Mineralogy and Geochemistry of Late Permian Coals within the Tongzi Coalfield in Guizhou Province, Southwest China

first_pagesettings Open AccessArticle Mineralogy and Geochemistry of Late Permian Coals within the Tongzi Coalfield in Guizhou Province, Southwest China by Baoqing Li 1,*,Xinguo Zhuang 1,Xavier Querol 1,2,Natalia Moreno 2OrcID,Linjian Yang 3,Yunfei Shangguan 1 andJing Li 1 1 Key Laboratory of Tectonics and Petroleum Resources (China University of Geosciences), Ministry of Education, Wuhan 430074, China 2 Institute of Environmental Assessment and Water Research, CSIC, C/Jordi Girona 18–26, 08034 Barcelona, Spain 3 No. 106 Geological Team of Guizhou Province Geology and Mineral Bureau, Zunyi 563000, China * Author to whom correspondence should be addressed. Minerals 2020, 10(1), 44; https://doi.org/10.3390/min10010044 Received: 18 December 2019 / Revised: 29 December 2019 / Accepted: 30 December 2019 / Published: 31 December 2019 (This article belongs to the Collection Minerals in Coal and Coal Combustion Products) Download PDF Browse Figures Abstract The lowermost Late Permian coal seam (C4 Coal) in the Tongzi Coalfield offers an opportunity to investigate the influence of terrigenous detrital materials from the Qianbei Upland on the mineralogical and geochemical patterns of the C4 Coal. The minerals are mainly dominated by pyrite and, to a lesser extent, tobelite, kaolinite, and calcite, along with traces of Al-oxyhydroxide minerals. The various degrees of marine influence may have resulted in the variation in the amount of Fe-sulfides (e.g., pyrite) and elements having Fe-sulfides affinity. Furthermore, the abundant Fe ions involved in the formation of Fe-sulfides were most likely derived from the claystone on the Qianbei Upland. The tobelite identified in the C4 Coal probably originated from the interaction between pre-existing kaolinite and NH4+ from NH3 released from the thermally affected organic matter at least shortly after the highly volatile bituminous stage under NH4+-rich and K+-poor conditions. The terrigenous detrital materials were derived from two possible sediment-region sources—the Qianbei Upland and Kangdian Upland—which is different from Late Permian coals in Western Guizhou Province. The claystone on the Qianbei Upland may have served as parent rock, as indicated by the presence of the Al-oxyhydroxide minerals as well as low SiO2/Al2O3 ratio (0.66 on average) and low quartz content. Meanwhile, the detrital materials from the Kangdian Upland most likely originated from the erosion of the felsic rocks at the uppermost part of the Kangdian Upland, as evidenced by the high Al2O3/TiO2 ratio (36.0 on average) and the strongly negative Eu anomaly (0.61 on average).The authors would like to give their sincere thanks to No. 106 Geological Team of Guizhou Province Geology for assistance during sampling and Institute of Environmental Assessment and Water Research, CSIC, Spain for assistance during the sample analysis. Also, many thanks are given to academic editor and two anonymous reviewers for their valuable comments on the manuscript.Peer reviewe

Comprehensive evaluation of potential coal mine dust emissions in an open-pit coal mine in Northwest China

Coal mining in China is continually increasing, and the associated emitted coal mine dust is of growing environmental and occupational concern. In this study, deposited coal mine dust (DD) was analysed in three different regions of an active, highly-volatile bituminous open-pit coal mine in the Xingjian Province, Northwest of China: coal working fronts, tailings handling sites, and road traffic sites. Samples were analysed for particle size, and geochemical and mineralogical patterns, and then compared with the respirable DD fractions (RDDs, <4 μm) separated from DD samples. Online measurements of ambient air concentrations of particulate matter (PM10 and PM2.5), black carbon (BC) and ultrafine particles (UFP) were performed in the same mine zones where DD was sampled. Furthermore, the RDD samples were subjected to analysis of specific biological response or toxicological indicators (oxidative potential, OP). The results demonstrated: i) large differences in particle size and composition among DD from tailings handling, road traffic and coal working front sites, ii) a strong influence of the DD moisture contents and ash yields on particle size, and, accordingly, on the potential dust emissions, iii) an enrichment of multiple elements (such as Nb, Th, Cr, Sr, Li, As, Pb, Cu, Zr and Ni) in the RDD from coal working fronts compared with their contents in the worked parent coal seams, mostly attributed to mining machinery, tyre and brake wear emissions and to deposition of dust emitted from gangue working zones, iv) low OP values of the RDD emitted from the studied mine, which works a high-quality coal, with OP being influenced by Mn, sulphate and anatase (TiO2) contents, and v) the impact of specific mining operations and mine areas on the levels of air pollutants, such as high PM from tailings handling in the upper parts of the mine or the high UFP levels in the bottom of the mine (due to vehicle and machinery emissions and lower dispersive conditions). The data presented here demonstrate the necessity of extracting the more deeply respirable size fraction of coal mine dusts in future studies on the health effects of these materials because this finer fraction is mineralogically and geochemically different from the parent rocks.This study was supported by Generalitat de Catalunya (AGAUR 2017 SGR41), Spain; by the National Science Foundation of China (grant 41972180); the Program of Introducing Talents of Discipline to Universities (grant B14031) and Overseas Top Scholars Program for the Recruitment of Global Experts, China and by the Spanish Ministry of Science and Innovation (Excelencia Severo Ochoa, Project CEX2018-000794-S). Pedro Trechera is contracted by the ROCD (Reducing risks from Occupational exposure to Coal Dust) project supported by the European Commission Research Fund for Coal and Steel; Grant Agreement Number-754205.Peer reviewe

Geochemistry and oxidative potential of the respirable fraction of powdered mined Chinese coals

This study evaluates geochemical and oxidative potential (OP) properties of the respirable (finer than 4 μm) fractions of 22 powdered coal samples from channel profiles (CP4) in Chinese mined coals. The CP4 fractions extracted from milled samples of 22 different coals were mineralogically and geochemically analysed and the relationships with the OP evaluated. The evaluation between CP4/CP demonstrated that CP4 increased concentrations of anatase, Cs, W, Zn and Zr, whereas sulphates, Fe, S, Mo, Mn, Hf and Ge decreased their CP4 concentrations. OP results from ascorbic acid (AA), glutathione (GSH) and dithiothreitol (DTT) tests evidenced a clear link between specific inorganic components of CP4 with OPAA and the organic fraction of OPGSH and OPDTT. Correlation analyses were performed for OP indicators and the geochemical patterns of CP4. These were compared with respirable dust samples from prior studies. They indicate that Fe (r = 0.83), pyrite (r = 0.66) and sulphate minerals (r = 0.42) (tracing acidic species from pyrite oxidation), followed by S (r = 0.50) and ash yield (r = 0.46), and, to a much lesser extent, Ti, anatase, U, Mo, V and Pb, are clearly linked with OPAA. Moreover, OPGSH correlation was identified by organic matter, as moisture (r = 0.73), Na (r = 0.56) and B (r = 0.51), and to a lesser extent by the coarse particle size, Ca and carbonate minerals. In addition, Mg (r = 0.70), B (r = 0.47), Na (r = 0.59), Mn, Ba, quartz, particle size and Sr regulate OPDTT correlations. These became more noticeable when the analysis was done for samples of the same type of coal rank, in this case, bituminous.This study was supported by Generalitat de Catalunya (AGAUR 2017 SGR41), Spain; by the National Science Foundation of China (grant 41972180); the Program of Introducing Talents of Discipline to Universities (grant B14031) and Overseas Top Scholars Program for the Recruitment of Global Experts, China; and by the Spanish Ministry of Science and Innovation (Excelencia Severo Ochoa, Project CEX2018-000794-S). Malvern Mastersizer Scirocco 2000 extension measurements were performed at the ICTS NANBIOSIS by the Nanostructured Liquids Unit (U12) of the CIBER in Bioengineering, Biomaterials & Nanomedicine (CIBER-BBN), located at the IQAC-CSIC (Barcelona, Spain). Pedro Trechera is contracted by the ROCD (Reducing risks from Occupational exposure to Coal Dust) project supported by the European Commission Research Fund for Coal and Steel; Grant Agreement Number 754205.Peer reviewe

Enrichment of Li–Ga–Zr–Hf and Se–Mo–Cr–V–As–Pb Assemblages in the No. 11 Superhigh Organic Sulfur Coal from the Sangshuping Coal Mine, Weibei Coalfield, Shaanxi, North China

© 2020 by the authors.Superhigh organic sulfur(SHOS) coals have currently attracted great attention due to their typical depositional environments and formation history as well as their great negative impact on the ecosystem. This study investigated the geochemistry of the No. 11coalof the Late Carboniferous Taiyuan Formation from the Sangshuping coalmine, Hancheng miningarea, Weibei coalfield, Shaanxi, North China. The No. 11 coal is a high-sulfur coal with a large proportion of organic sulfur content (3.7 to 5.5%, avg. 4.4%) and belongs to typical SHOS coal. The high sulfur content in the Sangshuping coal mine has been mainly caused by the combined influences of seawater and hydrothermal fluids. The SHOS in No. 11 coal was formed in the Fe-poor and S-rich high-marine influenced occlusive environment. During the late coalification stage, a high proportion of pyritic sulfur was formed due to sufficient Fe supply from the Fe–S-rich epigenetic hydrothermal fluids. The No. 11 SHOS coal is enriched in Li–Ga–Zr–Hf and Se–Mo–Cr–V–As–Pb element assemblages. The sediment provenance of the Sangshuping coal mine is predominantly felsic–intermediate rocks from both the Yinshan and Qinling Oldland. However, the elevated concentrations of critical elements (Li, Ga, Zr, and Hf) in the No. 11 coal are primarily inherited from the Yinshan Oldland. The enrichment of the Se–Mo–Cr–V–As–Pb assemblage in No. 11 coal can be ascribed to the influence of both seawater and epigenetic hydrothermal activity.This research was funded by the National Key R&D Program of China (No. 2018YFF0215400), the National Science Foundation of China (Nos. 41972179, 41972180), and the Fundamental Research Funds for the Central Universities (No. CUGCJ1819).Peer reviewe

Tire–Pavement Interaction Simulation Based on Finite Element Model and Response Surface Methodology

Acquiring accurate tire–pavement interaction information is crucial for pavement mechanical analysis and pavement maintenance. This paper combines the tire finite element model (FEM) and response surface methodology (RSM) to obtain tire–pavement interaction information and to analyze the pavement structure response under different loading conditions. A set of experiments was initially designed through the Box–Behnken design (BBD) method to obtain input and output variables for RSM calibration. The resultant RSM was evaluated accurately using the analysis of variance (ANOVA) approach. Then, tire loading simulations were conducted under different magnitudes of static loading using the optimal parameter combination obtained from the RSM. The results show that the deviations between the simulations and the real test results were mostly below 5%, validating the effectiveness of the tire FEM. Additionally, three different dynamic conditions—including free rolling, full brake, and full traction—were simulated by altering the tire rolling angle and translational velocities. Finally, the pavement mechanical response under the three rolling conditions was analyzed based on the tire–pavement contact feature

Behaviour and speciation of inorganic trace pollutants in a coal-fired power plant equipped with DENO<inf>X</inf>-SCR-ESP-NH<inf>3</inf>FGD controls

The behaviour and speciation of inorganic trace pollutants were studied in a 270 MWh coal-fired power station equipped with denitrification (DeNOx)-based selective catalytic reduction (SCR), electrostatic precipitators (ESP) and ammonia flue gas desulphurisation (NH3-FGD) controls. The aqueous (NH4)2SO4 slurry (pH 3.2) showed remarkably high concentrations of SO42−, Cl−, Fe, NH4+, PO43−, and F− and was substantially enriched in multiple trace pollutants, e.g. Mn, Ni, Zn, and As, which can be ascribed to the diffusion of gaseous pollutants released during combustion and to the partial dissolution of fly ash (FA) particles entrained in the flue gas FGD. These processes were favoured by the iteration of the FGD water re-circulation cycles within the scrubber. Three major unresolved performance issues remain for the NH3-FGD with respect to the retention efficiency of major and trace pollutants: (i) the high concentration of soluble salts and major and minor trace elements in the aqueous (NH4)2SO4 slurry could lead to entrainment of droplets and particles with the outgoing (OUT)-FGD gas; (ii) the ionic strength, as a result of the high concentration of the elements associated with soluble salts and major and minor elements, could lead to diminishing diffusivity of gaseous pollutants into the aqueous phase, where these are supposed to dissolve; and (iii) the acidic conditions of the aqueous (NH4)2SO4 slurry, caused by Fe-hydrolysis, could lead to low FGD efficiencies. Operating conditions at this power station affect Hg partitioning and fate across the PCC-SCR-ESP-NH3-FGD.We would like to thank the staff of the power plant for their support, help, and kind assistance during and after the sampling campaign. The corresponding author also gratefully acknowledges the Institute of Environmental Assessment and Water Research, Spanish National Research Council (IDÆA-CSIC) and Excelencia Severo Ochoa Project (CEX2018-000794-S) financed by Ministry of Science and Innovation (MINECO, Spain).Peer reviewe

A comprehensive analysis of the sedimentology, petrography, diagenesis and reservoir quality of sandstones from the Oligocene Xiaganchaigou (E3) Formation in the Lengdong area, Qaidam Basin, China

Abstract The sandstone from the Oligocene Xiaganchaigou Formation (E3) in the Lengdong area, Qaidam Basin, China, is extensively distributed and acts as an effective regional reservoir for hydrocarbon accumulation. Based on thin sections, scanning electron microscopy (SEM), X-ray diffraction (XRD) image analysis and cathodoluminescence (CL), a comprehensive analysis of the sedimentology, petrography, diagenesis and reservoir quality of the Oligocene sandstone reservoirs of the Xiaganchaigou (E3) Formation in the Lengdong area, Qaidam Basin, are studied. The sandstones in the Lengdong area are classified as argillaceous sandstone, silty sandstone, fine sandstone, medium sandstone, pebbly sandstone, conglomeratic sandstone and conglomerate based on their grain sizes, degrees of sorting, and matrix contents. Five sedimentary facies were identified in the Xiaganchaigou Formation (E3) of the Lengdong area, Qaidam Basin: distributary channel, interdistributary bay, mouth bar, central bar and distal sand sheet facies. Their major diagenetic processes include compaction, carbonate cementation and feldspar and calcite cement dissolution. The porosity and permeability values of the fine sandstone, conglomerate, and conglomeratic sandstone are the highest, followed by those of the medium sandstone and silty sandstone, and the argillaceous sandstone and pebbly sandstone have the lowest porosity and permeability values. The diagenetic sequence in the study area ranges from the eodiagenesis B stage to the mesodiagenetic A stage. Compaction has significantly reduced the primary porosity. Carbonate cements, mainly calcite cements, occlude pores by precipitating in intergranular and intragranular spaces. Dissolution largely contributes to increasing the secondary porosity. The well-sorted and relatively coarser-grained sandstones that formed in higher-energy sedimentary facies (distributary channel, mouth bar and central bar) have a better reservoir quality than the poorly sorted, clay-rich sandstones that formed in low-energy environments (interdistributary bay and distal sand sheet). Based on the comprehensive analysis of petrographic data, diagenesis and sedimentary facies, the reservoir in the Lengdong area is classified into three types: type A, type B and type C. Type A, located in the center of the study area, is the most favorable reservoir, while type C sandstone is the last to consider when looking for a good reservoir. This study can guide hydrocarbon exploration in the Lengdong area, as well as in northwestern China and similar areas throughout the world

Geological Controls on Enrichment of Rare Earth Elements and Yttrium (REY) in Late Permian Coals and Non-Coal Rocks in the Xian’an Coalfield, Guangxi Province

The highly elevated concentrations of the rare earth elements and yttrium (REY), U, Mo, Se, and Pb in late Permian coals in some coalfields in Guangxi Province, South China, have been widely investigated; however, the mode of occurrence and enrichment mechanism of these critical elements are still under debate. This study investigates the mineralogical and geochemical compositions of coals and non-coal rocks from the Xian’an Coalfield in Guangxi Province to discuss the geological factors influencing the distribution of critical elements. The mineral in the studied coals consists mainly of quartz, and to a lesser extent, muscovite and kaolinite, with a trace amount of anatase. The coals are significantly enriched in REY, Pb, Se, Mo, and U and display the REY–U–Se–Mo–Pb-enrichment horizon (Horizon I) and U–Mo-enrichment horizon (Horizon II) adjacent to the host rocks or partings. The REY, U, Se, and Pb show organic association while Mo is primarily hosted by Fe-sulfides within Horizon I. The U and Mo have a phosphate affinity within Horizon II. Both the input of pyroclastic and epiclastic materials and the leaching of acidic solutions jointly govern the distribution of the REY–U–Se–Mo–Pb-enrichment horizon (Horizon I) and the U–Mo-enrichment horizon (Horizon II). The concentrations of REY in Horizon I exceed the cutoff grade of REY, and, therefore, the coals in the Horizon I can be regarded as promising raw materials of REY.This study was funded by the National Science Foundation of China (no. 41972182), the National Science Foundation of Guangxi Province (no. 2018JJA150165), the “Overseas Top Scholars Program”, part of the “Recruitment Program of Global Experts” (no. G20190017067), and the Key Laboratory of Tectonics and Petroleum Resources (TPR-2018-16).Peer reviewe

Geological Controls on Geochemical Anomaly of the Carbonaceous Mudstones in Xian’an Coalfield, Guangxi Province, China

The anomalous enrichment of the rare earth elements and yttrium (REY), U, Mo, As, Se, and V in the coal-bearing intervals intercalated within the carbonate successions in South China has attracted much attention due to the highly promising recovery potential for these elements. This study investigates the mineralogical and geochemical characteristics of the late Permian coal-bearing intervals (layers A–F) intercalated in marine carbonate strata in the Xian’an Coalfield in Guangxi Province to elucidate the mode of occurrence and enrichment process of highly elevated elements. There are two mineralogical assemblages, including quartz-albite-kaolinite-carbonates assemblage in layers D–F and quartz-illite-kaolinite-carbonates assemblage in layers A–C. Compared to the upper continental crust composition (UCC), the REY, U, Mo, As, Se, and V are predominantly enriched in layers A and B, of which layer A displays the REY–V–Se–As assemblage while layer B shows the Mo–U–V assemblage. The elevated REY contents in layer B are primarily hosted by clay minerals, zircon, and monazite; Mo, U, and V show organic association; and As and Se primarily display Fe-sulfide association. Three geological factors are most likely responsible for geochemical anomaly: (1) the more intensive seawater invasion gives rise to higher sulfur, Co, Ni, As, and Se contents, as well as higher Sr/Ba ratio in layers A–C than in layers D–F; (2) both the input of alkaline pyroclastic materials and the solution/rock interaction jointly govern the anomalous enrichment of REY; and (3) the influx of syngenetic or early diagenetic hydrothermal fluids is the predominant source of U, Mo, V, Se, and As.This research was funded by the National Key Research and Development Program of China (No. 2021YFC2902005), National Science Foundation of China (No. 41972182), the National Science Foundation of Guangxi Province (No. 2018JJA150165), and Science Program of China National Administration of Coal Geology (no. ZMKJ-2021-ZX03).Peer reviewe