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Process intensification for the direct synthesis of adipic acid in a micro packed bed reactor
Abstract only
Magnetocrystalline anisotropic effect in GdCoFeAsO ()
From a systematic study of the electrical resistivity , magnetic
susceptibility , isothermal magnetization and the specific
heat , a temperature-magnetic field (-) phase diagram has been
established for GdCoFeAsO ( and ) polycrystalline
compounds. GdCoAsO undergoes two long-range magnetic transitions: ferromagnetic
(FM) transition of Co electrons () and
antiferromagnetic (AFM) transition of Gd electrons
(). For the Fe-doped sample (), an extra
magnetic reorientation transition takes place below ,
which is likely associated with Co moments. The two magnetic species of Gd and
Co are coupled antiferromagnetically to give rise to ferrimagnetic (FIM)
behavior in the magnetic susceptibility. Upon decreasing the temperature (), the magnetocrystalline anisotropy breaks up the FM
order of Co by aligning the moments with the local easy axes of the various
grains, leading to a spin reorientation transition at
. By applying a magnetic field,
monotonically decreases to lower temperatures, while
the is relatively robust against the external field.
On the other hand, the applied magnetic field pulls the magnetization of grains
from the local easy direction to the field direction via a first-order
reorientation transition, with the transition field () increasing
upon cooling the temperature.Comment: accepted by physical Review B 6 figures and 7 page
Ising-type Magnetic Anisotropy in CePdAs
We investigated the anisotropic magnetic properties of CePdAs by
magnetic, thermal and electrical transport studies. X-ray diffraction confirmed
the tetragonal ThCrSi-type structure and the high-quality of the single
crystals. Magnetisation and magnetic susceptibility data taken along the
different crystallographic directions evidence a huge crystalline electric
field (CEF) induced Ising-type magneto-crystalline anisotropy with a large
-axis moment and a small in-plane moment at low temperature. A detailed CEF
analysis based on the magnetic susceptibility data indicates an almost pure
CEF ground-state doublet with the dominantly
and the doublets at 290 K and 330
K, respectively. At low temperature, we observe a uniaxial antiferromagnetic
(AFM) transition at K with the crystallographic -direction being
the magnetic easy-axis. The magnetic entropy gain up to reaches almost
indicating localised -electron magnetism without significant
Kondo-type interactions. Below , the application of a magnetic field along
the -axis induces a metamagnetic transition from the AFM to a
field-polarised phase at T, exhibiting a text-book example
of a spin-flip transition as anticipated for an Ising-type AFM.Comment: 9 Pages, 8 figure
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