Low-temperature synthesis of CuO-interlaced nanodiscs for lithium ion battery electrodes

In this study, we report the high-yield synthesis of 2-dimensional cupric oxide (CuO) nanodiscs through dehydrogenation of 1-dimensional Cu(OH)2 nanowires at 60°C. Most of the nanodiscs had a diameter of approximately 500 nm and a thickness of approximately 50 nm. After further prolonged reaction times, secondary irregular nanodiscs gradually grew vertically into regular nanodiscs. These CuO nanostructures were characterized using X-ray diffraction, transmission electron microscopy, and Brunauer-Emmett-Teller measurements. The possible growth mechanism of the interlaced disc CuO nanostructures is systematically discussed. The electrochemical performances of the CuO nanodisc electrodes were evaluated in detail using cyclic voltammetry and galvanostatic cycling. Furthermore, we demonstrate that the incorporation of multiwalled carbon nanotubes enables the enhanced reversible capacities and capacity retention of CuO nanodisc electrodes on cycling by offering more efficient electron transport paths

Effect of supply chain structure and power dynamics on R&D and market performances

This study is the first investigating the effect of supply chain structure and players’ power dynamics on a supply chain’s R&D and market performances. We consider a three-stage supply chain, consisting of a R&D firm, a manufacturer, and a seller. We develop six supply chain models based on various structures and power dynamics, and reveal important implications by comparing the models. R&D performance is a function of supply chain structure; an integrated supply chain can expect improved performance. The selling price is a function of power dynamics, and is higher when R&D has bargaining power. Market and profit performances are higher in an integrated, manufacturer-led supply chain. The manufacturer’s role must be revisited; due to its location in the middle of the supply chain, the manufacturer can directly control the overall chain. On the other hand, a R&D firm could innately be associated with marginalization issues. Therefore, it is important for the R&D firm to have a systematic understanding of the entire system. This study contributes to the literature and practice by not only bridging the gap in the previous studies but also offering important managerial implications

EFFECTS OF MO, CR, AND V ADDITIONS ON TENSILE AND CHARPY IMPACT PROPERTIES OF API X80 PIPELINE STEELS

In this study, four API X80 pipeline steels were fabricated by varying Mo, Cr, and V additions, and their microstructures and crystallographic orientations were analyzed to investigate the effects of their alloying compositions on tensile properties and Charpy impact properties. Because additions of Mo and V promoted the formation of fine acicular ferrite (AF) and granular bainite (GB) while prohibiting the formation of coarse GB, they increased the strength and upper-shelf energy (USE) and decreased the energy transition temperature (ETT). The addition of Cr promoted the formation of coarse GB and hard secondary phases, thereby leading to an increased effective grain size, ETT, and strength, and a decreased USE. The addition of V resulted in a higher strength, a higher USE, a smaller effective grain size, and a lower ETT, because it promoted the formation of fine and homogeneous of AF and GB. The steel that contains 0.3 wt pct Mo and 0.06 wt pct V without Cr had the highest USE and the lowest ETT, because its microstructure was composed of fine AF and GB while its maintained excellent tensile properties.X1126sciescopu

GAS AND SOLID MIXING IN A THREE PARTITIONED FLUIDIZED BED

There are many gas-solid reaction systems which take place simultaneously in a single reactor, such as coal gasification. By splitting the reactions, high concentrated gases can be obtained without separation processes. Dual fluidized bed was proposed for this purpose. Similarly, simultaneous adsorption/desorption systems with dry sorbent for CO2 capture and the gasification reaction system with a char combustor and a gasifier separately were developed. For improving gas and solid mixing efficiencies of the dual fluidized beds, a hitherto unknown partitioned fluidized bed (PFB) is proposed. A basic concept of PFB is that lower parts between two separated fluidized beds are linked (opened), whereas upper parts are blocked by walls. Solid mixing occurs in lower parts with preventing gas mixing. The solid residence time becomes longer than that of dual fluidized bed and the high conversion of solid can be obtained. In this study, the gas and the solid mixing behaviors were investigated in three partitioned fluidized beds (left, center and right). The size of each fluidized bed is 7 cm (w) X 7 cm (d) X 30 cm (h) and partitioned above the 7 cm of distributor. Air and CO2-air mixture were used as fluidizing gas in each partitioned fluidized bed. For the gas mixing experiments, glass bead particles with 150 micron and density of 2.5g/cm3 were introduced. Outlet gas concentrations of each fluidized bed were analyzed by IR and then the gas exchanges between the reactors were calculated. For the solid mixing experiments, the polypropylene particles with 1000 micron and the density of 0.883 g/cm3 were continuously fed into the reactor. The gas mixing percentages were 0.4 ~ 16.0% of input gas amounts with varying gas velocities. The solid discharge rates in center and right side can be controlled by operating conditions

A case of anemia caused by combined vitamin B12 and iron deficiency manifesting as short stature and delayed puberty

Anemia caused by vitamin B12 deficiency resulting from inadequate dietary intake is rare in children in the modern era because of improvements in nutritional status. However, such anemia can be caused by decreased ingestion or impaired absorption and/or utilization of vitamin B12. We report the case of an 18-year-old man with short stature, prepubertal sexual maturation, exertional dyspnea, and severe anemia with a hemoglobin level of 3.3 g/dL. He had a history of small bowel resection from 50 cm below the Treitz ligament to 5 cm above the ileocecal valve necessitated by midgut volvulus in the neonatal period. Laboratory tests showed deficiencies of both vitamin B12 and iron. A bone marrow examination revealed dyserythropoiesis and low levels of hemosiderin particles, and a cytogenetic study disclosed a normal karyotype. After treatment with parenteral vitamin B12 and elemental iron, both anemia and growth showed gradual improvement. This is a rare case that presented with short stature and delayed puberty caused by nutritional deficiency anemia in Korea

A Study of Solids and Gas Mixing in a Partitioned Fluidized Bed

A partitioned fluidized bed gasifier has been developed for improving coal gasification performance. The basic concept is to divide a fluidized bed into two parts, a gasifier and a combustor, by a partition. Char is burnt in the combustor and generated heat is supplied to the gasifier by solid mixing. Therefore, solid mixing should be maximized whereas gas mixing between syngas and the combusted gas should be minimized. In this study, gas and solid mixing behaviors were verified in cold model acrylic beds. For monitoring solid mixing behavior, transient temperature trends in the beds were analyzed. A heat source and a heat sink were installed in each bed. Dozens of thermocouples were used to monitor temperature distribution