Superconductor Insulator Transition in Long MoGe Nanowires

Properties of one-dimensional superconducting wires depend on physical processes with different characteristic lengths. To identify the process dominant in the critical regime we have studied trans- port properties of very narrow (9-20 nm) MoGe wires fabricated by advanced electron-beam lithography in wide range of lengths, 1-25 microns. We observed that the wires undergo a superconductor -insulator transition that is controlled by cross sectional area of a wire and possibly also by the thickness-to-width ratio. Mean-field critical temperature decreases exponentially with the inverse of the wire cross section. We observed that qualitatively similar superconductor{insulator transition can be induced by external magnetic field. Some of our long superconducting MoGe nanowires can be identified as localized superconductors, namely in these wires one-electron localization length is much shorter than the length of a wire

Separating hyperfine from spin-orbit interactions in organic semiconductors by multi-octave magnetic resonance using coplanar waveguide microresonators

Separating the influence of hyperfine from spin-orbit interactions in spin-dependent carrier recombination and dissociation processes necessitates magnetic resonance spectroscopy over a wide range of frequencies. We have designed compact and versatile coplanar waveguide resonators for continuous-wave electrically detected magnetic resonance, and tested these on organic light-emitting diodes. By exploiting both the fundamental and higher-harmonic modes of the resonators we cover almost five octaves in resonance frequency within a single setup. The measurements with a common pi-conjugated polymer as the active material reveal small but non-negligible effects of spin-orbit interactions, which give rise to a broadening of the magnetic resonance spectrum with increasing frequency

Efect of magnetic Gd impurities on superconductivity in MoGe films with different thickness and morphology

We studied the effect of magnetic doping with Gd atoms on the superconducting properties of amorphous Mo70Ge30 films. We observed that in uniform films deposited on amorphous Ge, the pair-breaking strength per impurity strongly decreases with film thickness initially and saturates at a finite value in films with thickness below the spin-orbit scattering length. The variation is likely caused by surface induced magnetic anisotropy and is consistent with the fermionic mechanism of superconductivity suppression. In thin films deposited on SiN the pair-breaking strength becomes zero. Possible reasons for this anomalous response are discussed. The morphological distinctions between the films of the two types were identified using atomic force microscopy with a carbon nanotube tip

Floquet spin states in OLEDs

Electron and hole spins in organic light-emitting diodes constitute prototypical two-level systems for the exploration of the ultrastrong-drive regime of light-matter interactions. Floquet solutions to the time-dependent Hamiltonian of pairs of electron and hole spins reveal that, under non-perturbative resonant drive, when spin-Rabi frequencies become comparable to the Larmor frequencies, hybrid light-matter states emerge that enable dipole-forbidden multi-quantum transitions at integer and fractional g-factors. To probe these phenomena experimentally, we develop an electrically detected magnetic-resonance experiment supporting oscillating driving fields comparable in amplitude to the static field defining the Zeeman splitting; and an organic semiconductor characterized by minimal local hyperfine fields allowing the non-perturbative light-matter interactions to be resolved. The experimental confirmation of the predicted Floquet states under strong-drive conditions demonstrates the presence of hybrid light-matter spin excitations at room temperature. These dressed states are insensitive to power broadening, display Bloch-Siegert-like shifts, and are suggestive of long spin coherence times, implying potential applicability for quantum sensing

Perdeuteration of poly[2-methoxy-5-(2'- ethylhexyloxy)-1,4-phenylenevinylene] (d-MEH-PPV): control of microscopic charge-carrier spin–spin coupling and of magnetic-field effects in optoelectronic devices

Control of the effective local hyperfine fields in a conjugated polymer, poly[2-methoxy-5-(2 '-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), by isotopic engineering is reported. These fields, evident as a frequency-independent line broadening mechanism in electrically detected magnetic resonance (EDMR) spectroscopy, originate from the unresolved hyperfine coupling between the electronic spin of charge carrier pairs and the nuclear spins of surrounding hydrogen isotopes. The room temperature study of effects caused by complete deuteration of this polymer through magnetoresistance, magnetoelectroluminescence, coherent pulsed and multi-frequency EDMR, as well as inverse spin-Hall effect measurements, confirm the weak hyperfine broadening of charge-carrier magnetic resonance lines. As a consequence, we can resolve coherent charge-carrier spin-beating, allowing for direct measurements of the magnitude of electronic spin-spin interactions. In addition, the weak hyperfine coupling allows us to resolve substantial spin-orbit coupling effects in the EDMR spectra, even at low magnetic field strengths. These results illustrate the dramatic influence of hyperfine fields on the spin physics of organic light-emitting diode (OLED) materials at room temperature, and point to routes to reaching exotic ultra-strong resonant-drive regimes in the study of light-matter interactions

Doctor of Philosophy

dissertationThis dissertation focuses on the exploration of nonlinear magnetic resonance effects that occur under the ultra-strong magnetic resonant drive of electron spin transitions when the ratio of the driving field amplitude (B1) and the static magnetic Zeeman field B0 are close to 1. The ultra-strong and deep strong (B1/B0 > 1) drive regimes of electronic transitions, both magnetic dipolar and electric dipolar transitions, have attracted a lot of attention in recent years, as observables revealing strong drive may be used as potential indicators for ultra-strong light-matter coupling effects that occur when electron/photon hybridization takes place. For the work presented in this dissertation, spin-dependent electron-hole polaron transitions in polymer-based bipolar injection devices (layer structures that are essentially equivalent to organic light-emitting diodes, OLEDs) were used as probes for room temperature electron spin resonance under very low Zeeman field conditions (~3 mT). Spin permutation symmetry-dependent charge carrier recombination rates in materials with weak spin-orbit coupling (which causes spin conservation) change in the presence of magnetic resonant drive. Thus, by measurement of these rates, e.g., through current measurements, magnetic resonance can be recorded in the near complete absence of spin polarization. This phenomenon, also known as electrically detected magnetic resonance (EDMR) has been exploited in this dissertation for the exploration of the ultra-strong drive regime through maximization of B1, which was accomplished through the integration of a microscopic device structure and a resonant radio-frequency (RF) source (a thin-film microwire) into a single monolithic thin-film layer stack. Using RF driving powers in the mW range, B1 of more than 2mT was demonstrated and a variety of strong magnetic resonance drive phenomena were observed, including the inversion of the EDMR current change due to spin-collectivity (the spin-Dicke effect) as well as the Bloch-Siegert-shift. The developed nanolayer device stack allowed for the demonstration of macroscopic spin collectivity that emerges in polymer devices at room temperature. The work presented indicates that the strong drive effects could potentially serve as an indicator for ultra-strong light-matter coupling experiments in which the paramagnetic polaron states of charge carriers in polymers would serve as two-level spin quantum systems (Qubits)

Comparative Study of Bottled Water Microbial and Physicochemical Quality with National Standards and its label ( A Case Study in Qazvin City, Iran)

Background and Objectives: Water is essential for sustaining life & adequate safe supplies must be accessible to the public. Nowadays, people prefer to purchase bottled water for reasons including taste, convenience, following fashion, and its safety and sanitary conditions. According to the WHO guideline, it is of great importance to control the bottled water because of keeping it for longer period of time and at higher temperature in comparison with the water of distribution networks, reusing containers and bottles without adequate washing and disinfecting, and more growth of microorganisms having less important in the terms of health. The aim of this study was to investigate the microbial and physicochemical quality of bottled water in the stores of Qazvin City and to compare the aforesaid features with national standards and to check the quality with the bottles label. Materials and Methods: In this cross-sectional study, 51 samples of 11 bottled water brands with different production date were obtained. The features were studied in accordance with Standard Methods. Then, the data were analyzed by T-Test and one way ANOVA analysis using SPSS software. Eventually, the results were compared with the national standards, the WHO guidelines, and the product labels.Results: Results showed lack of microbial contamination of the samples. Physically and chemically, all the parameters measured were below the national standards level. Study of conformity of the variables to the label indicated that mostly there was a significant difference between the values measured and the values listed on the product labels. Conclusion: Although the concentration of microbial, physical and chemical features of samples were in the extent of national standards, there was a meaningful difference between labels and measured values so that the average concentration of TDS, TH, SO4-2, Ca2+, Mg2+ and Na+ would be more than the label values and the average of the other parameters was lower than the label values

Monolithic OLED-Microwire Devices for Ultrastrong Magnetic Resonant Excitation

Organic light-emitting diodes (OLEDs) make highly sensitive probes to test magnetic resonance phenomena under unconventional conditions since spin precession controls singlet-triplet transitions of electron-hole pairs, which in turn give rise to distinct recombination currents in conductivity. Electron paramagnetic resonance can therefore be detected in the absence of spin polarization. We exploit this characteristic to explore the exotic regime of ultrastrong light matter coupling, where the Rabi frequency of a charge carrier spin is of the order of the transition frequency of the two-level system. To reach this domain, we have to lower the Zeeman splitting of the spin states, defined by the static magnetic field B-0, and raise the strength of the oscillatory driving field of the resonance, B-1. This is achieved by shrinking the OLED and bringing the source of resonant radio frequency (RF) radiation as close as possible to the organic semiconductor in a monolithic device structure, which incorporates an OLED fabricated directly on top of an RF microwire within one monolithic thin-film device structure. With an RF driving power in the milliwatt range applied to the microwire, the regime of bleaching and inversion of the magnetic resonance signal is reached due to the onset of the spin-Dicke effect. In this example of ultrastrong light-matter coupling, the individual resonant spin transitions of electron-hole pairs become indistinguishable with respect to the driving field, and superradiance of the magnetic dipole transitions sets in