309 research outputs found

    Effect of KNO3 Molten Bath Na Enrichment on the Mechanical Performances of Ion-exchanged Soda-Lime-Silicate Glass

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    Systematic doping of pure molten KNO3 bath by sodium nitride was used to analyze the effect of salt poisoning on the mechanical performances of chemically tempered soda-lime-silicate float glass. The ion-exchange process appears partially influenced by the presence of limited amount of Na in the potassium nitride bath. The interdiffusion coefficient and the penetration depth of K are invariant for NaNO3 content up to 5 wt%; conversely, the surface concentration of potassium scales with the purity of the bath, and this accounts for different compressive residual stress. Nevertheless, the overall reinforcement associated to the final strength does not show clear dependence on the used bath mainly because of the large scatter in the surface flaws sizes, as typically observed in glass

    Electric Field-Assisted Ion Exchange of Borosilicate Glass Tubes

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    In this work, DC electric field-assisted ion exchange was carried out to enhance the sodium-potassium inter-diffusion and improve the mechanical performance of borosilicate glass. Electric fields with intensity varying between 100 V cm-1 and 3000 V cm-1 were applied in both direct and inverted polarizations. Four point bending test and the Vickers indentation method were used to characterize the mechanical properties. Energy dispersion x-ray spectroscopy was carried out to determine the potassium concentration within the surface layers of the samples
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