow-discharge plasma reactor operated at atmospheric pressure. A homogeneous circular plasma zone is observed between two electrodes of a rotor and a stator, the former of which is rotating at a high speed to make a larger reaction zone. It was recognized that in a stream of flowing helium that methane is converted to C 2 hydrocarbons at high selectivities which decreased with the residence time in the plasma zone. The ratio of ethane : ethylene : acetylene (2 : 2 : 5) produced was, however, independent of the methane conversion

Performance Evaluation of Hydrogen Permeability of Pore-filling Membrane Prepared from Nanoparticles

ナノダイナミクス国際シンポジウム 平成22年1月21日(木) 於長崎大学Nagasaki Symposium on Nano-Dynamics 2010 (NSND2010), January 21, 2010, Nagasaki University, Nagasaki, Japan, Invited Lectur

Variable Stars in the Magellanic Clouds: Results from OGLE and SIRIUS

We have performed a cross-identification between OGLE-II data and single-epoch SIRIUS JHK survey data in the LMC and SMC. After eliminating obvious spurious variables, we determined the pulsation periods for 9,681 and 2,927 variables in the LMC and SMC, respectively. Based on these homogeneous data, we studied the pulsation properties and metallicity effects on period-K magnitude (PK) relations by comparing the variable stars in the LMC and SMC. The sample analyzed here is much larger, and we found the following new features: (1) variable red giants in the SMC form parallel sequences on the PK plane, just like those found by Wood (2000) in the LMC; (2) both of the sequences A and B of Wood (2000) have discontinuities, and they occur at the K-band luminosity of the TRGB; (3) the sequence B of Wood (2000) separates into three independent sequences B+- and C'; (4) comparison between the theoretical pulsation models (Wood et al. 1996) and observational data suggests that the variable red giants on sequences C and newly discovered C' are pulsating in the fundamental and first overtone mode, respectively; (5) the theory can not explain the pulsation mode of sequences A+- and B+-, and they are unlikely to be the sequences for the first and second overtone pulsators, as was previously suggested; (6) the zero points of PK relations of Cepheids in the metal deficient SMC are fainter than those of LMC ones by ~0.1 mag but those of SMC Miras are brighter than those of LMC ones by ~0.13 mag, which are probably due to metallicity effects.Comment: 9 pages, 10 figures, accepted for publication in MNRAS. High resolution version is available at: http://www.ioa.s.u-tokyo.ac.jp/~yita/scr/astro/papers/RefereedPaper/yitaMD250 .pd

Preparation of superparamagnetic magnetite nanoparticles by reverse precipitation method: Contribution of sonochemically generated oxidants.

Magnetic iron oxide nanoparticles were successfully prepared by a novel reverse precipitation method with the irradiation of ultrasound. TEM, XRD and SQUID analyses showed that the formed particles were magnetite (Fe(3)O(4)) with about 10nm in their diameter. The magnetite nanoparticles exhibited superparamagnetism above 200K, and the saturation magnetization was 32.8emu/g at 300K. The sizes and size distributions could be controlled by the feeding conditions of FeSO(4).7H(2)O aqueous solution, and slower feeding rate and lower concentration lead to smaller and more uniform magnetite nanoparticles. The mechanisms of sonochemical oxidation were also discussed. The analyses of sonochemically produced oxidants in the presence of various gases suggested that besides sonochemically formed hydrogen peroxide, nitrite and nitrate ions contributed to Fe(II) ion oxidation

SiO Maser Sources toward Globular Clusters

We report on the detection of SiO masers in Asymptotic Giant Branch variables toward bulge/disk globular clusters. In five out of six cases, the radial velocities are compatible with the optically measured radial velocities of globular clusters in the assessed uncertainty. Two sources, toward Terzan~5 and Terzan~12, lie very close to the cluster centers. The objects toward Pal~6 and Terzan~12 have luminosities appropriate to the AGB tip in globular clusters, while those toward NGC 6171, Pal~10, and Terzan~5 are brighter than expected. It is suggested that the latter three may have evolved from merged binaries, offering a test for binary-evolution scenarios in globular clusters, if the membership is approved.Comment: 6 pages 1 figure PASJ, 57 No. 1 (in press

Interstellar Extinction Law in the J, H, and Ks Bands toward the Galactic Center

We have determined the ratios of total to selective extinction in the near-infrared bands (J, H, Ks) toward the Galactic center from the observations of the region |l| < 2.0deg and 0.5deg < |b| < 1.0deg with the IRSF telescope and the SIRIUS camera. Using the positions of red clump stars in color-magnitude diagrams as a tracer of the extinction and reddening, we determine the average of the ratios of total to selective extinction to be A(Ks)/E(H-Ks) = 1.44+-0.01, A(Ks)/E(J-Ks) = 0.494+-0.006, and A(H)/E(J-H) = 1.42+-0.02, which are significantly smaller than those obtained in previous studies. From these ratios, we estimate that A(J) : A(H) : A(Ks) = 1 : 0.573+-0.009 : 0.331+-0.004 and E(J-H)/E(H-Ks) = 1.72+-0.04, and we find that the power law A(lambda) \propto lambda^{-1.99+-0.02} is a good approximation over these wavelengths. Moreover, we find a small variation in A(Ks)/E(H-Ks) across our survey. This suggests that the infrared extinction law changes from one line of sight to another, and the so-called ``universality'' does not necessarily hold in the infrared wavelengths.Comment: 18 pages, 9 figures, Accepted for publication in the Ap

Preparation of Au-Pd Core-shell Nanoparticles Supported TiO2 and Influence of Photocatalytic Activity on the Shell Thickness

ナノダイナミクス国際シンポジウム 平成22年1月21日(木) 於長崎大学Nagasaki Symposium on Nano-Dynamics 2010 (NSND2010), January 21, 2010, Nagasaki University, Nagasaki, Japan, Invited Lectur