Intermittent Prediction Method Based On Marcov Method And Grey Prediction Method

This paper concentrates on the intermittent demand for electric power supply and studies the method of demand prediction. This chapter first divides the demand for electric power supply into two statistical sequences: (1) sequence of demand occurrence, among which “1”stands for the occurrence of demand,“0”means that the demand fails to occur; (2) sequence of demand quantity. Next the author predicts the moment of time and the number of times n that demand occurs within a specific time interval in the future based on 0-1 sequence using Markov arrival process (MAP). Then the paper forecasts the demand quantity in subsequent n intervals using Grey prediction model GM (1, 1) based on the sequence of demand quantity. Finally, the author places the demand quantity in the n intervals in order at the moments where demand occurs to get the predicted result of demand for electric material with intermittent demand. According to instance analysis, the integrated approach mentioned in this paper surpasses existing methods in providing accurate prediction on data of product with intermittent demand

Catalysis on singly dispersed bimetallic sites

A catalytic site typically consists of one or more atoms of a catalyst surface that arrange into a configuration offering a specific electronic structure for adsorbing or dissociating reactant molecules. The catalytic activity of adjacent bimetallic sites of metallic nanoparticles has been studied previously. An isolated bimetallic site supported on a non-metallic surface could exhibit a distinctly different catalytic performance owing to the cationic state of the singly dispersed bimetallic site and the minimized choices of binding configurations of a reactant molecule compared with continuously packed bimetallic sites. Here we report that isolated Rh1Co3 bimetallic sites exhibit a distinctly different catalytic performance in reduction of nitric oxide with carbon monoxide at low temperature, resulting from strong adsorption of two nitric oxide molecules and a nitrous oxide intermediate on Rh1Co3 sites and following a low-barrier pathway dissociation to dinitrogen and an oxygen atom. This observation suggests a method to develop catalysts with high selectivity