Finding buried metallic pipes using a non-destructive approach based on 3D time-domain induced polarization data

International audienceThe location of buried utility pipes is often unknown. We use the time-domain induced polarization method to non-intrusively localize metallic pipes. A new approach, based on injecting a primary electrical current between a pair of electrodes and measuring the time-lapse voltage response on a set of potential electrodes after shutting down this primary current is used. The secondary voltage is measured on all the electrodes with respect to a single electrode used as a reference for the electrical potential, in a way similar to a self-potential time lapse survey. This secondary voltage is due to the formation of a secondary current density in the ground associated with the polarization of the metallic pipes. An algorithm is designed to localize the metallic object using the secondary voltage distribution by performing a tomography of the secondary source current density associated with the polarization of the pipes. This algorithm is first benchmarked on a synthetic case. Then, two laboratory sandbox experiments are performed with buried metallic pipes located in a sandbox filled with some clean sand. In Experiment #1, we use a horizontal copper pipe while in Experiment #2 we use an inclined stainless steel pipe. The result shows that the method is effective in localizing these two pipes. At the opposite, electrical resis-tivity tomography is not effective in localizing the pipes because they may appear resistive at low frequencies. This is due to the polarization of the metallic pipes which blocks the charge carriers at its external boundaries

Theoretical analysis of support stability in large dip angle coal seam mined with fully-mechanized top coal caving

Support stability is critical to ensure fully-mechanized top coal caving of large dip angle coal seam. To obtain the relations between each factor and hydraulic support stability, the mechanic model of large dip angle coal seam along face dip and strike was built to analyze support stability, including antitoppling, anti-slip, and anti-rotation of supports. The result indicates: Along the face dip, the suport stability was negatively correlated with dip angle; Higher top caving means lower anti-rotation at suport tail; With initial support force and working resistance of supports enhanced, the anti-slip, and antirotation stability of supports can be risen significantly. Along the strike, the critical toppling angle was proportional to dip angle, mining height, support weight, support width and support force; The critica slip angle was positive correlation with support force, friction coefficient of roof and supports. According to the results of both mechanical analysis and engineering projects, support stability in large dip angle can be risen efficiently and supports slipping, toppling and rotation can be avoided by selecting proper technical methods and equipment, like enhancing initial support force appropriately

A general and facile one-pot process of isothiocyanates from amines under aqueous conditions

A general and facile one-pot protocol for the preparation of a broad range of alkyl and aryl isothiocyanates has been developed from their corresponding primary amines under aqueous conditions. This synthetic process involves an in situ generation of a dithiocarbamate salt from the amine substrate by reacting with CS2 followed by elimination to form the isothiocyanate product with cyanuric acid as the desulfurylation reagent. The choice of solvent is of decisive importance for the successful formation of the dithiocarbamate salt particularly for highly electron-deficient substrates. This novel and economical method is suitable for scale-up activities

Responses of Micropterus salmoides under Ammonia Stress and the Effects of a Potential Ammonia Antidote

Ammonia is a common environmental limiting factor in aquaculture. To investigate the effects of ammonia stress and explore the protective effect of N-carbamylglutamate (NCG) on Micropterus salmoides (M. salmoides), tissue sections and parameters related to oxidative stress and the inflammatory response in M. salmoides were carried out during the ammonia stress test and feeding test. The results demonstrated that the LC50 for 24 h, 48 h, 72 h, and 96 h under ammonia stress in M. salmoides were 25.78 mg/L, 24.40 mg/L, 21.90 mg/L, and 19.61 mg/L, respectively. Under ammonia stress, the structures of the tissues were damaged, and the GSH content decreased, while the MDA content increased with the increase in stress time and ammonia concentration. The NO content fluctuated significantly after the ammonia nitrogen stress. In the 15-day feeding test, with the increased NCG addition amount and feeding time, the GSH content increased while the MDA and NO contents decreased gradually in the NCG addition groups (NL group: 150 mg/kg; NM group: 450 mg/kg; NH group: 750 mg/kg) when compared with their control group (CK group: 0 mg/kg). In the ammonia toxicology test after feeding, the damage to each tissue was alleviated in the NL, NM, and NH groups, and the contents of GSH, MDA, and NO in most tissues of the NH group were significantly different from those in the CK group. The results suggested that ammonia stress caused tissue damage in M. salmoides, provoking oxidative stress and inflammatory response. The addition of NCG to the feed enhances the anti-ammonia ability of M. salmoides. Moreover, the gill and liver might be the target organs of ammonia toxicity, and the brain and kidney might be the primary sites where NCG exerts its effects. Our findings could help us to find feasible ways to solve the existing problem of environmental stress in M. salmoides culture