Dynamical mean-field theory of photoemission spectra of actinide compounds

A model of photoemission spectra of actinide compounds is presented. The complete multiplet spectrum of a single ion is calculated by exact diagonalization of the two-body Hamiltonian of the f^n shell. A coupling to auxiliary fermion states models the interaction with a conduction sea. The ensuing self-energy function is combined with a band Hamiltonian of the compound, calculated in the local-density approximation, to produce a solid state Green's function. The theory is applied to PuSe and elemental Am. For PuSe a sharp resonance at the Fermi level arises from mixed valent behavior, while several features at larger binding energies can be identified with quantum numbers of the atomic system. For Am the ground state is dominated by the |f^6;J=0> singlet but the strong coupling to the conduction electrons mixes in a significant amount of f^7 character.Comment: Solid State Communications, in press; 4 pages 4 figure

The Cerium volume collapse: Results from the LDA+DMFT approach

The merger of density-functional theory in the local density approximation (LDA) and many-body dynamical mean field theory (DMFT) allows for an ab initio calculation of Ce including the inherent 4f electronic correlations. We solve the DMFT equations by the quantum Monte Carlo (QMC) technique and calculate the Ce energy, spectrum, and double occupancy as a function of volume. At low temperatures, the correlation energy exhibits an anomalous region of negative curvature which drives the system towards a thermodynamic instability, i.e., the $\gamma$-to-$\alpha$ volume collapse, consistent with experiment. The connection of the energetic with the spectral evolution shows that the physical origin of the energy anomaly and, thus, the volume collapse is the appearance of a quasiparticle resonance in the 4f-spectrum which is accompanied by a rapid growth in the double occupancy.Comment: 4 pages, 3 figure

Coexistence of ferromagnetism and superconductivity

A comprehensive theory is developed that describes the coexistence of p-wave, spin-triplet superconductivity and itinerant ferromagnetism. It is shown how to use field-theoretic techniques to derive both conventional strong-coupling theory, and analogous gap equations for superconductivity induced by magnetic fluctuations. It is then shown and discussed in detail that the magnetic fluctuations are generically stronger on the ferromagnetic side of the magnetic phase boundary, which substantially enhances the superconducting critical temperature in the ferromagnetic phase over that in the paramagnetic one. The resulting phase diagram is compared with the experimental observations in UGe_2 and ZrZn_2.Comment: 16 pp., REVTeX, 6 eps figs; final version as publishe

Multi-phonon Resonant Raman Scattering Predicted in LaMnO3 from the Franck-Condon Process via Self-Trapped Excitons

Resonant behavior of the Raman process is predicted when the laser frequency is close to the orbital excitation energy of LaMnO3 at 2 eV. The incident photon creates a vibrationally excited self-trapped ``orbiton'' state from the orbitally-ordered Jahn-Teller (JT) ground state. Trapping occurs by local oxygen rearrangement. Then the Franck-Condon mechanism activates multiphonon Raman scattering. The amplitude of the $n$-phonon process is first order in the electron-phonon coupling $g$. The resonance occurs {\it via} a dipole forbidden $d$ to $d$ transition. We previously suggested that this transition (also seen in optical reflectivity) becomes allowed because of asymmetric oxygen fluctuations. Here we calculate the magnitude of the corresponding matrix element using local spin-density functional theory. This calculation agrees to better than a factor of two with our previous value extracted from experiment. This allows us to calculate the absolute value of the Raman tensor for multiphonon scattering. Observation of this effect would be a direct confirmation of the importance of the JT electron-phonon term and the presence of self-trapped orbital excitons, or ``orbitons''.Comment: 8 pages and 3 embedded figures. The earlier short version is now replaced by a more complete paper with a slightly different title. This version includes a caculation by density-functional theory of the dipole matrix element for exciting the self-trapped orbital exciton which activates the multiphonon Raman signal

First-principles calculations of the self-trapped exciton in crystalline NaCl

The atomic and electronic structure of the lowest triplet state of the off-center (C2v symmetry) self-trapped exciton (STE) in crystalline NaCl is calculated using the local-spin-density (LSDA) approximation. In addition, the Franck-Condon broadening of the luminescence peak and the a1g -> b3u absorption peak are calculated and compared to experiment. LSDA accurately predicts transition energies if the initial and final states are both localized or delocalized, but 1 eV discrepancies with experiment occur if one state is localized and the other is delocalized.Comment: 4 pages with 4 embeddded figure

Fabrication of microchannels using polynorbornene photosensitive sacrificial materials

© 2003 The Electrochemical Society, Inc. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).A processing method has been demonstrated for the fabrication of microchannels using photosensitive polynorbornene copolymer based sacrificial materials. The channel geometric patterns of sacrificial polymer were made via photolithography. The sacrificial polymer patterns were encapsulated with a dielectric medium and then thermally decomposed to form air channels. For the thermal decomposition of sacrificial polymer, the heating program was determined on the basis of the kinetic model obtained from thermogravimetric analysis to maintain the decomposition at a constant rate. The results indicate that a properly selected heating program can avoid the deformation in the channel structure; at the same conditions, a large-size channel is more easily deformed than a small one. The tapered-structure microchannels were also produced using a gray-scale mask. The result shows that a suitably low contrast for the photosensitive sacrificial material can lead to smooth and tapered microchannels

¿La presupuestación tiene algún futuro?

Resumen Presupuestar es decidir sobre la base de informaciones inadecuadas, sin conocer la forma en que los créditos anteriores fueron utilizados o lo que fue realizado, ni tampoco los resultados que podrían dar las nuevas asignaciones. La presupuestación es un proceso que obedece a una lógica de plazos, en el cual la regla es una toma de decisiones sub-óptima, porque el Estado no tiene la posibilidad de no tomar ninguna decisión. Cuando un ciclo llega a su término, el siguiente empieza sin plazos y según un esquema idéntico al del año anterior. La rutina de la presupuestación atenúa los conflictos pero también alimenta la frustración. En este mundo bajo presión, los que elaboran presupuestos o los que son afectados por ellos aspiran a un proceso más racional y más ordenado. Los responsables del presupuesto, en su búsqueda sin fin de mejores modalidades de repartición de los recursos y de planificación del trabajo de las autoridades públicas, emprenden a veces reformas radicales tales como la planificación y presupuestos por programas y el presupuesto base cero, aunque en general se esfuerzan por realizar ajustes sobre tal o cual elemento del proceso. Las correcciones son permanentes porque los cambios adoptados producen rara vez las mejoras esperadas. En el presupuesto, el fracaso de una reforma genera otra reforma. ¿La presupuestación tiene algún futuro? Aunque la presupuestación pública está condenada a perdurar, las evoluciones y las posibilidades dibujadas aquí permiten pensar que en el futuro los presupuestos serán quizás mayores, pero el proceso presupuestario será más débil

The future of budgeting: more of the same but different

Incluye Bibliografí

ASEXUAL REPRODUCTION AND GENETIC POPULATION STRUCTURE IN THE COLONIZING SEA ANEMONE HALIPLANELLA LUCIAE

Volume: 153Start Page: 604End Page: 61

Functionalized Polynorbornene Dielectric Polymers: Adhesion and Mechanical Properties

ABSTRACT: Within the microelectronics industry, there is an ongoing trend toward miniaturization coupled with higher performance. High glass-transition temperature polynorbornenes exhibit many of the key performance criteria necessary for these demanding applications. However, homopolynorbornene exhibits poor adhesion to common substrate materials, including silicon, silicon dioxide, aluminum, gold, and copper. In addition, this homopolymer is extremely brittle, yielding less than 1% elongationto-break values. To address these issues, the homopolymer was functionalized to improve adhesive and mechanical properties. Attaching triethoxysilyl groups to the polymer backbone substantially improved the adhesion, but at the cost of increasing the dielectric constant because of the polarity of the functional group. Alkyl groups were also added to the backbone, which decreased the rigidity of the system, and resulted in significantly higher elongation-to-break values and a decrease in residual stress. The addition of an alkyl group slightly decreased the dielectric constant of the polymer as a result of an increase in molar volume. The coefficient of thermal expansion and modulus are also reported for the polynorbornene functionalized with triethoxysilyl groups using a multiple substrate approach