11 research outputs found
Polyethylenimine-Modified Graphene Oxide as a Novel Antibacterial Agent and Its Synergistic Effect with Daptomycin for Methicillin-Resistant <i>Staphylococcus aureus</i>
An
aqueous dispersion of polyethylenimine-modified graphene oxide
(PEI-GO) was prepared via a one-step synthesis through an epoxy ring-opening
reaction. PEI-GO exhibited bacterial growth inhibition activity on
methicillin-resistant <i>Staphylococcus aureus</i> (MRSA)
with a minimum inhibitory concentration as low as 8 Ī¼g mL<sup>ā1</sup>. Timeākill curve assay and SYTOX Green assay
showed the antibacterial activity and bacteria cell membrane permeability
of PEI-GO, respectively. Most importantly, when PEI-GO was employed
at 1ā2 Ī¼g mL<sup>ā1</sup>, a synergistic effect
with daptomycin to resensitize daptomycin-resistant MRSA was revealed.
A synergistic effect between PEI-GO and daptomycin provides a possible
way to increase bacterial killing and reduce the development of daptomycin
resistance. The antibacterial activity of PEI-GO is attributed to
the damaged cell membrane caused by the sharp edge and chain structure
of the PEI-GO nanosheets as well as the high density of amine groups
present in the PEI chains. Our results indicate that PEI-GO dispersion
has a great potential for clinical pathogenic bacteria treatment
Omnidirectional Harvesting of Weak Light Using a Graphene Quantum Dot-Modified Organic/Silicon Hybrid Device
Despite
great improvements in traditional inorganic photodetectors
and photovoltaics, more progress is needed in the detection/collection
of light at low-level conditions. Traditional photodetectors tend
to suffer from high noise when operated at room temperature; therefore,
these devices require additional cooling systems to detect weak or
dim light. Conventional solar cells also face the challenge of poor
light-harvesting capabilities in hazy or cloudy weather. The real
world features such varying levels of light, which makes it important
to develop strategies that allow optical devices to function when
conditions are less than optimal. In this work, we report an organic/inorganic
hybrid device that consists of graphene quantum dot-modified polyĀ(3,4-ethylenedioxythiophene)
polystyrenesulfonate spin-coated on Si for the detection/harvest of
weak light. The hybrid configuration provides the device with high
responsivity and detectability, omnidirectional light trapping, and
fast operation speed. To demonstrate the potential of this hybrid
device in real world applications, we measured near-infrared light
scattered through human tissue to demonstrate noninvasive oximetric
photodetection as well as characterized the deviceās photovoltaic
properties in outdoor (<i>i</i>.<i>e</i>., weather-dependent)
and indoor weak light conditions. This organic/inorganic device configuration
demonstrates a promising strategy for developing future high-performance
low-light compatible photodetectors and photovoltaics
Size and Dopant Dependent Single Particle Fluorescence Properties of Graphene Quantum Dots
The emissive properties of both doped
and nondoped graphene quantum
dots (GQDs) with sizes ranging from 3 to 11 nm were analyzed at the
single particle level. Both doped and nondoped GQDs are a composite
of particles exhibiting green, red, or NIR fluorescence on excitation
at 488, 561, and 640 nm, respectively. Nitrogen-doped GQDs (N-GQDs)
with diameters ranging from 3.4 to 5.2 nm show a larger proportion
of particles with NIR emission as compared to nondoped particles.
Doping of GQDs also resulted in changes in the photostability and
the fluorescence intermittency seen in single GQD particles. While
milliseconds to seconds time scale blinking was regularly observed
for red-emitting nondoped GQDs, nitrogen doping significantly reduced
blinking. Both doped and nondoped particles also exhibit moderate
size dependent photophysical properties
Wafer-Scale Synthesis of High-Quality Semiconducting Two-Dimensional Layered InSe with Broadband Photoresponse
Large-scale synthesis
of two-dimensional (2D) materials is one
of the significant issues for fabricating layered materials into practical
devices. As one of the typical IIIāVI semiconductors, InSe
has attracted much attention due to its outstanding electrical transport
property, attractive quantum physics characteristics, and dramatic
photoresponse when it is reduced to atomic scale. However, scalable
synthesis of single phase 2D InSe has not yet been achieved so far,
greatly hindering further fundamental studies and device applications.
Here, we demonstrate the direct growth of wafer-scale layered InSe
nanosheets by pulsed laser deposition (PLD). The obtained InSe layers
exhibit good uniformity, high crystallinity with macro texture feature,
and stoichiometric growth by <i>in situ</i> precise control.
The characterization of optical properties indicates that PLD grown
InSe nanosheets have a wide range tunable band gap (1.26ā2.20
eV) among the large-scale 2D crystals. The device demonstration of
field-effect transistor shows the n-type channel feature with high
mobility of 10 cm<sup>2</sup> V<sup>ā1</sup> s<sup>ā1</sup>. Upon illumination, InSe-based phototransistors show a broad photoresponse
to the wavelengths from ultraviolet to near-infrared. The maximum
photoresponsivity attains 27 A/W, plus a response time of 0.5 s for
the rise and 1.7 s for the decay, demonstrating the strong and fast
photodetection ability. Our findings suggest that the PLD grown InSe
would be a promising choice for future device applications in the
2D limit
Efficiency Enhancement of Silicon Heterojunction Solar Cells via Photon Management Using Graphene Quantum Dot as Downconverters
By
employing graphene quantum dots (GQDs), we have achieved a high
efficiency of 16.55% in n-type Si heterojunction solar cells. The
efficiency enhancement is based on the photon downconversion phenomenon
of GQDs to make more photons absorbed in the depletion region for
effective carrier separation, leading to the enhanced photovoltaic
effect. The short circuit current and the fill factor are increased
from 35.31 to 37.47 mA/cm<sup>2</sup> and 70.29% to 72.51%, respectively.
The work demonstrated here holds the promise for incorporating graphene-based
materials in commercially available solar devices for developing ultrahigh
efficiency photovoltaic cells in the future
Exceptional Tunability of Band Energy in a Compressively Strained Trilayer MoS<sub>2</sub> Sheet
Tuning band energies of semiconductors through strain engineering can significantly enhance their electronic, photonic, and spintronic performances. Although low-dimensional nanostructures are relatively flexible, the reported tunability of the band gap is within 100 meV per 1% strain. It is also challenging to control strains in atomically thin semiconductors precisely and monitor the optical and phonon properties simultaneously. Here, we developed an electromechanical device that can apply biaxial compressive strain to trilayer MoS<sub>2</sub> supported by a piezoelectric substrate and covered by a transparent graphene electrode. Photoluminescence and Raman characterizations show that the direct band gap can be blue-shifted for ā¼300 meV per 1% strain. First-principles investigations confirm the blue-shift of the direct band gap and reveal a higher tunability of the indirect band gap than the direct one. The exceptionally high strain tunability of the electronic structure in MoS<sub>2</sub> promising a wide range of applications in functional nanodevices and the developed methodology should be generally applicable for two-dimensional semiconductors
Uncooled Mid-Infrared Sensing Enabled by Chip-Integrated Low-Temperature-Grown 2D PdTe<sub>2</sub> Dirac Semimetal
Next-generation
mid-infrared (MIR) imaging chips demand free-cooling
capability and high-level integration. The rising two-dimensional
(2D) semimetals with excellent infrared (IR) photoresponses are compliant
with these requirements. However, challenges remain in scalable growth
and substrate-dependence for on-chip integration. Here, we demonstrate
the inch-level 2D palladium ditelluride (PdTe2) Dirac semimetal
using a low-temperature self-stitched epitaxy (SSE) approach. The
low formation energy between two precursors facilitates low-temperature
multiple-point nucleation (ā¼300 Ā°C), growing up, and merging,
resulting in self-stitching of PdTe2 domains into a continuous
film, which is highly compatible with back-end-of-line (BEOL) technology.
The uncooled on-chip PdTe2/Si Schottky junction-based photodetector
exhibits an ultrabroadband photoresponse of up to 10.6 Ī¼m with
a large specific detectivity. Furthermore, the highly integrated device
array demonstrates high-resolution room-temperature imaging capability,
and the device can serve as an optical data receiver for IR optical
communication. This study paves the way toward low-temperature growth
of 2D semimetals for uncooled MIR sensing
Si Hybrid Solar Cells with 13% Efficiency <i>via</i> Concurrent Improvement in Optical and Electrical Properties by Employing Graphene Quantum Dots
By
employing graphene quantum dots (GQDs) in PEDOT:PSS, we have
achieved an efficiency of 13.22% in Si/PEDOT:PSS hybrid solar cells.
The efficiency enhancement is based on concurrent improvement in optical
and electrical properties by the photon downconversion process and
the improved conductivity of PEDOT:PSS via appropriate incorporation
of GQDs. After introducing GQDs into PEDOT:PSS, the short circuit
current and the fill factor of rear-contact optimized hybrid cells
are increased from 32.11 to 36.26 mA/cm<sup>2</sup> and 62.85% to
63.87%, respectively. The organicāinorganic hybrid solar cell
obtained herein holds the promise for developing photon-managing,
low-cost, and highly efficient photovoltaic devices
Nonlithographic Fabrication of Crystalline Silicon Nanodots on Graphene
We report a nonlithographic fabrication method to grow uniform and large-scale crystalline silicon (Si) nanodot (c-SiNDs) arrays on single-layer graphene by an ultrathin anodic porous alumina template and Ni-induced Si crystallization technique. The lateral height of the template can be as thin as 160 nm and the crystallization of Si can be achieved at a low temperature of 400 Ā°C. The effects of c-SiNDs on graphene were studied by Raman spectroscopy. Furthermore, the c-SiNDs/graphene based field effect transistors were demonstrated
Deep Ultraviolet Photoluminescence of Water-Soluble Self-Passivated Graphene Quantum Dots
Glucose-derived water-soluble crystalline graphene quantum dots (GQDs) with an average diameter as small as 1.65 nm (ā¼5 layers) were prepared by a facile microwave-assisted hydrothermal method. The GQDs exhibits deep ultraviolet (DUV) emission of 4.1 eV, which is the shortest emission wavelength among all the solution-based QDs. The GQDs exhibit typical excitation wavelength-dependent properties as expected in carbon-based quantum dots. However, the emission wavelength is independent of the size of the GQDs. The unique optical properties of the GQDs are attributed to the self-passivated layer on the surface of the GQDs as revealed by electron energy loss spectroscopy. The photoluminescence quantum yields of the GQDs were determined to be 7ā11%. The GQDs are capable of converting blue light into white light when the GQDs are coated onto a blue light emitting diode