Formation of porous surface layers in reaction bonded silicon nitride during processing

An effort was undertaken to determine if the formation of the generally observed layer of large porosity adjacent to the as-nitride surfaces of reaction bonded silicon nitrides could be prevented during processing. Isostatically pressed test bars were prepared from wet vibratory milled Si powder. Sintering and nitriding were each done under three different conditions:(1) bars directly exposed to the furnance atmosphere; (2) bars packed in Si powder; (3) bars packed in Si3N4 powder. Packing the bars in either Si of Si3N4 powder during sintering retarded formation of the layer of large porosity. Only packing the bars in Si prevented formation of the layer during nitridation. The strongest bars (316 MPa) were those sintered in Si and nitrided in Si3N4 despite their having a layer of large surface porosity; failure initiated at very large pores and inclusions. The alpha/beta ratio was found to be directly proportional to the oxygen content; a possible explanation for this relationship is discussed

Capturing the scale and pattern of recurrent care proceedings: initial observations from a feasibility study

This article reports the initial findings of a feasibility study that has captured the scale and pattern of recurrent care proceedings. Although frontline professionals have reported long-standing concerns about the repeat clients of public law proceedings, prior to the study we report, the scale of the problem has been unknown. With funding from the Nuffield Foundation and support from the Child and Family Court Advisory Service (CAFCASS) and the President of the Family Division, the research team has arrived at a first estimate of prevalence, confirming that recurrence is a sizeable problem for the English family court. Based on cases that completed during the observational window 2007-2013 (calendar years), 7,143 birth mothers appeared in 15,645 recurrent care applications concerning 22,790 infants and children. Moreover, the study most likely underestimates recurrence, because reliable data concerning completed cases is not available before 2007. Initial observations are that the spacing between recurrent care proceedings is very short, which raises searching questions about prevention. Where episodes of care proceedings follow in swift succession, most likely prompted by the birth of another infant, this affords mothers little opportunity to effect change. Unless, this ‘status quo’ is tackled, it is difficult to envisage how vulnerable birth mothers can exit this cycle. Preliminary recommendations are made in respect of policy and practice change

Distributed lag models for hydrological data

The distributed lag model (DLM), used most prominently in air pollution studies, finds application wherever the effect of a covariate is delayed and distributed through time. We explore the use of modified formulations of DLMs to provide flexible varying-coeficient models with smoothness constraints, applicable in any setting in which lagged covariates are regressed on a time-dependent response. The models are applied to simulated flow and rainfall data and to flow data from a Scottish mountain river, with particular emphasis on approximating the relationship between environmental covariates and flow regimes in order to detect the influence of unobserved processes. It was found that under certain rainfall conditions some of the variability in the influence of rainfall on flow arises through a complex interaction between antecedent ground wetness and the time-delay in rainfall. The models are able to identify subtle changes in rainfall response, particularly in the location of peak influence in the lag structure and offer a computationally attractive approach for fitting DLMs

Sub-femtosecond electron bunches created by direct laser acceleration in a laser wakefield accelerator with ionization injection

In this work, we will show through three-dimensional particle-in-cell simulations that direct laser acceleration in laser a wakefield accelerator can generate sub-femtosecond electron bunches. Two simulations were done with two laser pulse durations, such that the shortest laser pulse occupies only a fraction of the first bubble, whereas the longer pulse fills the entire first bubble. In the latter case, as the trapped electrons moved forward and interacted with the high intensity region of the laser pulse, micro-bunching occurred naturally, producing 0.5 fs electron bunches. This is not observed in the short pulse simulation.Comment: AAC 201

Constraining Primordial Magnetism

Primordial magnetic fields could provide an explanation for the galactic magnetic fields observed today, in which case they may also leave interesting signals in the CMB and the small-scale matter power spectrum. We discuss how to approximately calculate the important non-linear magnetic effects within the guise of linear perturbation theory, and calculate the matter and CMB power spectra including the SZ contribution. We then use various cosmological datasets to constrain the form of the magnetic field power spectrum. Using solely large-scale CMB data (WMAP7, QUaD and ACBAR) we find a 95% CL on the variance of the magnetic field at 1 Mpc of B_\lambda < 6.4 nG. When we include SPT data to constrain the SZ effect, we find a revised limit of B_\lambda < 4.1 nG. The addition of SDSS Lyman-alpha data lowers this limit even further, roughly constraining the magnetic field to B_\lambda < 1.3 nG.Comment: 12 pages, 9 figure

Reaction bonded silicon nitride prepared from wet attrition-milled silicon

Silicon powder wet milled in heptane was dried, compacted into test bar shape, helium-sintered, and then reaction bonded in nitrogen-4 volume percent hydrogen. As-nitrided bend strengths averaged approximately 290 MPa at both room temperature and 1400 C. Fracture initiation appeared to be associated with subsurface flaws in high strength specimens and both subsurface and surface flaws in low strength specimens

Barriers to accessing psychological treatment for medium to high risk male young offenders

Within the young offender population, rates of personality disorder and mood disorders are considerably higher than both the general and adult offender population. Despite this high level of need and high risk of harm, psychological services within prisons are widely underutilized. Little is known about the barriers to accessing treatment for young offenders. This study investigated barriers to accessing psychological treatment for male young offenders detained in a UK prison. There were 128 participants, aged 18–21. A cross-sectional design compared self-reported barriers and psychological distress for Black and Minority Ethnic (BME) and White young offenders not accessing treatment, as well as those who were. A preference for self-reliance, a lack of trust in the prison system, lengthy waiting times and a general reluctance to talk about emotions were the most commonly cited barriers. BME young offenders not engaged in treatment reported significantly more barriers to accessing treatment than BME young offenders who were engaged in treatment, but both BME groups had equal levels of psychological distress. There was no significant difference between BME and White young offenders in the number of barriers reported, including stigma barriers. Future research should evaluate interventions to increase access for this marginalised population

Contrasts between Equilibrium and Non-equilibrium Steady States: Computer Aided Discoveries in Simple Lattice Gases

A century ago, the foundations of equilibrium statistical mechanics were laid. For a system in equilibrium with a thermal bath, much is understood through the Boltzmann factor, exp{-H[C]/kT}, for the probability of finding the system in any microscopic configuration C. In contrast, apart from some special cases, little is known about the corresponding probabilities, if the same system is in contact with more than one reservoir of energy, so that, even in stationary states, there is a constant energy flux through our system. These non-equilibrium steady states display many surprising properties. In particular, even the simplest generalization of the Ising model offers a wealth of unexpected phenomena. Mostly discovered through Monte Carlo simulations, some of the novel properties are understood while many remain unexplained. A brief review and some recent results will be presented, highlighting the sharp contrasts between the equilibrium Ising system and this non-equilibrium counterpart.Comment: 9 pages, 3 figure

A randomised, controlled, double blind, non-inferiority trial of ultrasound-guided fascia iliaca block vs. spinal morphine for analgesia after primary hip arthroplasty

We performed a single centre, double blind, randomised, controlled, non-inferiority study comparing ultrasound-guided fascia iliaca block with spinal morphine for the primary outcome of 24-h postoperative morphine consumption in patients undergoing primary total hip arthroplasty under spinal anaesthesia with levobupivacaine. One hundred and eight patients were randomly allocated to receive either ultrasound-guided fascia iliaca block with 2 mg.kg−1 levobupivacaine (fascia iliaca group) or spinal morphine 100 μg plus a sham ultrasound-guided fascia iliaca block using saline (spinal morphine group). The pre-defined non-inferiority margin was a median difference between the groups of 10 mg in cumulative intravenous morphine use in the first 24 h postoperatively. Patients in the fascia iliaca group received 25 mg more intravenous morphine than patients in the spinal morphine group (95% CI 9.0–30.5 mg, p &lt; 0.001). Ultrasound-guided fascia iliaca block was significantly worse than spinal morphine in the provision of analgesia in the first 24 h after total hip arthroplasty. No increase in side-effects was noted in the spinal morphine group but the study was not powered to investigate all secondary outcomes