Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)

In the title compound, [Ni(C7H4NS2)2(C7H9N3O3S)], the NiII ion is in a slightly distorted N4S2 octa­hedral coordination environment. The two benzothia­zole-2-thiol­ate ligands chelate via their thia­zole N and thiol­ate S atoms while the methyl 2-(2-amino­thia­zol-4-yl)-2-(methoxy­imino)acetate also acts as a chelate ligand binding through the thia­zole and imino N atoms. Intra­molecular N—H⋯N, C—H⋯N and C—H⋯O inter­actions contribute to the mol­ecular conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds produce R 1 2(6) rings and generate chains along the c axis. An extensive one-dimensional supra­molecular network of N—H⋯O hydrogen bonds and C—H⋯π inter­actions is responsible for the crystal structure stabilization